Abstract
The Thermo-oxidation engine Oil Simulation Test (TEOST 33C), one request of the new ILSAC GF-5 specification for passenger car, has been developed as a simulation test to evaluate the “coking” of engine oil in turbocharger. Generally, molybdenum dithiocarbamate (MoDTC) is added into engine oil as an effective friction modifier to improve fuel economy. Zinc dialkyldithiophosphate (ZnDDP) has also been used as a multifunction additive in engine oils for more than 50 years. However, the results of this study showed that the coexistence of MoDTC and ZnDDP in engine oil could cause deposits accretion of the oil in the TEOST 33C. Pressurized Differential Scanning Calorimetry (PDSC) revealed that excess MoDTC led to the oxidative degradation of engine oil and there was no obvious relationship between oxidation stability and “coking” of engine oil. In addition, the elemental analysis of deposits demonstrated that deposits accretion was not caused by the increase ash of MoDTC. In summary, the MoDTC coexisted with ZnDDP might be acted as a “coking” catalyst under high temperature.
F2012-A03-009
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References
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Acknowledgements
The authors would gratefully acknowledge the previous work of Satoru Yoshida and Yasushi Naitoh in research of TEOST 33C. Assistance from Wang aixiang and Xu jinbao is also acknowledged.
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Wang, L., Wang, L., Li, G. (2013). Analysis of Engine Oil Containing MoDTC on the Thermo-Oxidation Engine Oil Simulation Test (TEOST 33C). In: Proceedings of the FISITA 2012 World Automotive Congress. Lecture Notes in Electrical Engineering, vol 189. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-33841-0_35
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DOI: https://doi.org/10.1007/978-3-642-33841-0_35
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