Thermodynamic Information from Ion-Molecule Equilibrium Constant Determinations

  • Sharon G. Lias
Chapter
Part of the Lecture Notes in Chemistry book series (LNC, volume 7)

Abstract

According to the principles of thermodynamics, the equilibrium constant of any chemical equilibrium gives information about the thermochemistry of the chemical reactions in the forward and reverse directions:
$$ - RT\ln {K_{eq}} = \Delta {G^o} = \Delta {H^o} - T\Delta {S^o}$$
(I)
Equation I has been applied extensively to the derivation of thermochemical information, particularly in the liquid phase.

Keywords

Partition Function Entropy Change Proton Affinity Proton Transfer Reaction Transfer Equilibrium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Springer-Verlag Berlin Heidelberg 1978

Authors and Affiliations

  • Sharon G. Lias
    • 1
  1. 1.Institute for Materials ResearchNational Bureau of StandardsUSA

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