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Diffusion coefficient of methanol in toluene at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of methanol in toluene at infinite dilution for various temperature and pressure conditions measured using diaphragm cell and Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C H4 O

(1)

methanol

67-56-1

C7 H8

(2)

toluene

108-88-3

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: DIA

Ref.: [1967S7]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15 ± 0.01

D 0 1(2)

3.620 ± 0.5%

 

298.15 ± 0.01

D 0 2(1)

2.560 ± 0.5%

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: DIA

Ref.: [1984E7]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15

D 0 1(2)

3.99 ± 1%

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: DIA

Ref.: [1991R2]

T [K]

Type

D ⋅ 109 [m2/s]

 

301 ± 0.5

D 0 2(1)

1.374

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1997R5]

T [K]

Type

D ⋅ 109 [m2/s]

 

313.15

D 0 1(2)

3.283 ± 1%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

TAYLOR

Taylor dispersion technique

DIA

diaphragm cell

References

  1. [1967S7]
    Shemilt, L.W., Nagarajan, R.: Canad. J. Chem. 45 (1967) 1143–1148.CrossRefGoogle Scholar
  2. [1984E7]
    Easteal, A. J., Woolf, L. A.: J. Chem. Soc., Faraday Trans. I 80 (1984) 1287–1295.Google Scholar
  3. [1991R2]
    Ramprasad, G., Das, T. R., Mukherjee, A. K.: J. Chem. Eng. Jpn. 24 (1991) 389–391.CrossRefGoogle Scholar
  4. [1997R5]
    Rowley, R. L., Adams, M. E., Marshall, T. L., Oscarson, J. L., Wilding, W. V., Anderson, D. J.: J. Chem. Eng. Data 42 (1997) 310–317.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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