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Diffusion coefficient of methanol-d in methanol-d4 at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of methanol-d in methanol-d4 at infinite dilution for various temperature and pressure conditions measured using NMR spin echo pulse gradient.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C H3 D O

(1)

methanol-d

1455-13-6

C D4 O

(2)

methanol-d4

811-98-3

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: NMR PG

Ref.: [1996H9]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15 ± 0.1

D 0 1(2)

2.15 ± 1.0%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

NMR PG

NMR spin echo pulse gradient

References

  1. [1996H9]
    Holz, M., Mao, X., Seiferling, D., Sacco, A.: J. Chem. Phys. 104 (1996) 669–679.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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