Terahertz Spectroscopy of Crystalline and Non-Crystalline Solids

  • Edward P. J. Parrott
  • Bernd  M. Fischer
  • Lynn F. Gladden
  • J. Axel Zeitler
  • Peter U. Jepsen
Part of the Springer Series in Optical Sciences book series (SSOS, volume 171)


Terahertz spectroscopy of crystalline and non-crystalline solids is probably one of the most active research fields within the terahertz community. Many potential applications, amongst which spectral recognition is probably one of the most prominent, have significantly stimulated the development of commercial systems and have spurred an increased technical advancement. However, the topic is very complex and multifaceted. Therefore, it is beyond the scope of this chapter to provide a fully comprehensive review of the works performed in this area. We would rather like to demonstrate, based on some selected examples, the potential the technique holds for various different applications. A particular focus will be given to data analysis and, in particular, how we may account for effects resulting from non-ideal sample preparation.


  1. 1.
    G.W. Chantry, Submillimetre Spectroscopy—A Guide to the Theoretical and Experimental Physics of the Far Infrared Radiation (Academic Press, New York, 1971)Google Scholar
  2. 2.
    K.D. Möller, W.G. Rothschild, Far-Infrared Spectroscopy (Wiley, New York, 1971)Google Scholar
  3. 3.
    E.V. Loewenstein, D.R. Smith, R.L. Morgan, Appl. Opt. 12(2), 398 (1973)ADSCrossRefGoogle Scholar
  4. 4.
    M. Kerker, The scattering of light, and other electromagnetic radiation (Academic Press, New York, 1969)Google Scholar
  5. 5.
    H.C. van de Hulst, Light scattering by small particles (Dover Publications, New York, 1981)Google Scholar
  6. 6.
    C.F. Bohren, D.R. Huffman, Absorption and scattering of light by small particles (Wiley, New York, 1983)Google Scholar
  7. 7.
    G.M. Png, R.J. Falconer, B.M. Fischer, H.A. Zakaria, S.P. Mickan, A.P.J. Middelberg, D. Abbott, Opt. Express 17(15), 13102 (2009)ADSCrossRefGoogle Scholar
  8. 8.
    W. Withayachumnankul, B.M. Fischer, D. Abbott, Opt. Express 16(10), 7382 (2008)ADSCrossRefGoogle Scholar
  9. 9.
    M. Franz, B.M. Fischer, M. Walther, Appl. Phys. Lett. 92(2), 021107 (2008)ADSCrossRefGoogle Scholar
  10. 10.
    R. Barnes, L. Bonner, Phys. Rev. 49(10), 732 (1936)ADSCrossRefGoogle Scholar
  11. 11.
    C.V. Raman, Proc. Indian Acad. Sci. A 29, 381 (1949)Google Scholar
  12. 12.
    L. Duvillaret, F. Garet, J.L. Coutaz, Appl. Opt. 38(2), 409 (1999)ADSCrossRefGoogle Scholar
  13. 13.
    T.D. Dorney, R.G. Baraniuk, D.M. Mittleman, J. Opt. Soc. Am. A 18(7), 1562 (2001)ADSCrossRefGoogle Scholar
  14. 14.
    I. Pupeza, R. Wilk, M. Koch, Opt. Express 15(7), 4335 (2007)ADSCrossRefGoogle Scholar
  15. 15.
    R. Wilk, I. Pupeza, R. Cernat, M. Koch, IEEE J. Sel. Top. Quant. 14(2), 392 (2008)CrossRefGoogle Scholar
  16. 16.
    E.P.J. Parrott, J.A. Zeitler, L.F. Gladden, S.N. Taraskin, S.R. Elliott, J. Non-Cryst, Solids 355(37–42), 1824 (2009)Google Scholar
  17. 17.
    E.P.J. Parrott, J.A. Zeitler, G. Simon, B. Hehlen, L.F. Gladden, S.N. Taraskin, S.R. Elliott, Phys. Rev. B 82(14), 140203 (2010)ADSCrossRefGoogle Scholar
  18. 18.
    T.I. Jeon, J.H. Son, K.H. An, Y.H. Lee, Y.S. Lee, J. Appl. Phys. 98(3), 034316 (2005)ADSCrossRefGoogle Scholar
  19. 19.
    E.P.J. Parrott, J.A. Zeitler, J. McGregor, S.P. Oei, H.E. Unalan, S.C. Tan, W.I. Milne, J.P. Tessonnier, R. Schlögl, L.F. Gladden, J. Phys. Chem. C 113, 10554 (2009)CrossRefGoogle Scholar
  20. 20.
    E.P.J. Parrott, J.A. Zeitler, J. McGregor, S.P. Oei, H.E. Unalan, W.I. Milne, J.P. Tessonnier, D.S. Su, R. Schlögl, L.F. Gladden, Adv. Mater. 21(38–39), 3953 (2009)CrossRefGoogle Scholar
  21. 21.
    J.C.M. Garnett, Philos. T. R. Soc. Lond. 203(1), 385 (1904)ADSMATHCrossRefGoogle Scholar
  22. 22.
    D.A.G. Bruggeman, Ann. Phys. 416, 636 (1935)CrossRefGoogle Scholar
  23. 23.
    J.C.M. Garnett, Philos. T. R. Soc. Lond. 205(1), 237 (1906)ADSCrossRefGoogle Scholar
  24. 24.
    J.E. Spanier, I.P. Herman, Phys. Rev. B 61(15), 10437 (2000)ADSCrossRefGoogle Scholar
  25. 25.
    W. Fan, A. Burnett, P. Upadhya, J. Cunningham, E. Linfield, A. Davies, Appl. Spectrosc. 61(6), 638 (2007)ADSCrossRefGoogle Scholar
  26. 26.
    Y.C. Shen, P.C. Upadhya, E. Linfield, H. Beere, A. Davies, Appl. Phys. Lett. 83(15), 3117 (2003)Google Scholar
  27. 27.
    P.U. Jepsen, B. Fischer, Opt. Lett. 30(1), 29 (2005)Google Scholar
  28. 28.
    A. Markelz, A. Roitberg, E. Heilweil, Chem. Phys. Lett. 320(1–2), 42 (2000)ADSCrossRefGoogle Scholar
  29. 29.
    M. Walther, B. Fischer, M. Schall, H. Helm, P.U. Jepsen, Chem. Phys. Lett. 332(3–4), 389 (2000)ADSCrossRefGoogle Scholar
  30. 30.
    A.G. Markelz, S. Whitmire, J.R. Hillebrecht, R. Birge, Phys. Med. Biol. 47, 3797 (2002)CrossRefGoogle Scholar
  31. 31.
    H.A. Lorentz, in Proceedings of the KNAW, vol. 18, p. 134, 1915Google Scholar
  32. 32.
    B.M. Fischer, M. Walther, P.U. Jepsen, Phys. Med. Biol. 47(21), 3807 (2002)CrossRefGoogle Scholar
  33. 33.
    K. Yamamoto, M.H. Kabir, K. Tominaga, J. Opt. Soc. Am. B 22(11), 2417 (2005)ADSCrossRefGoogle Scholar
  34. 34.
    N. Brandt, A. Chikishev, A. Kargovsky, M. Nazarov, O. Parashchuk, D. Sapozhnikov, I. Smirnova, A. Shkurinov, N. Sumbatyan, Vib. Spectrosc. 47(1), 53 (2008)CrossRefGoogle Scholar
  35. 35.
    M. Walther, P. Plochocka, B. Fischer, H. Helm, P.U. Jepsen, Biopolymers 67(4–5), 310 (2002)Google Scholar
  36. 36.
    M. Walther, B.M. Fischer, P.U. Jepsen, Chem. Phys. 288(2–3), 261 (2003)CrossRefGoogle Scholar
  37. 37.
    B. Fischer, M. Hoffmann, H. Helm, G. Modjesch, P.U. Jepsen, Semicond. Sci. Tech. 20(7), S246 (2005)ADSCrossRefGoogle Scholar
  38. 38.
    P.F. Taday, I.V. Bradley, D.D. Arnone, M. Pepper, J. Pharm. Sci. 92(4), 831 (2003)CrossRefGoogle Scholar
  39. 39.
    E.P.J. Parrott, J.A. Zeitler, T. Friscic, M. Pepper, W. Jones, G.M. Day, L.F. Gladden, Cryst. Growth Des. 9(3), 1452 (2009)CrossRefGoogle Scholar
  40. 40.
    C.J. Strachan, T. Rades, D.A. Newnham, K.C. Gordon, M. Pepper, P.F. Taday, Chem. Phys. Lett. 390(1–3), 20 (2004)ADSCrossRefGoogle Scholar
  41. 41.
    M. Ge, G. Liu, S. Ma, W. Wang, Bull. Korean Chem. Soc. 30(10), 2265 (2009)CrossRefGoogle Scholar
  42. 42.
    R. Chakkittakandy, J.A.W.M. Corver, P.C.M. Planken, J. Pharm. Sci. 99(2), 932 (2010)Google Scholar
  43. 43.
    J.A. Zeitler, D.A. Newnham, P.F. Taday, T.L. Threlfall, R.W. Lancaster, R.W. Berg, C.J. Strachan, M. Pepper, K.C. Gordon, T. Rades, J. Pharm. Sci. 95, 2486 (2006)CrossRefGoogle Scholar
  44. 44.
    Y.C. Shen, P.F. Taday, IEEE J. Sel. Top. Quant. 14(2), 407 (2008)CrossRefGoogle Scholar
  45. 45.
    J.A. Zeitler, D.A. Newnham, P.F. Taday, C.J. Strachan, M. Pepper, K.C. Gordon, T. Rades, Thermochim. Acta 436(1–2), 71 (2005)CrossRefGoogle Scholar
  46. 46.
    J.A. Zeitler, P.F. Taday, K.C. Gordon, M. Pepper, T. Rades, Chem. Phys. Chem. 8, 1924 (2007)CrossRefGoogle Scholar
  47. 47.
    M. Franz, B.M. Fischer, M. Walther, J. Mol. Struct. 1006(1–3), 34 (2011)Google Scholar
  48. 48.
    P. Upadhya, K. Nguyen, Y. Shen, J. Obradovic, K. Fukushige, R. Griffiths, L. Gladden, A. Davies, E. Linfield, Spectrosc. Lett. 39(3), 215 (2006)ADSCrossRefGoogle Scholar
  49. 49.
    J.A. Zeitler, P.F. Taday, M. Pepper, T. Rades, J. Pharm. Sci. 96, 2703 (2007)CrossRefGoogle Scholar
  50. 50.
    J.A. Zeitler, K. Kogermann, J. Rantanen, T. Rades, P.F. Taday, M. Pepper, J. Aaltonen, C.J. Strachan, Int. J. Pharm. 334(1–2), 78 (2007)CrossRefGoogle Scholar
  51. 51.
    H.b. Liu, Y. Chen, X.C. Zhang, J. Pharm. Sci. 96(4), 927 (2007)Google Scholar
  52. 52.
    H. Liu, X.C. Zhang, Chem. Phys. Lett. 429(1–3), 229 (2006)ADSCrossRefGoogle Scholar
  53. 53.
    M. Ge, W. Wang, H. Zhao, Z. Zhang, X. Yu, W. Li, Chem. Phys. Lett. 444(4–6), 355 (2007)ADSCrossRefGoogle Scholar
  54. 54.
    K.L. Nguyen, T. Friscić, G.M. Day, L.F. Gladden, W. Jones, Nat. Mater. 6(3), 206 (2007)ADSCrossRefGoogle Scholar
  55. 55.
    P.F. Taday, Philos. T. Roy. Soc. A 362(1815), 351 (2004)ADSCrossRefGoogle Scholar
  56. 56.
    C.J. Strachan, P.F. Taday, D.A. Newnham, K.C. Gordon, J.A. Zeitler, M. Pepper, T. Rades, J. Pharm. Sci. 94(4), 837 (2005)CrossRefGoogle Scholar
  57. 57.
    Y. Shen, P. Taday, D. Newnham, M. Pepper, Semicond. Sci. Tech. 20(7), 254 (2005)ADSCrossRefGoogle Scholar
  58. 58.
    Z. Zeng-Yan, J. Te, Y. Xiao-Han, X. Ti-Qiao, X. Hong-Jie, Chinese Phys. Lett. 23(8), 2239 (2006)ADSCrossRefGoogle Scholar
  59. 59.
    E.P.J. Parrott, J.A. Zeitler, L.F. Gladden, Opt. Lett. 34(23), 3722 (2009)ADSCrossRefGoogle Scholar
  60. 60.
    H. Tuononen, K. Fukunaga, M. Kuosmanen, J. Ketolainen, K.E. Peiponen, Appl. Spectrosc. 64(1), 127 (2010)ADSCrossRefGoogle Scholar
  61. 61.
    M. Scheller, S. Wietzke, C. Jansen, M. Koch, J. Phys. D: Appl. Phys. 42(6), 065415 (2009)ADSCrossRefGoogle Scholar
  62. 62.
    G. Gallot, S. Jamison, R. McGowan, D. Grischkowsky, J. Opt. Soc. Am. B 17(5), 851 (2000)ADSCrossRefGoogle Scholar
  63. 63.
    J.S. Melinger, N. Laman, S.S. Harsha, D. Grischkowsky, Appl. Phys. Lett. 89(25), 251110 (2006)ADSCrossRefGoogle Scholar
  64. 64.
    N. Laman, S.S. Harsha, D. Grischkowsky, Appl. Spectrosc. 62(3), 319 (2008)ADSCrossRefGoogle Scholar
  65. 65.
    M.C. Kemp, P.F. Taday, B.E. Cole, J.A. Cluff, A.J. Fitzgerald, W.R. Tribe, Proc. SPIE 5070, 44 (2003)ADSCrossRefGoogle Scholar
  66. 66.
    F. Huang, B. Schulkin, H. Altan, J.F. Federici, D. Gary, R. Barat, D. Zimdars, M. Chen, D.B. Tanner, Appl. Phys. Lett. 85(23), 5535 (2004)ADSCrossRefGoogle Scholar
  67. 67.
    Y. Chen, H. Liu, Y. Deng, D. Schauki, M.J. Fitch, R. Osiander, C. Dodson, J.B. Spicer, M. Shur, X.C. Zhang, Chem. Phys. Lett. 400(4–6), 357 (2004)ADSCrossRefGoogle Scholar
  68. 68.
    W.H. Fan, A. Burnett, P.C. Upadhya, J. Cunningham, E.H. Linfield, A.G. Davies, Appl. Spectrosc. 61(6), 638 (2007)ADSCrossRefGoogle Scholar
  69. 69.
    J. Barber, D.E. Hooks, D.J. Funk, R.D. Averitt, A.J. Taylor, D. Babikov, J. Phys. Chem. A 109(15), 3501 (2005)CrossRefGoogle Scholar
  70. 70.
    J.S. Melinger, N. Laman, D. Grischkowsky, Appl. Phys. Lett. 93(1), 011102 (2008)ADSCrossRefGoogle Scholar
  71. 71.
    J. Chen, Y. Chen, H. Zhao, G.J. Bastiaans, X.C. Zhang, Opt. Express 15(19), 12060 (2007)ADSCrossRefGoogle Scholar
  72. 72.
    Y.C. Shen, T. Lo, P.F. Taday, B.E. Cole, W.R. Tribe, M.C. Kemp, Appl. Phys. Lett. 86(24), 241116 (2005)ADSCrossRefGoogle Scholar
  73. 73.
    D.G. Allis, T.M. Korter, Chem.Phys.Chem. 7(11), 2398 (2006)CrossRefGoogle Scholar
  74. 74.
    D.G. Allis, D.A. Prokhorova, T.M. Korter, J. Phys. Chem. A 110(5), 1951 (2006)CrossRefGoogle Scholar
  75. 75.
    D.G. Allis, J.A. Zeitler, P.F. Taday, T.M. Korter, Chem. Phys. Lett. 463, 84 (2008)ADSCrossRefGoogle Scholar
  76. 76.
    A.D. Burnett, J. Kendrick, J.E. Cunningham, M.D. Hargreaves, T. Munshi, H.G.M. Edwards, E.H. Linfield, A.G. Davies, Chem.Phys.Chem. 11(2), 368 (2010)CrossRefGoogle Scholar
  77. 77.
    C.T. Konek, B.P. Mason, J.P. Hooper, C.A. Stoltz, J. Wilkinson, Chem. Phys. Lett. 489(1–3), 48 (2010)ADSCrossRefGoogle Scholar
  78. 78.
    D. Grischkowsky, S. Keiding, M. van Exter, C. Fattinger, J. Opt. Soc. Am. B 7(10), 20062015 (1990)CrossRefGoogle Scholar
  79. 79.
    A.J.L. Adam, P.C.M. Planken, S. Meloni, J. Dik, Opt. Express 17(5), 3407 (2009)ADSCrossRefGoogle Scholar
  80. 80.
    E. Courtens, M. Foret, B. Hehlen, R. Vacher, Solid State Commun. 117(3), 187 (2001)ADSCrossRefGoogle Scholar
  81. 81.
    R. Zeller, R. Pohl, Phys. Rev. B 4(6), 2029 (1971)ADSCrossRefGoogle Scholar
  82. 82.
    M. Naftaly, R. Miles, J. Non-Cryst, Solids 351(40–42), 3341 (2005)Google Scholar
  83. 83.
    S.N. Taraskin, S.I. Simdyankin, S.R. Elliott, J.R. Neilson, T. Lo, Phys. Rev. Lett. 97(5), 1 (2006)CrossRefGoogle Scholar
  84. 84.
    B. Hehlen, E. Courtens, R. Vacher, A. Yamanaka, M. Kataoka, K. Inoue, Phys. Rev. Lett. 84(23), 5355 (2000)ADSCrossRefGoogle Scholar
  85. 85.
    T.I. Jeon, K.J. Kim, C. Kang, S.J. Oh, J.H. Son, K.H. An, D.J. Bae, Y.H. Lee, Appl. Phys. Lett. 80(18), 3403 (2002)ADSCrossRefGoogle Scholar
  86. 86.
    T.I. Jeon, K.J. Kim, C. Kang, I.H. Maeng, J.H. Son, K.H. An, J.Y. Lee, Y.H. Lee, J. Appl. Phys. 95, 5736 (2004)ADSCrossRefGoogle Scholar
  87. 87.
    C. Kang, I.H. Maeng, S.J. Oh, J.H. Son, T.I. Jeon, K.H. An, S.C. Lim, Y.H. Lee, Appl. Phys. Lett. 87(4), 041908 (2005)ADSCrossRefGoogle Scholar
  88. 88.
    C. Kang, I.H. Maeng, S.J. Oh, S.C. Lim, K.H. An, Y.H. Lee, J.H. Son, Phys. Rev. B 75(8), 1 (2007)CrossRefGoogle Scholar
  89. 89.
    I. Maeng, C. Kang, S.J. Oh, J.H. Son, K.H. An, Y.H. Lee, Appl. Phys. Lett. 90(5), 051914 (2007)ADSCrossRefGoogle Scholar
  90. 90.
    H. Altan, F. Huang, J.F. Federici, A. Lan, H. Grebel, J. Appl. Phys. 96(11), 6685 (2004)ADSCrossRefGoogle Scholar
  91. 91.
    N. Akima, Y. Iwasa, S. Brown, A.M. Barbour, J. Cao, J. Musfeldt, H. Matsui, N. Toyota, M. Shiraishi, H. Shimoda, O. Zhou, Adv. Mater. 18(9), 1166 (2006)CrossRefGoogle Scholar
  92. 92.
    H. Nishimura, N. Minami, R. Shimano, Appl. Phys. Lett. 91(1), 011108 (2007)ADSCrossRefGoogle Scholar
  93. 93.
    R. Rungsawang, V.G. Geethamma, E.P.J. Parrott, D.A. Ritchie, E.M. Terentjev, J. Appl. Phys. 103(12), 123503 (2008)ADSCrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2012

Authors and Affiliations

  • Edward P. J. Parrott
    • 1
  • Bernd  M. Fischer
    • 2
  • Lynn F. Gladden
    • 3
  • J. Axel Zeitler
    • 3
  • Peter U. Jepsen
    • 4
  1. 1.Department of Electronic EngineeringThe Chinese University of Hong KongHong KongChina
  2. 2.Institut franco-allemand de recherches de Saint-LouisSaint-Louis CedexFrance
  3. 3.Department of Chemical Engineering and BiotechnologyUniversity of CambridgeCambridgeUK
  4. 4.DTU Fotonik-Department of Photonics EngineeringTechnical University of DenmarkKongens LyngbyDenmark

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