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Diffusion coefficient of biphenyl in ethanol at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of biphenyl in ethanol at infinite dilution for various temperature and pressure conditions measured using diaphragm cell and Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C12 H10

(1)

biphenyl

92-52-4

C2 H6 O

(2)

ethanol

64-17-5

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1998C5]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15 ± 0.02

D 0 1(2)

1.20 ± 0.01

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1992C5]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15 ± 0.02

D 0 1(2)

1.19 ± 0.01

 

Comment: data are identical to those in [1997C5]

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: DIA

Ref.: [1971L4]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

1.16 ± 3%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

TAYLOR

Taylor dispersion technique

DIA

diaphragm cell

References

  1. [1971L4]
    Lusis, M. A., Ratcliff, G. A.: AIChE J. 17 (1971) 1492–1496.CrossRefGoogle Scholar
  2. [1992C5]
    Chan, T. C., Chan, M. L.: J. Chem. Soc., Faraday Trans. 88 (1992) 2371–2374.CrossRefGoogle Scholar
  3. [1997C5]
    Chen, N., Chan, T.C.: Chem.Commun., 1997 719–720.Google Scholar
  4. [1998C5]
    Chan, T. C., Chen, N., Lu, J. G.: J. Phys. Chem. A 102 (1998) 9087–9090.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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