Coupled Processes in Electrolyte Solutions
Chapter
Abstract
There are various ways to treat irreversible thermodynamic processes in which electrolyte solutions exhibit coupled transport processes and chemical reactions. The phenomenological procedure chosen here is that of irreversible thermodynamics relating the flows to the underlying gradients. Strongly coupled relaxation processes evading the description by a set of one-particle equations will not be considered, such as the relaxation effect of electric migration and self-diffusion. The following treatment is based on sets of two-particle equations justified from first principles of statistical mechanics.
Keywords
Electrolyte Solution Couple Diffusion Laplace Transformation Normal Mode Analysis Mutual Diffusion
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© Springer-Verlag Berlin Heidelberg 1992