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Diffusion coefficient of ferrocene in acetonitrile at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of ferrocene in acetonitrile at infinite dilution for various temperature and pressure conditions measured using Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C10 H10 Fe

(1)

ferrocene

102-54-5

C2 H3 N

(2)

acetonitrile

75-05-8

Diffusion Coefficient at infinite dilution: p = 0.18 MPa; Method: TAYLOR

Ref.: [2010T1]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

2.654 ± 0.024

 

303.15

D 0 1(2)

2.797 ± 0.024

 

313.15

D 0 1(2)

3.151 ± 0.033

 

322.95*

D 0 1(2)

3.550 ± 0.042

 

333.15*

D 0 1(2)

3.985 ± 0.039

 

298.15**

D 0 1(2)

2.516 ± 0.017

 

Comment: *: p = 0.19 MPa; **: 0.1M tetraethylammonium perchlorate added

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

TAYLOR

Taylor dispersion technique

References

  1. [2010T1]
    Toriumi M., Katooka, R., Yui, K., Funazukuri, T., Kong, C. Y., Kagei, S. I.: Fluid Phase Equilib. 297 (2010) 62–66.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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