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Diffusion coefficient of methanol in benzene at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of methanol in benzene at infinite dilution for various temperature and pressure conditions measured using diaphragm cell, correlation of experimental data and Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C H4 O

(1)

methanol

67-56-1

C6 H6

(2)

benzene

71-43-2

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [2012B2]

T [K]

Type

D ⋅ 109 [m2/s]

 

293.15

D 0 1(2)

3.80

 

293.15

D 0 2(1)

2.45

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: CORR

Ref.: [2001L3]

T [K]

Type

D ⋅ 109 [m2/s]

 

293.15

D 0 1(2)

3.700

 

293.15

D 0 2(1)

2.500

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: DIA

Ref.: [1967S7]

T [K]

Type

D ⋅ 109 [m2/s]

 

300.15

D 0 1(2)

4.400

 

300.15

D 0 2(1)

2.760

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1997R5]

T [K]

Type

D ⋅ 109 [m2/s]

 

313.15

D 0 1(2)

3.054 ± 1%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

TAYLOR

Taylor dispersion technique

DIA

diaphragm cell

CORR

correlation of experimental data

References

  1. [1967S7]
    Shemilt, L.W., Nagarajan, R.: Canad. J. Chem. 45 (1967) 1143–1148.CrossRefGoogle Scholar
  2. [1997R5]
    Rowley, R. L., Adams, M. E., Marshall, T. L., Oscarson, J. L., Wilding, W. V., Anderson, D. J.: J. Chem. Eng. Data 42 (1997) 310–317.CrossRefGoogle Scholar
  3. [2001L3]
    Li J., Liu, H., Hu, Y.: Fluid Phase Equilibria 187188 (2001) 193–208.CrossRefGoogle Scholar
  4. [2012B2]
    Beigzadeh R., Rahimi, M., Shabanian, S. R.: Fluid Phase Equilib. 331 (2012) 48–57.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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