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Diffusion coefficient of tetrachloro-methane in carbon disulfide

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of tetrachloro-methane in carbon disulfide at different concentrations measured using dynamic light scattering.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C Cl4

(1)

tetrachloro-methane

56-23-5

C S2

(2)

carbon disulfide

75-15-0

Mutual Diffusion Coefficient: D12(xi); T = 293.15 ± 0.5 K; Method: DLS

Ref.: [1975C10]

x 2

p [kPa]

D ⋅ 109 [m2/s]

 

0.20

101.32

2.12 ± 5%

 

0.35

101.32

2.17 ± 5%

 

0.50

101.32

2.33 ± 5%

 

0.65

101.32

2.28 ± 5%

 

0.80

101.32

2.62 ± 5%

 

Mutual Diffusion Coefficient: D12(x1); Method: DLS

Ref.: [1987S8]

Equation: D = A + B x + C x2 + E x3

Range: 0.0 < x1 < 1.0

Comment: D12 [m2/s] = D ⋅ 10−9

Parameter:

T [K]

A

B

C

E

Std-Dev

 

293.1

3.002

−2.711

3.124

−1.060

0.019

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

DLS

dynamic light scattering

x i

mole fraction

References

  1. [1975C10]
    Czworniak, K. J., Andersen, H. C., Pecora, R.: Chem. Phys. 11 (1975) 451–473.CrossRefGoogle Scholar
  2. [1987S8]
    Siddiqi, M. A., Krahn, W., Lucas, K.: J. Chem. Eng. Data 32 (1987) 48–50.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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