Porphyrins pp 241-241 | Cite as
Spectral data of porphyrin derivative C46H38I3N7O2
Abstract
This chapter contains a tabular compilation of nuclear magnetic resonance data and UV-visible spectral data of porphyrin derivative C46H38I3N7O2.
Spectral Studies
2.1. Spectral Data of Porphyrins: Tetraphenyl and Analogous Porphyrins
Structure formula
NMR | IR | UV-visible | Remarks | Ref. | ||
---|---|---|---|---|---|---|
Solvent | Peaks δ [ppm]/nJ [Hz] | Peaks Wave number \( \tilde{v} \) [cm−1] | Solvent | Peaks λ [nm]/(ε [M−1 cm−1]/log ε) | ||
DMSO | 1 H NMR 1.30 (s, 3H, CH3), 4.72 (s, 9H, N+–Me), 7.65 (d, J = 8.45, 2H, 3,5-phenyl), 8.26 (d, J = 5.53, 2H, 2,6-phenyl), 9.00 (d, 6H, 3,5-pyridinium), 9.07 (s, 4H, β-pyrrole), 9.16 (s, 4H, β-pyrrole), 9.46 (d, J = 5.81, 6H, 2,6-pyridinium) | tris buffer | 422 (5.07), 520 (3.84), 562 (3.60), 583 (3.56), 642 (3.19) | [08Zha] |
Short Form | Full Form |
---|---|
NMR | nuclear magnetic resonance |
IR | infrared |
UV-Visible | ultraviolet–visible |
δ | chemical shift |
γ | absorption band |
λ | wavelength |
ε | molar absorptivity |
References
- [08Zha]Zhao, P., Xu, L.-C., Huang, J.-W., Zheng, K.-C., Fu, B., Yu, H.-C., Ji, L.-N.: Biophys. Chem. 135, 102–109 (2008)CrossRefGoogle Scholar