Porphyrins pp 636-636 | Cite as

Spectral data of nickel complex of porphyrin derivative C54H40N4Ni

  • R. Gupta
Part of the Molecules and Radicals book series (volume 32C1)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data, infrared data and UV-visible spectral data of nickel complex of porphyrin derivative C54H40N4Ni.

Spectral Studies

2.1. Spectral Data of Porphyrins: Tetraphenyl and Analogous Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks

Wave number

\( \tilde{v} \) [cm−1]

Solvent

Peaks

λ [nm]/(ε [M−1 cm−1]/log ε)

  

CDCl3

1 H NMR

1.13 (d, J = 6.9, 12H, 4CH3),

2.60-2.54 (m, 2H, 2CH),

7.69-7.58 (m, 12H, meso-ArH),

7.90-7.87 (m, 4H, meso-ArH),

7.99-7.96 (m, 4H, meso-ArH),

8.62 (d, J = 5.1, 2H, β-pyrrolic-H),

8.64 (d, J = 5.1, 2H, β-pyrrolic H),

8.67 (s, 2H, β-pyrrolic H)

3047, 2967,

2215, 1598,

1576, 1481,

1440, 1365,

1346, 1310,

1190, 1178,

1147, 1073,

1005, 947,

836, 794,

749, 716,

698

CH2Cl2

579

(0.87 × 10−4),

542

(1.86 × 10−4),

428

(25.09 × 10−4)

 

[11Nat]

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

References

  1. [11Nat]
    Nath, M., Pink, M., Zaleski, J.M.: J. Organomet. Chem. 696, 4152–4157 (2011)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • R. Gupta
    • 1
  1. 1.JaipurIndia

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