Dynamical Linewidth Effects of Hole Burning of Free Base Phthalocyanine in Polymers: Spectral Diffusion and Exchange Narrowing

  • A. Gutierrez
  • G. Castro
  • G. Schulte
  • D. Haarer
Conference paper
Part of the Springer Series in Solid-State Sciences book series (SSSOL, volume 49)

Abstract

The temperature dependence of the hole burning linewidth of free base phthalocyanine is investigated in polystyrene (PS) and polyethylene (PE) matrices. The linewidth in both polymers differs by more than a factor of 10. The temperature dependence in PS can be explained with theories which are applicable to other amorphous systems. The temperature dependence in PE shows, in a limited temperature range, an increase of linewidth with falling temperature, which we attribute to motional effects.

Keywords

Hole Burning Spectral Diffusion Limited Temperature Range Hole Width Dephasing Process 
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Copyright information

© Springer-Verlag Berlin Heidelberg 1983

Authors and Affiliations

  • A. Gutierrez
    • 1
  • G. Castro
    • 1
  • G. Schulte
    • 2
  • D. Haarer
    • 2
  1. 1.IBM Research LaboratorySan JoseUSA
  2. 2.Physikalisches InstitutUniversität BayreuthBayreuthFed. Rep. of Germany

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