Porphyrins pp 588-589 | Cite as

Spectral data of nickel complex of porphyrin derivative C53H47BrN6NiPd

  • R. Gupta
Chapter
Part of the Molecules and Radicals book series (volume 32C1)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data and UV-visible spectral data of nickel complex of porphyrin derivative C53H47BrN6NiPd.

Spectral Studies

2.1. Spectral Data of Porphyrins: Tetraphenyl and Analogous Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks

Wave number

\( \tilde{v} \) [cm−1]

Solvent

Peaks

λ [nm]/(ε [M−1 cm−1]/log ε)

  

CDCl3

1 H NMR

2.60 (s, 3H, ArCH3),

2.62 (s, 6H, ArCH3),

3.06 (s, 12H, N(CH3)2),

4.10 (s, 4H, CH2N),

7.33 (s, 2H, ArHpincer),

7.44 (m, 6H, ArHp-tol),

7.88 (m, 6H, ArHp-tol),

8.72 (m, 8H, β-H)

13 C NMR

21.7, 54.1, 74.8, 119.1, 119.3, 125.5, 127.8, 132.1, 132.3, 132.4, 133.8, 133.9, 137.7, 138.2, 142.9, 143.0, 143.0, 143.0, 143.6, 157.1

 

CH2Cl2

418 (5.74),

530 (4.62)

orange solid

[10Sui]

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

References

  1. [10Sui]
    Suijkerbuijk, B.M.J.M., Schamhart, D.J., Kooijman, H., Spek, A.L., van Koten, G., Klein Gebbink, R.J.M.: Dalton Trans. 39, 6198–6216 (2010)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • R. Gupta
    • 1
  1. 1.JaipurIndia

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