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Diffusion coefficient of 1-azabicyclo[2.2.2]octane in dideuterium oxide

  • Jochen Winkelmann
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of 1-azabicyclo[2.2.2]octane in dideuterium oxide at different concentrations measured using NMR spin echo pulse gradient.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C7 H13 N

(1)

1-azabicyclo[2.2.2]octane

100-76-5

D2 O

(2)

dideuterium oxide

7789-20-0

Intradiffusion Coefficient: D1T (xi); T = 318 K; Method: NMR PG

Ref.: [1990M4]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.020

101.32

0.5

 

0.060

101.32

0.27*

 

Comment: *: temperature of measurement 309 K

Intradiffusion Coefficient: D2T (xi); T = 318 K; Method: NMR PG

Ref.: [1990M4]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.020

101.32

2.1

 

0.060

101.32

1.3*

 

Comment: *: temperature of measurement 309 K

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

NMR PG

NMR spin echo pulse gradient

x i

mole fraction

References

  1. [1990M4]
    Maliniak A., Laaksonen, A., Korppi-Tommola, J.: J. Am. Chem. Soc. 112 (1990) 86–93.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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