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Diffusion coefficient of 2,2-dichloro-propane into 1,1,1-trichloro-ethane and tetrachloro-methane

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of 2,2-dichloro-propane into 1,1,1-trichloro-ethane and tetrachloro-methane at different concentrations measured using diaphragm cell.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.3. Diffusion in Ternary Mixtures

C3 H6 Cl2

(1)

2,2-dichloro-propane

594-20-7

C2 H3 Cl3

(2)

1,1,1-trichloro-ethane

71-55-6

C Cl4

(3)

tetrachloro-methane

56-23-5

Mutual Diffusion Coefficient Matrix: Dij (xi, xj); Method: DIA

Ref.: [1976M7]

T = 298.15 K; p = 101.325 kPa

x 1

x 2

D11 ⋅ 109 [m2/s]

D12 ⋅ 109 [m2/s]

D21 ⋅ 109 [m2/s]

D22 ⋅ 109 [m2/s]

0.101

0.152

1.38 ± 0.07

−0.03 ± 0.04

−0.05 ± 0.03

1.41 ± 0.02

T = 303.15 K

0.101

0.152

1.54 ± 0.08

0.08 ± 0.08

0.00 ± 0.04

1.55 ± 0.04

T = 308.15 K

0.101

0.152

1.64 ± 0.08

0.03 ± 0.08

−0.07 ± 0.04

1.66 ± 0.04

T = 318.15 K

0.101

0.152

2.05 ± 0.11

0.11 ± 0.13

0.05 ± 0.05

2.02 ± 0.05

Mutual Diffusion Coefficient Matrix: Dij (xi, xj); Method: DIA

Ref.: [1975M9]

T = 298.15 ± 0.02 K; p = 101.325 kPa

x 1

x 2

D11 ⋅ 109 [m2/s]

D12 ⋅ 109 [m2/s]

D21 ⋅ 109 [m2/s]

D22 ⋅ 109 [m2/s]

0.1889

0.4506

1.375 ± 0.032

0.003 ± 0.038

−0.035 ± 0.048

1.436 ± 0.071

0.1007

0.1518

1.427 ± 0.072

−0.010 ± 0.028

−0.022 ± 0.042

1.403 ± 0.023

0.2854

0.3515

1.472 ± 0.074

−0.028 ± 0.082

0.022 ± 0.072

1.514 ± 0.082

0.2375

0.7008

1.558 ± 0.101

−0.003 ± 0.069

−0.185 ± 0.163

1.430 ± 0.108

0.0598

0.9006

1.522 ± 0.072

−0.017 ± 0.069

−0.133 ± 0.208

1.689 ± 0.166

0.0492

0.7999

1.364 ± 0.084

−0.004 ± 0.117

−0.175 ± 0.335

1.346 ± 0.450

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

x i

mole fraction

DIA

diaphragm cell

References

  1. [1975M9]
    Mortimer, R. G., Marlow, W. R., Shenep, J. L.: I & EC Fundamentals 14 (1975) 114–119.CrossRefGoogle Scholar
  2. [1976M7]
    Mortimer R. G., Hicks, B. C.: J. Phys. Chem. 80 (1976) 1376–1380.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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