This thesis describes (1) the synthesis and structural characterization of B-substituted nickel-1,2-o-carboryne complexes, (2) the reaction chemistry of Ni-1,2-o-carboryne with alkenes or/and alkynes, and (3) the formation of 1,3-o-carboryne and its reaction with alkynes catalyzed by transition metals.
Reaction Chemistry Sequential Insertion Methyl Acrylate Cycloaddition Reaction Metal Halide
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