Relationship between NMR 29Si Chemical Shifts and FT-IR Wave Numbers in Calcium Silicates

  • Yoshihiko Okada
  • Tsuguya Masuda
  • Minori Takada
  • Lingling Xu
  • Takeshi Mitsuda
Conference paper

Abstract

The relationship between 29Si NMR (chemical shift values), and IR (wave numbers) results is discussed as far as calcium silicates are concerned. This relation shows a good correlation with R = 0.86 for the hydrates and 0.99 for the anhydrates. The results indicate that the higher the polymerization or condensation of silicate tetrahedra the higher the IR wave number and the lower the NMR chemical shift value.

Keywords

29Si NMR chemical shift infrared spectroscopy calcium silicate correlation 
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References

  1. 1.
    Ishida H, Mabuchi S, Sasaki K, Mitsuda T (1992) J Am Ceram Soc 75: 2427CrossRefGoogle Scholar
  2. 2.
    Ishida H, Yamazaki S, Sasaki K, Okada Y, Mitsuda T (1993) J Am Ceram Soc 76: 1707CrossRefGoogle Scholar
  3. 3.
    Okada Y, Ishida H, Mitsuda T (1994) J Am Ceram Soc 77: 2277CrossRefGoogle Scholar
  4. 4.
    Lippmaa E, Mägi M, Samoson A, Tarmak M, Engelhardt G, Grimmer AR (1980) J Am Chem Soc 102: 4889CrossRefGoogle Scholar
  5. 5.
    Okada Y, Ishida H, Mitsuda T (1994) J Am Ceram Soc 77: 765CrossRefGoogle Scholar
  6. 6.
    Okada Y, Sasaki K, Ishida H, Mitsuda T (1993) Ceramic Transactions 37: 11Google Scholar
  7. 7.
    Wieker W, Grimmer AR, Winkler A, Mägi M, Tarmak M, Lippmaa E (1982) Cern Concr Res 12: 333CrossRefGoogle Scholar
  8. 8.
    Okada Y, Fang Y, Ishida H, Nishido H (1994) J Ceram Soc Japan 102: 449CrossRefGoogle Scholar
  9. 9.
    Okada Y, Masuda T, Ishida H, Nishido H (1994) J Ceram Soc Japan 102: 919CrossRefGoogle Scholar
  10. 10.
    Engelhardt G, Zeigan Z, Hoebbel H, Wieker W(1975) Z Anorg Chem 418: 17CrossRefGoogle Scholar
  11. 11.
    Nyquist RA (1986) In: IR and NMR Spectra Data-Structure Correlation for the Carbonyl Group. Sadtler/Sanyo, Tokyo, p. 102Google Scholar
  12. 12.
    Smith KA, Kirkpatrick RJ, Oldfield E, Henderson DM (1983) Amer Mineral 68: 1206Google Scholar
  13. 13.
    Grimmer AR, Fechner E, Peter R, Molgedey G (1981) Chem Phys Letters 77: 331CrossRefGoogle Scholar
  14. 14.
    Henning O (1974) In: Farmer VC (ed) The Infrared Spectra of Minerals. Mineralogical Society, London, p. 445Google Scholar
  15. 15.
    Bensted J, Prakash S (1974) Cem Technology Sep/Oct: 440Google Scholar
  16. 16.
    Bensted J, Prakash S (1974) Cem Technology July/Aug: 378Google Scholar
  17. 17.
    Bell G, Bensted J, Glasser FP (1989) Advan Cem Res 2: 61Google Scholar
  18. 18.
    Rao CNR (1963) In: ChemicalApplication of Infrared Spectroscopy.Academic Press, New York, p. 8Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1998

Authors and Affiliations

  • Yoshihiko Okada
    • 1
  • Tsuguya Masuda
    • 1
  • Minori Takada
    • 1
  • Lingling Xu
    • 2
  • Takeshi Mitsuda
    • 3
  1. 1.Central Research LaboratoryChichibu Onoda Cement Corp.Sakura, 285Japan
  2. 2.Department of Materials Science and EngineeringNanjing University of Chemical TechnologyNanjingChina
  3. 3.Nagoya Institute of TechnologyGokiso, Showa, Nagoya, 466Japan

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