Physics of Solid Surfaces pp 895-895 | Cite as
Hydrohalic acid anion interaction with silver surfaces: Ag(110) – chloride, bromide, and iodide
Abstract
In this chapter the experimental results on adsorption of chloride, bromide and iodide on Ag(110) surface is described.
UHV-based AES, XPS, LEED, and thermal desorption spectroscopy (TDS) measurements are described in [1, 4]. Only one TDS peak is found for all three halides and shows very similar adsorption/desorption characteristics. LEED reveals a p(2 × 1) → c(4 × 2) phase transition. While the most stable adsorption sites of chlorine on Ag(100) and Ag(111) are the hollow sites, the most stable site of all three halides on Ag(110) is the short-bridge site as concluded from DFT calculations [1, 2, 3, 4, 5].
| Short form | Full form |
|---|---|
| LEED | low-energy electron diffraction |
| XPS | X-ray photoelectron spectroscopy |
| UHV | ultrahigh vacuum |
| AES | Auger electron spectroscopy |
| TDS | thermal desorption spectroscopy |
References
- 1.Hinzert, H., Kleinherbers, K.K., Janssen, E., Goldmann, A.: Appl. Phys. A Mater. Sci. Process. 49, 313 (1989)ADSCrossRefGoogle Scholar
- 2.Wang, Y., Sun, Q., Fan, K., Deng, J.: Chem. Phys. Lett. 334, 411 (2001)ADSCrossRefGoogle Scholar
- 3.Fui, H., Jia, L., Wang, W., Fan, K.: Surf. Sci. 584, 187 (2005)ADSCrossRefGoogle Scholar
- 4.Bange, K., Strehler, B., Sass, J.K.: J. Electroanal. Chem. Interfacial Chem. 229, 87 (1987)CrossRefGoogle Scholar
- 5.Tang, H.-R., Wang, W.-N., Li, Z.-H., Dai, W.-L., Fan, K.-N., Dang, J.-F.: Surf. Sci. 450, 133 (2000)ADSCrossRefGoogle Scholar