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Diffusion coefficient of tetrachloro-methane in acetonitrile at infinite dilution

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of tetrachloro-methane in acetonitrile at infinite dilution for various temperature and pressure conditions measured using interferometry, Gouy interferometry and Taylor dispersion technique.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.2. Diffusion in Binary Mixtures at Infinite Dilution

C Cl4

(1)

tetrachloro-methane

56-23-5

C2 H3 N

(2)

acetonitrile

75-05-8

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1985Y1]

T [K]

Type

D ⋅ 109 [m2/s]

 

301.2 ± 0.1

D 0 1(2)

3.37 ± 0.04

 

313.2 ± 0.1

D 0 1(2)

3.89 ± 0.09

 

328.2 ± 0.1

D 0 1(2)

4.57 ± 0.03

 

343.2 ± 0.1

D 0 1(2)

5.28 ± 0.04

 

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: TAYLOR

Ref.: [1979E2]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15 ± 0.01

D 0 1(2)

3.32

 

Comment: data are identical to those in [1981E2]

Diffusion Coefficient at infinite dilution: p = 101.325 kPa; Method: G-INT

Ref.: [1977E3]

T [K]

Type

D ⋅ 109 [m2/s]

 

298.15 ± 0.01

D 0 1(2)

3.32

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

TAYLOR

Taylor dispersion technique

INT

interferometry

G-INT

Gouy interferometry

References

  1. [1977E3]
    Evans, D. F., Chan, C., Lamartine, B. C.: J. Am. Chem. Soc. 99 (1977) 6492.CrossRefGoogle Scholar
  2. [1979E2]
    Evans, D. F., Tominaga, T., Chan, C.: J. Solution Chem. 8 (1979) 461–478.CrossRefGoogle Scholar
  3. [1981E2]
    Evans, D. F., Tominaga, T., Davis, H. T.: J. Chem. Phys. 74 (1981) 1298–1305.CrossRefGoogle Scholar
  4. [1985Y1]
    Yumet, E., Chen, H.-C., Chen, S.-H.: AIChE J. 31 (1985) 76–81.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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