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Electron Spectroscopy for Chemical Analysis (ESCA) — Basic Features and their Model Description

  • Zvonimir B. Maksić

Abstract

The conceptual framework of the inner-core binding energy shifts in molecules is considered. It is shown that the basic facets of electron spectroscopy for chemical analysis (ESCA) are well understood and can be interpreted by simple physical models based on classical electrostatics. This transparent and intuitively appealing approach provides a rationale for characteristic ESCA fingerprints of atoms in chemical environments and offers the underlying principle for empirical additivity of ESCA shifts exhibited by functional groups. The role of the final state after photoionization has been completed is discussed in extenso. Finally, the importance of ESCA in atomic charge analysis, determination of gas-phase acidities and basicities and its interplay with other spectroscopic techniques (PES, NMR, MW and Mössbauer) is briefly discussed.

Keywords

Proton Affinity Relaxation Energy Reorganization Energy Average Absolute Error Positive Hole 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin Heidelberg 1991

Authors and Affiliations

  • Zvonimir B. Maksić
    • 1
    • 2
  1. 1.Ruder Bošković InstituteTheoretical Chemistry GroupZagreb, CroatiaYugoslavia
  2. 2.Yugoslavia and Faculty of Natural Sciences and MathematicsUniversity of ZagrebZagreb, CroatiaYugoslavia

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