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Diffusion coefficient of propan-2-one in trichloro-methane at infinite dilution

  • Jochen Winkelmann
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of propan-2-one in trichloro-methane at infinite dilution for various temperature and pressure conditions measured using correlation of experimental data and diaphragm cell.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C3 H6 O

(1)

propan-2-one

67-64-1

C H Cl3

(2)

trichloro-methane

67-66-3

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [2012B2]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

2.34

 

298.15

D 0 2(1)

3.62

 

313.15

D 0 1(2)

2.92

 

313.15

D 0 2(1)

4.33

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [2001L3]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

2.350

 

298.15

D 0 2(1)

3.620

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: DIA

Ref.: [1971R2]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15 ± 0.05

D 0 1(2)

2.34

 

313.15 ± 0.05

D 0 1(2)

2.88

 

298.15 ± 0.05

D 0 2(1)

3.63

 

313.15 ± 0.05

D 0 2(1)

4.31

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

DIA

diaphragm cell

CORR

correlation of experimental data

References

  1. [1971R2]
    Ratcliff, G. A., Lusis, M. A.: I & EC Fundamentals 10 (1971) 474–477.CrossRefGoogle Scholar
  2. [2001L3]
    Li J., Liu, H., Hu, Y.: Fluid Phase Equilibria 187188 (2001) 193–208.CrossRefGoogle Scholar
  3. [2012B2]
    Beigzadeh R., Rahimi, M., Shabanian, S. R.: Fluid Phase Equilib. 331 (2012) 48–57.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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