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Diffusion coefficient of cyclohexa-amylose into 2-amino-3-phenyl-propanoic acid and water

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of cyclohexa-amylose into 2-amino-3-phenyl-propanoic acid and water at different concentrations measured using interferometry and Gouy interferometry.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.3. Diffusion in Ternary Mixtures

C36 H60 O30

(1)

cyclohexa-amylose

10016-20-3

C9 H11 N O2

(2)

2-amino-3-phenyl-propanoic acid

63-91-2

H2 O

(3)

water

7732-18-5

Mutual Diffusion Coefficient Matrix: Dij (ci, cj); Method: G-INT

Ref.: [1990P1]

T = 298.15 ± 0.01 K; p = 101.325 kPa

c1 [mol/dm3]

c2 [mol/dm3]

D11 ⋅ 1010 [m2/s]

D12 ⋅ 1010 [m2/s]

D21 ⋅ 1010 [m2/s]

D22 ⋅ 1010 [m2/s]

0.02015

0.02503

3.276 ± 0.005

0.007 ± 0.002

−0.411 ± 0.030

6.287 ± 0.011

0.02012

0.05001

3.245 ± 0.008

−0.002 ± 0.003

−0.951 ± 0.050

6.315 ± 0.018

0.02010

0.07491

3.177 ± 0.006

0.005 ± 0.001

−1.220 ± 0.025

6.298 ± 0.016

0.02005

0.10020

3.157 ± 0.016

0.000 ± 0.004

−1.630 ± 0.101

6.332 ± 0.024

Mutual Diffusion Coefficient Matrix: Dij (ci, cj); Method: G-INT

Ref.: [1990P2]

T = 298.15 ± 0.02 K; p = 101.325 kPa

c1 [mol/L]

c2 [mol/L]

D11 ⋅ 109 [m2/s]

D12 ⋅ 109 [m2/s]

D21 ⋅ 109 [m2/s]

D22 ⋅ 109 [m2/s]

0.02015

0.02503

0.3276

−0.0007

−0.0411

0.6287

0.02015

0.05001

0.3245

−0.0002

−0.0951

0.6315

0.02015

0.07491

0.3177

0.0005

−0.1220

0.6298

0.02015

0.1002

0.3157

0.000

−0.1630

0.6332

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

c i

molarity

INT

interferometry

G-INT

Gouy interferometry

References

  1. [1990P1]
    Paduano, L., Sartorio, R., Vitagliano, V., Albright, J. G., Miller, D. G., Mitchell, J.: J. Phys. Chem. 94 (1990) 6885–6888.CrossRefGoogle Scholar
  2. [1990P2]
    Paduano, L., Sartorio, R., Vitagliano, V., Castronuovo, G.: Thermochim. Acta 162 (1990) 155–161.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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