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Diffusion coefficient of propan-2-one into benzene, tetrachloro-methane and hexane at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of propan-2-one into benzene, tetrachloro-methane and hexane at infinite dilution for different concentrations measured using diaphragm cell.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.5. Diffusion in Quaternary Mixtures

C3 H6 O

(1)

propan-2-one

67-64-1

C6 H6

(2)

benzene

71-43-2

C Cl4

(3)

tetrachloro-methane

56-23-5

C6 H14

(4)

hexane

110-54-3

Mutual Diffusion Coefficient Matrix: Dij (xi, xj, xk); Method: DIA

Ref.: [1973R1]

T = 298.15 ± 0.02 K; p = 101.325 kPa

 

x 1

x 2

x 3

Di1 ⋅ 109 [m2/s]

Di2 ⋅ 109 [m2/s]

Di3 ⋅ 109 [m2/s]

0.25

0.25

0.25

2.321 ± 0.052

−0.494 ± 0.043

−0.191 ± 0.054

   

−0.299 ± 0.032

2.962 ± 0.042

−0.065 ± 0.041

   

0.074 ± 0.043

−0.026 ± 0.033

2.860 ± 0.049

Comment: deviation at 95% confidence interval

Symbols and Abbreviations

Short Form

Full Form

x i

mole fraction

D

diffusion coefficient

p

pressure

T

temperature

DIA

diaphragm cell

References

  1. [1973R1]
    Rai, G. P., Cullinan, H. T.: J. Chem. Eng. Data 18 (1973) 213–214.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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