Fundamentals of Chromatography

  • Heinz Engelhardt
Part of the Chemical Laboratory Practice book series (CHEMICAL LABORA)

Abstract

The elution-chromatographic separation of two substances on a column can be likened to a steeple chase in that the time required for the substances to reach the end of the column depends on their retardation by the obstacles (the degree of retention by the stationary phase). The substances differ only in the time spent in or on the stationary phase) i.e., their net retention times t R are different. The total retention time tR consists of this net retention time in the stationary phase and the time spent in the mobile phase t0, also called the dead time.

Keywords

Volume Flow Rate Retention Volume Column Length Plate Number Band Spreading 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References Chapter II

  1. 1.
    Anderson, J.R.: J. Am. Chem. Soc. 78, 5692 (1956)CrossRefGoogle Scholar
  2. 2.
    Kelker, H.: Ber. Bunsenges. 77, 187 (1973)Google Scholar
  3. 3.
    Caxman, P.C.: Flow of Gases through Porous Media. London: Butterworth 1956Google Scholar
  4. 4.
    Bohemen, J., Purnell, J.H.: J. Chem. Soc., London 1961, 360Google Scholar
  5. 5.
    Deninger, G.: Ber. Bunsenges. 77, 145 (1973)Google Scholar
  6. 6.
    Halász, I.: Ber. Bunsenges. 77, 140 (1973)Google Scholar
  7. 7.
    Endele, R., Halász, I., Unger, K.: J. Chromatogr. 99, 377 (1974)CrossRefGoogle Scholar
  8. 8.
    Halász, I., Naefe, M.: Anal. Chem. 44, 76 (1972)CrossRefGoogle Scholar
  9. 9.
    Giddings, J.C.: Dynamics of Chromatography. New York: Marcel Dekker 1965Google Scholar
  10. 10.
    Littlewood, A.B.: Gas Chromatography, 2nd ed. New York: Academic Press 1970Google Scholar
  11. 11.
    Halász, I. in: Kirkland, J.J. (Ed.): Modern Practice of Liquid Chromatography. New York: Wiley Interscience 1971Google Scholar
  12. 12.
    Desty, D.H., Goldup, A., Swanton, W.T., in: Brenner, N., Gallen, J.E., Weiss, M.D. (Eds.): Gas Chromatography, New York: Academic Press 1962Google Scholar
  13. 13.
    Purnell, J.H.: J. Chem. Soc., London 1960, 1268Google Scholar
  14. 14.
    van Deemter, J.J., Zuiderweg, F.J., Klinkenberg, A.: Chem. Engng. Sci. 5, 271 (1956)CrossRefGoogle Scholar
  15. 15.
    Halász, I., Horvath, C.: Anal. Chem. 36, 1179 (1964)Google Scholar
  16. 16.
    Endele, R.: Dissertation, Saarbrücken 1974Google Scholar
  17. 17.
    Snyder, L.R.: J. Chromatogr. Sci. 7, 352 (1969)Google Scholar
  18. 18.
    Waters, J.L., Little, J.N., Horgan, D.F.: J. Chromatogr. Sci. 7, 293 (1969)Google Scholar
  19. 19.
    Halász, I., Kroneisen, A., Gerlach, H.O., Walkling, P.: Z. anal. Chem. 234, 81 (1968)CrossRefGoogle Scholar
  20. 20.
    Halász, I., Kroneisen, A., Gerlach, H.O., Walkling, P.: Z. anal. Chem. 234, 97 (1968)CrossRefGoogle Scholar
  21. 21.
    Halász, I., Walkling, P.: Ber. Bunsenges. 74, 66 (1970)Google Scholar
  22. 22.
    Deininger, G., Halász, I.: J. Chromatogr. Sci. 9, 83 (1971)Google Scholar
  23. 23.
    Halász, I., Heine, E., in: Purneil, J.H. (Ed.): Progress in Gas Chromatography. New York: Interscience 1968Google Scholar
  24. 24.
    Halász, I., Aßhauer, J., Endele, R.: J. Chromatogr. 112, 37 (1975)CrossRefGoogle Scholar
  25. 25.
    Kennedy, G.J., Knox, J.H.: J. Chromatogr. Sci. 10, 549 (1972)Google Scholar
  26. 26.
    Knox, J.H., Vasvari, J.: J. Chromatogr. 83, 181 (1973)CrossRefGoogle Scholar
  27. 27.
    Knox, J.H., Pryde, A.: J. Chromatogr. 112, 171 (1975)CrossRefGoogle Scholar
  28. 28.
    Knox, J.H., Jurand, J., Luird, G.R.: Proc. Soc. Anal. Chem. 1974, 310Google Scholar
  29. 29.
    Knox, J.H., Saleem, M.: J. Chromatogr. Sci. 7, 614 (1969)Google Scholar
  30. 30.
    Majors, R.: J. Chromatogr. Sci. 11, 88 (1973)Google Scholar
  31. 31.
    Kirkland, J.J.: J. Chromatogr. Sci. 10, 129 (1972)Google Scholar
  32. 32.
    Halász, I.: Z. Anal. Chem. 277, 257 (1975)CrossRefGoogle Scholar
  33. 33.
    Golay, M.J.E., in: Desty, D.H., (Ed.): Gas Chromatography 1958. London: Butterworth 1958. S. 36 ff.Google Scholar
  34. 34.
    Halász, I., Schmidt, H., Vogtel, P.: J. Chromatogr. 126, 19 (1976)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin · Heidelberg 1979

Authors and Affiliations

  • Heinz Engelhardt
    • 1
  1. 1.Angewandte Physikalische ChemieUniversität des SaarlandesSaarbrückenGermany

Personalised recommendations