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Diffusion coefficient of propan-1-ol-d1 into dideuterium oxide and urea-d4

  • Jochen Winkelmann
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of propan-1-ol-d1 into dideuterium oxide and urea-d4 at different concentrations measured using NMR spin echo pulse gradient.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.3. Diffusion in Ternary Mixtures

C3 H7 D O

(1)

propan-1-ol-d1

4712-36-1

D2 O

(2)

dideuterium oxide

7789-20-0

C D4 N2 O

(3)

urea-d4

1433-11-0

Intradiffusion Coefficient: DiT (xi); T = 298.15 ± 0.3 K; Method: NMR PG

Ref.: [1996S1]

x 1

x 3

p [kPa]

D1T ⋅ 109 [m2/s]

D2T ⋅ 109 [m2/s]

D3T ⋅ 109 [m2/s]

0.0091

0.09

101.325

0.76 ± 2.0%

  

0.0455

0.09

101.325

0.58 ± 2.0%

  

0.091

0.09

101.325

0.48 ± 2.0%

  

0.182

0.09

101.325

0.39 ± 2.0%

  

0.273

0.09

101.325

0.38 ± 2.0%

  

0.364

0.09

101.325

0.41 ± 2.0%

  

0.455

0.09

101.325

0.42 ± 2.0%

  

0.0095

0.05

101.325

0.72 ± 2.0%

  

0.0475

0.05

101.325

0.57 ± 2.0%

  

0.095

0.05

101.325

0.47 ± 2.0%

  
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

x i

mole fraction

NMR PG

NMR spin echo pulse gradient

References

  1. [1996S1]
    Sacco, A., Asciolla, A., Matteoli, E., Holz, M.: J. Chem. Soc., Faraday Trans. 92 (1996) 35–40.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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