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A New Polyparaphenylene Thin Film Obtained by Electroreduction: Characterization and Electrochemical Studies

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Electronic Properties of Conjugated Polymers

Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 76))

Abstract

Polyparaphenylene (PPP) is one of the most attractive conducting polymers as it shows a non-degenerate ground state. Much work has been done on this polymer in the last few years /1/ but it was carried out on either powder form polymer /2/ or films obtained by electrooxidation methods /3/. We have recently succeeded in forming PPP film onto various substrates by using electrochemical reduction of 1,4-dibromobiphenyl in the presence of a nickel complex /4/.

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References

  1. See Proceedings of the ICSM′86 KYOTO in Synthetic Metals, Vol. 17-18 (1987)

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  2. P. Kovacic and J. Oziomek, Macromol. Syntheses, Vol. 2, J. Wiley (New-York 1966), p. 23 T. Yamamoto, Y. Hayashi, A. Yamamoto, Bull. Chem. Soc. Japan 51, 2091 (1978)

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  3. M. Tabata, M. Satoh, K. Kaneto, K. Yoshino, J. Phys. C, Solid State Phys. 19, L 101 (1986)

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  4. J.F. Fauvarque, M.A. Petit, A. Digua, G. Froyer, Makromol. Chem., accepted for publication

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  5. G. Froyer, F. Maurice, J.P. Mercier, D. Rivière, M. Le Cun and P. Auvray, Polymer 22, 992 (1981)

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  6. S. Krichene, S. Lefrant, Y. Pelous, G. Froyer, M. Petit, A. Digua, J.F. Fauvarque, Synthetic Metals, 17, 607 (1987)

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  7. J. Rault, Dissertation, Rennes (1986)

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  8. G. Froyer, Y. Pelous, F. Maurice, M.A. Petit, A. Digua, J.F. Fauvarque, to appear in Synthetic Metals.

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Author information

Authors and Affiliations

  1. C.N.E.T., LAB/ROC/TIC, BP 40, F-22301, Lannion, Cedex, France

    G. Froyer, Y. Pelous & G. Ollivier

Authors
  1. G. Froyer
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  2. Y. Pelous
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  3. G. Ollivier
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Editor information

Editors and Affiliations

  1. Institut für Festkörperphysik, Universität Wien, Strudlhofgasse 4, A-1090, Wien, Austria

    Hans Kuzmany

  2. Ludwig Boltzmann Institut für Festkörperphysik, Wien, Kopernikusgasse 15, A-1090, Wien, Austria

    Hans Kuzmany

  3. Physikalisches Institut II, Universität Stuttgart, Pfaffenwaldring 57, D-7000, Stuttgart 80, Fed. Rep. of Germany

    Michael Mehring

  4. Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, D-7000, Stuttgart 80, Fed. Rep. of Germany

    Siegmar Roth

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© 1987 Springer-Verlag Berlin Heidelberg

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Froyer, G., Pelous, Y., Ollivier, G. (1987). A New Polyparaphenylene Thin Film Obtained by Electroreduction: Characterization and Electrochemical Studies. In: Kuzmany, H., Mehring, M., Roth, S. (eds) Electronic Properties of Conjugated Polymers. Springer Series in Solid-State Sciences, vol 76. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-83284-0_56

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  • DOI: https://doi.org/10.1007/978-3-642-83284-0_56

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-83286-4

  • Online ISBN: 978-3-642-83284-0

  • eBook Packages: Springer Book Archive

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