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Diffusion coefficient of N,N-dimethyl-N-(3-sulfopropyl)-1- decanaminium into N,N-dimethyl-N-(3-sulfopropyl)-1- dodecanaminium and water

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of N,N-dimethyl-N-(3-sulfopropyl)-1- decanaminium into N,N-dimethyl-N-(3-sulfopropyl)-1- dodecanaminium and water at different concentrations measured using Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.3. Diffusion in Ternary Mixtures

C15 H33 N O3 S

(1)

N,N-dimethyl-N-(3-sulfopropyl)-1-decanaminium

15163-36-7

C17 H37 N O3 S

(2)

N,N-dimethyl-N-(3-sulfopropyl)-1-dodecanaminium

14933-08-5

H2 O

(3)

water

7732-18-5

Mutual Diffusion Coefficient Matrix: Dij (ci, cj); Method: TAYLOR

Ref.: [2008D1]

T = 298.15 K; p = 101.325 kPa

c1 [mol/dm3]

c2 [mol/dm3]

D11 ⋅ 109 [m2/s]

D12 ⋅ 109 [m2/s]

D21 ⋅ 109 [m2/s]

D22 ⋅ 109 [m2/s]

0.0

0.0200

0.400 ± 0.006

−0.001 ± 0.003

−0.025 ± 0.004

0.108 ± 0.005

0.0050

0.0150

0.406 ± 0.008

−0.033 ± 0.002

−0.027 ± 0.008

0.112 ± 0.003

0.0100

0.0100

0.418 ± 0.004

−0.080 ± 0.003

−0.025 ± 0.003

0.122 ± 0.002

0.0150

0.0050

0.451 ± 0.003

−0.187 ± 0.014

−0.029 ± 0.003

0.145 ± 0.010

0.0180

0.0020

0.470 ± 0.003

−0.271 ± 0.010

−0.024 ± 0.004

0.208 ± 0.006

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

c i

molarity

TAYLOR

Taylor dispersion technique

References

  1. [2008D1]
    Das B., Maitra, B., Mercer, S. M., Everist, M., Leaist, D. G.: Phys. Chem. Chem. Phys. 10 (2008) 3083–3092.CrossRefPubMedGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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