Advertisement

Diffusion coefficient of anthracene in acetonitrile

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of anthracene in acetonitrile at different concentrations measured using rotating disk electrode, chronopotentiometry and open ended capillary.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C14 H10

(1)

anthracene

120-12-7

C2 H3 N

(2)

acetonitrile

75-05-8

Intradiffusion Coefficient: D1T (c1); T = 298.15 ± 0.1 K; Method: OEC

Ref.: [1965M6]

c1 [mol/L]

p [kPa]

D ⋅ 109 [m2/s]

 

0.001

101.32

2.55 ± 5%

 

0.001

101.32

2.65*

 

0.001

101.32

6.6**

 

Comment: solution contains 0.1 M tetraethylammonium perchlorate; *: obtained by EA RDE; **: measured by EA Ch

Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

OEC

open ended capillary

EA RDE

electroanalytical methods:rotating disk electrode

EA Ch

electroanalytical methods:chronopotentiometry

c i

molarity

References

  1. [1965M6]
    Miller, T. A., Prater, B., Lee, J. K., Adams, R. N.: J. Am. Chem. Soc. 87 (1965) 121–122.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

Personalised recommendations