Peterson Reaction

  • William P. Weber
Chapter
Part of the Reactivity and Structure Concepts in Organic Chemistry book series (REACTIVITY, volume 14)

Abstract

The Silyl-Wittig or Peterson reaction involves addition of a stoichiometric quantity of an α-silyl carbanion to the carbonyl group of a ketone or aldehyde. This yields a β-silyl alkoxide which decomposes by alkoxide attack on silicon to yield an alkene and a silanoate. The ease of this decomposition is dependent on the cation. Potassium and sodium alkoxides decompose far more readily than the more covalent magnesium alkoxides [1].

Keywords

Grignard Reagent Trimethylsilyl Group Magnesium Bromide Vinyl Silane Vinyl Sulfide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Springer-Verlag Berlin Heidelberg 1983

Authors and Affiliations

  • William P. Weber
    • 1
  1. 1.Department of ChemistryUniversity of Southern CaliforniaUniversity Park, Los AngelesUSA

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