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Diffusion coefficient of benzene in methanol at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of benzene in methanol at infinite dilution for various temperature and pressure conditions measured using diaphragm cell and Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C6 H6

(1)

benzene

71-43-2

C H4 O

(2)

methanol

67-56-1

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1999L4]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15 ± 0.02

D 0 1(2)

2.61 ± 0.02

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1984C6]

T [K]

Type

D ⋅ 109 [m2/s]

 

300.21 ± 0.02

D 0 1(2)

2.74 ± 0.02

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [2010S2]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

2.66 ± 3%

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [2008S4]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

2.66 ± 3%

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: DIA

Ref.: [1971L4]

T [K]

Type

D ⋅ 109 [m2/s]

 

300.15

D 0 1(2)

2.76 ± 3%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

TAYLOR

Taylor dispersion technique

DIA

diaphragm cell

References

  1. [1971L4]
    Lusis, M. A., Ratcliff, G. A.: AIChE J. 17 (1971) 1492–1496.CrossRefGoogle Scholar
  2. [1984C6]
    Chan, T. C.: J. Chem. Phys. 80 (1984) 5862–5864.CrossRefGoogle Scholar
  3. [1999L4]
    Lu, J.G., Kong, R., Chan, T.C.: J. Chem. Phys. 110 (1999) 3003–3008.CrossRefGoogle Scholar
  4. [2008S4]
    Safi A., Nicolas, C., Neau, E., Chevalier, J. L.: J. Chem. Eng. Data 53 (2008) 444–448.CrossRefGoogle Scholar
  5. [2010S2]
    Safi A., Nicolas, C., Neau, E., Escandell, J.: J. Chem. Eng. Data 55 (2010) 5449–5452.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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