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Diffusion coefficient of toluene in chlorobenzene

  • Jochen Winkelmann
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of toluene in chlorobenzene at different concentrations measured using Mach-Zehnder interferometry.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C7 H8

(1)

toluene

108-88-3

C6 H5 Cl

(2)

chlorobenzene

108-90-7

Mutual Diffusion Coefficient: D12(x i ); T = 283.15 K; Method: MZ-INT

Ref.: [1956C1]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.01337

101.32

1.346 ± 1%

 

0.2501

101.32

1.404 ± 1%

 

0.4992

101.32

1.556 ± 1%

 

0.7492

101.32

1.652 ± 1%

 

0.9862

101.32

1.759 ± 1%

 

Mutual Diffusion Coefficient: D12(x i ); T = 300.11 K; Method: MZ-INT

Ref.: [1956C1]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.01337

101.32

1.756 ± 1%

 

0.0501

101.32

1.852 ± 1%

 

0.4992

101.32

1.985 ± 1%

 

0.7492

101.32

2.128 ± 1%

 

0.9862

101.32

2.264 ± 1%

 

Mutual Diffusion Coefficient: D12(x i ); T = 313.16 K; Method: MZ-INT

Ref.: [1965C1]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.01337

101.32

2.113 ± 1%

 

0.2501

101.32

2.277 ± 1%

 

0.4992

101.32

2.435 ± 1%

 

0.7492

101.32

2.586 ± 1%

 

0.9862

101.32

2.714 ± 1%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

MZ-INT

Mach-Zehnder interferometry

x i

mole fraction

References

  1. [1956C1]
    Caldwell, C. S., Babb, A. L.: J. Phys. Chem. 60 (1956) 51–56.CrossRefGoogle Scholar
  2. [1965C1]
    Campbell, A. N., Lakshminarayanan, G. R.: Can. J. Chem. 43 (1965) 1729–1737.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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