Advertisement

Diffusion coefficient of propan-2-one in succinonitrile

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of propan-2-one in succinonitrile at different concentrations measured using NMR spin echo pulse gradient.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C3 H6 O

(1)

propan-2-one

67-64-1

C4 H4 N2

(2)

succinonitrile

110-61-2

Intradiffusion Coefficient: D1T (T); Method: NMR PG

Ref.: [2000L3]

T [K]

p [kPa]

D ⋅ 109 [m2/s]

 

308.15 ± 0.3

101.32

0.716

 

308.15 ± 0.3

101.32

0.760

 

308.15 ± 0.3

101.32

0.74 ± 0.02

 

318.15 ± 0.3

101.32

0.920

 

318.15 ± 0.3

101.32

0.959

 

318.15 ± 0.3

101.32

0.865

 

318.15 ± 0.3

101.32

0.926 ± 0.04

 

328.15 ± 0.3

101.32

1.14

 

328.15 ± 0.3

101.32

1.40

 

328.15 ± 0.3

101.32

1.3 ± 0.1

 

Comment: concentration of solution: x2 = 0.88

Intradiffusion Coefficient: D2T (T); Method: NMR PG

Ref.: [2000L3]

T [K]

p [kPa]

D ⋅ 109 [m2/s]

 

308.15 ± 0.3

101.32

0.469

 

308.15 ± 0.3

101.32

0.494

 

308.15 ± 0.3

101.32

0.48 ± 0.01

 

318.15 ± 0.3

101.32

0.668

 

318.15 ± 0.3

101.32

0.611

 

318.15 ± 0.3

101.32

0.641

 

318.15 ± 0.3

101.32

0.642

 

318.15 ± 0.3

101.32

0.64 ± 0.02

 

328.15 ± 0.3

101.32

0.951

 

328.15 ± 0.3

101.32

1.04

 

328.15 ± 0.3

101.32

1.00 ± 0.04

 

Comment: concentration of solution: x2 = 0.88

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

NMR PG

NMR spin echo pulse gradient

x i

mole fraction

References

  1. [2000L3]
    Lutz J. L., Mendenhall, G. D.: J. Cryst. Growth 217 (2000) 183–188.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

Personalised recommendations