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Diffusion coefficient of chlorobenzene in bromobenzene at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of chlorobenzene in bromobenzene at infinite dilution for various temperature and pressure conditions measured using diaphragm cell, correlation of experimental data and interferometry.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C6 H5 Cl

(1)

chlorobenzene

108-90-7

C6 H5 Br

(2)

bromobenzene

108-86-1

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [2012B2]

T [K]

Type

D ⋅ 109 [m2/s]

 

283.15

D 0 1(2)

1.01

 

283.15

D 0 2(1)

1.31

 

298.15

D 0 1(2)

1.33

 

298.15

D 0 2(1)

1.72

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [2001L3]

T [K]

Type

D ⋅ 109 [m2/s]

 

299.93

D 0 1(2)

1.330

 

299.93

D 0 2(1)

1.720

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: DIA

Ref.: [1962B3]

T [K]

Type

D ⋅ 109 [m2/s]

 

302.75 ± 0.03

D 0 1(2)

1.36 ± 2%

 

302.75 ± 0.03

D 0 2(1)

1.76 ± 2%

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: MZ-INT

Ref.: [1969K3]

T [K]

Type

D ⋅ 109 [m2/s]

 

303.15 ± 0.03

D 0 1(2)

1.36

 

303.15 ± 0.03

D 0 2(1)

1.76

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

INT

interferometry

DIA

diaphragm cell

CORR

correlation of experimental data

References

  1. [1962B3]
    Burchard, J. K., Toor, H. L.: J. Phys. Chem. 66 (1962) 2015–2022.CrossRefGoogle Scholar
  2. [1969K3]
    Kett, T. K., Anderson, D. K.: J. Phys. Chem. 73 (1969) 1268–1275.CrossRefGoogle Scholar
  3. [2001L3]
    Li J., Liu, H., Hu, Y.: Fluid Phase Equilibria 187188 (2001) 193–208.CrossRefGoogle Scholar
  4. [2012B2]
    Beigzadeh R., Rahimi, M., Shabanian, S. R.: Fluid Phase Equilib. 331 (2012) 48–57.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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