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Diffusion coefficient of propan-2-one into butan-1-ol and propan-1-ol

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of propan-2-one into butan-1-ol and propan-1-ol at different concentrations measured using holographic interferometry.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.3. Diffusion in Ternary Mixtures

C3 H6 O

(1)

propan-2-one

67-64-1

C4 H10 O

(2)

butan-1-ol

71-36-3

C3 H8 O

(3)

propan-1-ol

71-23-8

Mutual Diffusion Coefficient Matrix: Dij (xi, xj); Method: HOLO

Ref.: [2007R4]

T = 298.15 K; p = 101.325 kPa

x 1

x 2

D11 ⋅ 109 [m2/s]

D12 ⋅ 109 [m2/s]

D21 ⋅ 109 [m2/s]

D22 ⋅ 109 [m2/s]

0.05

0.05

1.1259

0.1767

−0.1025

0.7340

0.05

0.475

0.9635

0.0242

−0.3547

0.5958

0.05

0.9

0.9591

0.0178

−0.5008

0.5405

0.1

0.3

1.1428

0.0068

−0.1888

0.6904

0.1

0.6

1.0860

0.0270

−0.3444

0.6991

0.15

0.15

1.1181

0.0431

−0.2212

0.8147

0.15

0.7

1.1210

0.0832

−0.3335

0.7495

0.2

0.4

0.9920

−0.0006

−0.4228

0.8392

0.25

0.25

1.0786

0.0122

−0.3471

0.9309

0.25

0.5

1.1352

−0.0078

−0.4035

1.0648

0.3

0.1

1.2422

−0.0048

−0.2659

1.0948

0.3

0.6

1.1115

0.0155

−0.3993

0.9407

0.333

0.333

1.0150

0.0000

−0.4738

1.0710

0.4

0.2

1.2483

−0.0039

−0.4200

1.1730

0.4

0.4

1.1308

−0.0012

−0.4447

1.1823

0.475

0.05

1.1876

0.0216

−0.6617

1.4424

0.475

0.475

1.3634

−0.0106

−0.3009

1.3546

0.5

0.25

1.0284

0.0174

−0.8174

1.3516

0.6

0.1

1.3757

0.0257

−0.6789

1.6831

0.6

0.3

1.2161

0.0641

−0.8635

1.7525

0.7

0.15

1.5521

0.0351

−0.8141

1.8909

0.9

0.05

2.0419

0.0219

−0.9989

2.3702

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

x i

mole fraction

HOLO

holographic interferometry

References

  1. [2007R4]
    Rehfeldt S., Stichlmair, J.: Fluid Phase Equilib. 256 (2007) 99–104.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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