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Diffusion coefficient of hexane in tetrachloro-methane at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of hexane in tetrachloro-methane at infinite dilution for various temperature and pressure conditions measured using interferometry, correlation of experimental data and Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C6 H14

(1)

hexane

110-54-3

C Cl4

(2)

tetrachloro-methane

56-23-5

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1985C12]

T [K]

Type

D ⋅ 109 [m2/s]

 

293.7

D 0 1(2)

1.28 ± 0.02

 

308.2

D 0 1(2)

1.65 ± 0.01

 

323.2

D 0 1(2)

2.02 ± 0.01

 

337.2

D 0 1(2)

2.51 ± 0.01

 

353.2

D 0 1(2)

2.97 ± 0.02

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [2012B2]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

1.49

 

298.15

D 0 2(1)

3.90

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: MZ-INT

Ref.: [1969B8]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

1.47 ± 1%

 

Comment: data of low reliability; a factor of 10−5 is missing in dimension of D

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [2003C7]

T [K]

Type

D ⋅ 109 [m2/s]

 

303.15

D 0 1(2)

1.60

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

TAYLOR

Taylor dispersion technique

INT

interferometry

CORR

correlation of experimental data

References

  1. [1969B8]
    Bidlack, D. L., Kett, T. K., Kelly, C. M., Anderson, D. K.: J. Chem. Eng. Data 14 (1969) 342–343.CrossRefGoogle Scholar
  2. [1985C12]
    Chen H. C., Chen, S. H.: Chemical Engineering Science 40 (1985) 521–526.CrossRefGoogle Scholar
  3. [2003C7]
    Chan J., Popov, J. J., Kolisnek-Kehl, S., Leaist, D. G.: J. Solution Chem. 32 (2003) 197–214.CrossRefGoogle Scholar
  4. [2012B2]
    Beigzadeh R., Rahimi, M., Shabanian, S. R.: Fluid Phase Equilib. 331 (2012) 48–57.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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