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Diffusion coefficient of tetrabutyl-stannane in methanol at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of tetrabutyl-stannane in methanol at infinite dilution for various temperature and pressure conditions measured using Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C16 H36 Sn

(1)

tetrabutyl-stannane

1461-25-2

C H4 O

(2)

methanol

67-56-1

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1983C5]

T [K]

Type

D ⋅ 109 [m2/s]

 

283

D 0 1(2)

0.89 ± 0.001

 

298

D 0 1(2)

1.18 ± 0.001

 

313

D 0 1(2)

1.48 ± 0.001

 

333

D 0 1(2)

1.92 ± 0.001

 

353

D 0 1(2)

2.64 ± 0.002

 

383

D 0 1(2)

3.79 ± 0.003

 

Comment: precision: ±1%

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1979E2]

T [K]

Type

D ⋅ 109 [m2/s]

 

283.15 ± 0.01

D 0 1(2)

0.89 ± 0.01

 

298.15 ± 0.01

D 0 1(2)

1.18 ± 0.01

 

313.15 ± 0.01

D 0 1(2)

1.53 ± 0.02

 

Comment: data are identical to those in [1981E2] and in [1977E3]

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

TAYLOR

Taylor dispersion technique

References

  1. [1977E3]
    Evans, D. F., Chan, C., Lamartine, B. C.: J. Am. Chem. Soc. 99 (1977) 6492.CrossRefGoogle Scholar
  2. [1979E2]
    Evans, D. F., Tominaga, T., Chan, C.: J. Solution Chem. 8 (1979) 461–478.CrossRefGoogle Scholar
  3. [1981E2]
    Evans, D. F., Tominaga, T., Davis, H. T.: J. Chem. Phys. 74 (1981) 1298–1305.CrossRefGoogle Scholar
  4. [1983C5]
    Chen, S.-H., Evans, D. F., Davis, H. T.: AIChE J. 29 (1983) 640–645.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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