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Diffusion coefficient of acetonitrile in trichloro-methane

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of acetonitrile in trichloro-methane at different concentrations measured using diaphragm cell.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C2 H3 N

(1)

acetonitrile

75-05-8

C H Cl3

(2)

trichloro-methane

67-66-3

Intradiffusion Coefficient: D1T (x i ); T = 298.15 K; Method: No Info

Ref.: [2011A1]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.00

101.32

2.24

 

0.03

101.32

2.59

 

0.100

101.32

2.65

 

0.150

101.32

2.60

 

0.300

101.32

2.67

 

0.500

101.32

2.89

 

0.700

101.32

3.28

 

1.00

101.32

4.04

 

Comment: data extracted from graphics

Intradiffusion Coefficient: D2T (x i ); T = 298.15 K; Method: No Info

Ref.: [2011A1]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.00

101.32

2.45

 

0.03

101.32

2.41

 

0.100

101.32

2.39

 

0.150

101.32

2.33

 

0.300

101.32

2.34

 

0.500

101.32

2.43

 

0.700

101.32

2.69

 

Comment: data extracted from graphics

Intradiffusion Coefficient: D2T (T); Method: DIA

Ref.: [1984E7]

T [K]

p [kPa]

D ⋅ 109 [m2/s]

 

298.15

101.32

3.39 ± 1%

 

Comment: values at trace concentration of 3H labelled component (2)

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

No Info

no information on method used

DIA

diaphragm cell

x i

mole fraction

References

  1. [1984E7]
    Easteal, A. J., Woolf, L. A.: J. Chem. Soc., Faraday Trans. I 80 (1984) 1287–1295.CrossRefGoogle Scholar
  2. [2011A1]
    Arkhipov V. P.: Russ. J. Phys. Chem. A 85 (2011) 423–426.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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