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Diffusion coefficient of toluene in chlorobenzene at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of toluene in chlorobenzene at infinite dilution for various temperature and pressure conditions measured using interferometry, correlation of experimental data and Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C7 H8

(1)

toluene

108-88-3

C6 H5 Cl

(2)

chlorobenzene

108-90-7

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: MZ-INT

Ref.: [1956C1]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

1.68

 

298.15

D 0 2(1)

2.21

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1962B3]

T [K]

Type

D ⋅ 109 [m2/s]

 

302.75 ± 0.03

D 0 1(2)

1.80 ± 2%

 

302.75 ± 0.03

D 0 2(1)

2.36 ± 2%

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [2001L3]

T [K]

Type

D ⋅ 109 [m2/s]

 

300.11

D 0 1(2)

1.750

 

300.11

D 0 2(1)

2.260

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [2012B2]

T [K]

Type

D ⋅ 109 [m2/s]

 

300.15

D 0 1(2)

1.75

 

300.15

D 0 2(1)

2.26

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

TAYLOR

Taylor dispersion technique

INT

interferometry

CORR

correlation of experimental data

References

  1. [1956C1]
    Caldwell, C. S., Babb, A. L.: J. Phys. Chem. 60 (1956) 51–56.CrossRefGoogle Scholar
  2. [1962B3]
    Burchard, J. K., Toor, H. L.: J. Phys. Chem. 66 (1962) 2015–2022.CrossRefGoogle Scholar
  3. [2001L3]
    Li J., Liu, H., Hu, Y.: Fluid Phase Equilibria 187188 (2001) 193–208.CrossRefGoogle Scholar
  4. [2012B2]
    Beigzadeh R., Rahimi, M., Shabanian, S. R.: Fluid Phase Equilib. 331 (2012) 48–57.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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