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Diffusion coefficient of chlorobenzene in propane-1,2-diol

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of chlorobenzene in propane-1,2-diol at different concentrations measured using Savart plate interferometry.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C6 H5 Cl

(1)

chlorobenzene

108-90-7

C3 H8 O2

(2)

propane-1,2-diol

57-55-6

Mutual Diffusion Coefficient: D12(x i ); T = 288.15 K; Method: SAV-INT

Ref.: [1975S9]

m1 [mol/kg]

p [kPa]

D ⋅ 1011 [m2/s]

 

0.097

101.32

3.30 ± 0.03

 

0.175

101.32

3.34 ± 0.02

 

0.243

101.32

3.45 ± 0.04

 

0.428

101.32

3.68 ± 0.03

 

0.637

101.32

3.80 ± 0.05

 

Mutual Diffusion Coefficient: D12(x i ); T = 298.15 K; Method: SAV-INT

Ref.: [1975S9]

m1 [mol/kg]

p [kPa]

D ⋅ 1011 [m2/s]

 

0.241

101.32

6.53 ± 0.06

 

0.373

101.32

6.94 ± 0.05

 

0.516

101.32

7.17 ± 0.07

 

0.830

101.32

8.52 ± 0.06

 

1.078

101.32

9.22 ± 0.07

 

Mutual Diffusion Coefficient: D12(x i ); T = 308.15 K; Method: SAV-INT

Ref.: [1975S9]

m1 [mol/kg]

p [kPa]

D ⋅ 1011 [m2/s]

 

0.119

101.32

11.18 ± 0.10

 

0.171

101.32

11.31 ± 0.14

 

0.241

101.32

11.62 ± 0.10

 

0.301

101.32

11.73 ± 0.09

 

0.462

101.32

12.35 ± 0.11

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

x i

mole fraction

m i

molality

SAV-INT

Savart plate interferometry

References

  1. [1975S9]
    Skipp, C. J., Tyrrell, H. J. V.: J. Chem. Soc., Faraday Trans. I 71 (1975) 1744–1752.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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