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Diffusion coefficient of naphthalene in cyclohexane at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of naphthalene in cyclohexane at infinite dilution for various temperature and pressure conditions measured using Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C10 H8

(1)

naphthalene

91-20-3

C6 H12

(2)

cyclohexane

110-82-7

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1985S6]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.2 ± 0.1

D 0 1(2)

1.452 ± 0.005

 

333.2 ± 0.1

D 0 1(2)

2.51 ± 0.02

 

373.2 ± 0.1

D 0 1(2)

4.30 ± 0.01

 

423.2 ± 0.1

D 0 1(2)

7.29 ± 0.04

 

473.4 ± 0.1

D 0 1(2)

11.5 ± 0.1

 

523.2 ± 0.1

D 0 1(2)

19.3 ± 0.2

 

523.2 ± 0.1

D 0 1(2)

18.15 ± 0.04

 

523.2 ± 0.1

D 0 1(2)

17.71 ± 0.07

 

Diffusion Coefficient at infinite dilution: p = 16.0 MPa; Method: TAYLOR

Ref.: [1994F2]

T [K]

Type

D ⋅ 109 [m2/s]

 

303.2

D 0 1(2)

1.31

 

313.2

D 0 1(2)

1.52

 

323.2

D 0 1(2)

1.79

 

333.2

D 0 1(2)

2.06

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [2013C1]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15 ± 0.01

D 0 1(2)

1.44 ± 0.01

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [2007S5]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

1.18 ± 3%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

TAYLOR

Taylor dispersion technique

References

  1. [1985S6]
    Sun, C. K. J., Chen, S. H.: AIChE J. 31 (1985) 1510–1515.CrossRefGoogle Scholar
  2. [1994F2]
    Funazukuri, T., Nishimoto, N., Wakao, N.: J. Chem. Eng. Data 39 (1994) 911–915.CrossRefGoogle Scholar
  3. [2007S5]
    Safi A., Nicolas, C., Neau, E., Chevalier, J. L.: J. Chem. Eng. Data 52 (2007) 977–981.CrossRefGoogle Scholar
  4. [2013C1]
    Chan T. C., Tang, W. K.: J. Chem. Phys. 138 (2013) 224503-1-224503/15.Google Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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