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Diffusion coefficient of chlorobenzene in bromobenzene

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of chlorobenzene in bromobenzene at different concentrations measured using Mach-Zehnder interferometry.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C6 H5 Cl

(1)

chlorobenzene

108-90-7

C6 H5 Br

(2)

bromobenzene

108-86-1

Mutual Diffusion Coefficient: D12(x i ); T = 283.16 K; Method: MZ-INT

Ref.: [1956C1]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.0332

101.32

1.007 ± 1%

 

0.2642

101.32

1.069 ± 1%

 

0.5122

101.32

1.146 ± 1%

 

0.7617

101.32

1.226 ± 1%

 

0.9652

101.32

1.291 ± 1%

 

Mutual Diffusion Coefficient: D12(x i ); T = 299.93 K; Method: MZ-INT

Ref.: [1956C1]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.0332

101.32

1.342 ± 1%

 

0.2642

101.32

1.380 ± 1%

 

0.5122

101.32

1.506 ± 1%

 

0.7617

101.32

1.596 ± 1%

 

0.9652

101.32

1.708 ± 1%

 

Mutual Diffusion Coefficient: D12(x i ); T = 313.12 K; Method: MZ-INT

Ref.: [1956C1]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.0332

101.32

1.584 ± 1%

 

0.2642

101.32

1.691 ± 1%

 

0.5122

101.32

1.806 ± 1%

 

0.7617

101.32

1.902 ± 1%

 

0.9652

101.32

1.996 ± 1%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

MZ-INT

Mach-Zehnder interferometry

x i

mole fraction

References

  1. [1956C1]
    Caldwell, C. S., Babb, A. L.: J. Phys. Chem. 60 (1956) 51–56.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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