Advertisement

Diffusion coefficient of diethyl ether in trichloro-methane

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of diethyl ether in trichloro-methane at different concentrations measured using interferometry and diaphragm cell.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C4 H10 O

(1)

diethyl ether

60-29-7

C H Cl3

(2)

trichloro-methane

67-66-3

Mutual Diffusion Coefficient: D12(xi); T = 298.15 K; Method: DIA

Ref.: [1971S5]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.0

101.32

2.131

 

0.1

101.32

2.550

 

0.2

101.32

2.930

 

0.3

101.32

3.331

 

0.4

101.32

3.685

 

0.5

101.32

4.001

 

0.6

101.32

4.212

 

0.7

101.32

4.353

 

0.8

101.32

4.380

 

0.9

101.32

4.420

 

1.0

101.32

4.475

 

Comment: mean deviation: ±1–2%; identical data set published in [1973S3]

Mutual Diffusion Coefficient: D12(xi); T = 298.15 K; Method: MZ-INT

Ref.: [1961A1]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.00435

101.32

2.147

 

0.2044

101.32

2.909

 

0.404

101.32

3.683

 

0.601

101.32

4.211

 

0.794

101.32

4.381

 

0.794

101.32

4.442

 

0.896

101.32

4.488

 

0.997

101.32

4.509

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

x i

mole fraction

INT

interferometry

DIA

diaphragm cell

References

  1. [1961A1]
    Anderson, D. K., Babb, A. L.: J. Phys. Chem. 65 (1961) 1281–1283.CrossRefGoogle Scholar
  2. [1971S5]
    Sanni, S. A., Fell, C. J. D., Hutchison, H. P.: J. Chem. Eng. Data 16 (1971) 424–427.CrossRefGoogle Scholar
  3. [1973S3]
    Sanni, S. A., Hutchison, P.: J. Chem. Eng. Data 18 (1973) 317–322.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

Personalised recommendations