Influence of Molecular Parameters on Laminar Non-Newtonian and on Turbulent Flows of Dilute Polymer Solutions
Conference paper
Summary
We show that the hydrodynamic radius of Poly(ethyleneoxide) macromolecules may be very different in water and water-isopropanol mixture (90%/10%). This dimension is a function of the age of the solution in pure water. The influence of the solvent and the age (i.e. of the hydrodynamic radius-) on the properties in laminar and turbulent flows is studied.
Keywords
Shear Rate Drag Reduction Hydrodynamic Radius Specific Viscosity Dilute Polymer Solution
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
Preview
Unable to display preview. Download preview PDF.
Bibliography
- 1.Cuniberti, C.: Evidence for aggregation of Poly(ethyleneoxide). Polymer 16 (1975) 306–307CrossRefGoogle Scholar
- 2.Carpenter, D.K.; Santiago, G.; Hunt, A.H.: Aggregation of polyexyethylene in dilute solution. J. Polym. Sci., Polym. Symp. 44 (1974) 75–92CrossRefGoogle Scholar
- 3.Güner, A.; Güven, O.: Molecular association in aqueous solutions of high molecular weight poly(ethyleneoxide). Makromol.Chem. 179 (1978) 2789–2791CrossRefGoogle Scholar
- 4.Bailey, F.E., Jr.; Koleske, J.V.: Poly(ethylene oxide), Acad.press N.Y. (1976)Google Scholar
- 5.Shin, H.: PhD Thesis. Reduction of drag in turbulence by dilute polymer solutions. MIT (1965)Google Scholar
- 6.Mc Gary, C.W.jr.: Degradation of Poly(ethylene oxide)/J. Polym.Sci. XLVI (1960) 51–57Google Scholar
- 7.Bortel, E.; Lamot, R.: Untersuchung des Abbaus hochmolecularer Polyäthylenoxide. Makromol. Chem. 178 (1977) 2617–2628CrossRefGoogle Scholar
- 8.Barnard, B.J.S.; Sellin, R.H.J.: Degradation of dilute solutions of drag reducing polymers. Nature Phys. Sci. 236 (1972) 12–14Google Scholar
- 9.Ting, R.Y.; Little, R.C.: Characterization of drag reduction and degradation effects in the turbulent pipe flow of dilute polymer solutions. J. Applied Polym. Sci. 17 (1973) 3345–3356CrossRefGoogle Scholar
- 10.Fisher, D.H.; Rodriguez, F.: Degradation of drag reducing polymers. J. Appl. Polym. Sci 15 (1971) 2975–2985CrossRefGoogle Scholar
- 11.Kenis, P.R.: Turbulent flow friction reduction and hydrodynamic degradation of polysaccharides and synthetic polymers. J. Appl. Polym. Sci. 15 (1971) 607CrossRefGoogle Scholar
- 12.Gold, P.I.; Amar, P.K.; Swaidan, B.E.: Friction reduction degradation in dilute PEO solutions. J. Appl. Polym. Sci. 17 (1973) 333CrossRefGoogle Scholar
- 13.Hinch, E.J.; Elata, C.;: Heterogeneity of dilute polymer solutions. J. N. N. Fl. Mech. 5 (1979) 411–425CrossRefGoogle Scholar
- 14.Dunlop, E.H.; Cox, L.R.: Role of molecular aggregates in liquid drag reduction by polymers. Phys. of Fluids 20–10 (II) (1977) S203CrossRefADSGoogle Scholar
- 15:.Laufer, Z.; Jalink, H.L.; Staverman, A.J.: J. Polym. Sci.; Polym. Chem. Ed. 11 (1973) 3005Google Scholar
- 16.Gadd, G.E.: Effect of drag reducing additives on vortex stretching. Nature 217 (1968) 1040–1042CrossRefADSGoogle Scholar
- 17.Layec Y.: to be publishedGoogle Scholar
- 18.Koppel, D.E.: Analysis of Macromolecular polydispersity in intensity correlation spectroscopy: the method of cumulants. J. Chem. Phys. 57 (1972) 4814–4820CrossRefADSGoogle Scholar
- 19.Layec-Raphalen, M.N.; Wolff, C.: On the shear thickening behaviour of dilute solutions of chain macromolecules. J. N. N. Fl. Mech. 1 (1976) 159–176CrossRefGoogle Scholar
- 20.Kato, T.; Nakamura, K.; Kawaguchi, M.; Takahashi, A.: Polym. J. 13–11 (1981) 1037Google Scholar
- 21.Layec, Y.; Layec-Raphalen, M.N.: Instability of dilute poly(ethyleneoxide) solutions. J. Phys. Lett. 44 (1983) L121 - L128CrossRefGoogle Scholar
- 22.Yamakawa, H.: Modern theory of polymer solutions. New-York, Harper et Row 1971Google Scholar
- 23.Flory, P.J.: Principles in polymer chemistry. New York, Cornell Univ. press 1963Google Scholar
- 24.Chauveteau, G.; Ghoniem, S.; Moan, M.: Effet del’entrée sur les écoulements laminaires de solutions de polymère. C. R. Acad. Sci. (Paris)Google Scholar
- 25.Ouibrahim, A.; Fruman, D.H.: Characteristics of HPAM dilute polymer solutions in three elongational flow situations. J. N. N. F1. Mech. 7–4 (1980) 315–332Google Scholar
- 26.Ambari, A.: Ecoulement des solutions aqueuses diluées de polyoxyethylene dans une fente rectangulaire très allongée en mince paroi. C.R. Acad. Sci. (Paris) 289 (1979) 1–4Google Scholar
- 27.Layec-Raphalen, M.N.; Wolff, C.: Shear rate dependence of the association of high molecular weight macromolecules in dilute solution. Rheology, Vol. 2, 303-, Ed. G. Astarita et al., Plenum Press, 1980Google Scholar
- 28.Wolff, C.: Comparaison des courbes de viscosité intrinsèque non-newtonienne obtenues avec différents types de polymères. J. Phys. 32 (1971) 263Google Scholar
Copyright information
© Springer, Berlin Heidelberg 1985