Oxidation, Nitridation, and Reduction

Chapter

Abstract

Surface oxidation of metals and semiconductors in an oxidizing agent is a well-known phenomenon. Clean surfaces of many materials such as Al, Nb, Si, etc., spontaneously react in air, even at room temperature, to form thin native oxide layers. With the materials under consideration the native oxide layer is very dense and terminates further oxidation. Native oxide layers are, typically, 10–100Å thick.

Keywords

Oxide Layer Oxidation Rate Oxide Growth Oxidic Perovskite Thin Metal Film 
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References

  1. Baufay L., F.A. Houle, R.J. Wilson: Optical self-regulation during laser-induced oxidation of copper, J. Appl. Phys. 61, 4640 (1987)ADSCrossRefGoogle Scholar
  2. Bergmann H.W.: Surface Treatment, in Landolt-Börnstein – Numerical Data and Functional Relationships in Science and Technology, New Series, Group VIII/1C (Group VIII: Advanced Materials and Technologies, Vol. 1 Laser Physics and Applications, Subvolume C: Laser Applications, edited by R. Poprawe, H. Weber, G. Herziger (Springer Berlin, Heidelberg, New York 2004), p. 75Google Scholar
  3. Bertness K.A., T.T. Chiang, C.E. McCants, P.H. Mahowald, A.K. Wahi, T. Kendelewicz, I. Lindau, W.E. Spicer: Comparative uptake kinetics of N2O and O2 chemisorption on GaAs (110), Surf. Sci. 185, 544 (1987)ADSCrossRefGoogle Scholar
  4. Boyd I.W., V. Craciun, A. Kazor: Vacuum-ultra-violet and ozone induced oxidation of silicon and silicon-germanium, Jpn. J. Appl. Phys. 32, 6141 (1993)ADSCrossRefGoogle Scholar
  5. Boyd I.W.: Laser Processing of Thin Films and Microstructures, Springer Ser. Mater. Sci., Vol.3 (Springer, Berlin, Heidelberg 1987)CrossRefGoogle Scholar
  6. Cabrera N., N.F. Mott: Theory of the Oxidation of Metals, Rep. Prog. Phys. 12, 163 (1949)ADSCrossRefGoogle Scholar
  7. Carpene E., P. Schaaf, M. Han, K.P. Lieb, M. Shinn: Reactive surface processing by irradiation with excimer laser, Nd:YAG laser, free electron laser and Ti:sapphire laser in nitrogen atmosphere, Appl. Surf. Sci. 186, 195 (2002)ADSCrossRefGoogle Scholar
  8. Deal B.E., A.S. Grove: General Relationship for the Thermal Oxidation of Silicon, J. Appl. Phys. 36, 3770 (1965)ADSCrossRefGoogle Scholar
  9. Fernandes A.J., D.M. Kane, B. Gong, R.N. Lamb: UV Laser-induced dehydroxylation of UV fused silica surfaces, in “Laser Cleaning II”,  Chap. 6, p. 147, ed. D.M.Kane (World Scientific, Singapore, 2006)Google Scholar
  10. Gasser A., E.W. Kreutz, K. Wissenbach: Beschichten mit CO2-laserstrahlung, (cladding with CO2-laser radiation) oberflächentechnik, SURTEC Berlin’89, (Hanser, München 1989) p. 545Google Scholar
  11. Hartmann N., B. Klingebiel, T. Balgar, S. Franzka, E. Hasselbrink: Laser-induced local dehydroxylation on surface-oxidized silicon substrates: mechanistic aspects and prospects in nanofabricaiton, Appl. Phys. A 94, 95 (2009)ADSCrossRefGoogle Scholar
  12. Kabashin A.V., A. Trudeau, W. Marine, M.Meunier: Synthesis of efficient ZnO-based random lasing medium using laser-induced air breakdown processing, Appl. Phys. Lett. 91, 201101 (2007)ADSCrossRefGoogle Scholar
  13. Kapenieks A., M. Eyett, D. Bäuerle: Laser-induced surface metallization of ceramic PLZT, Appl. Phys. A 41, 331 (1986a)ADSCrossRefGoogle Scholar
  14. Kapenieks A., M. Eyett, R. Stumpe, D. Bäuerle: Laser Direct Writing of Electrodes on PLZT Ceramics, in Laser Processing and Diagnostics II, ed. by D. Bäuerle, K.L. Kompa, L.D. Laude (Physique, Les Ulis 1986b) p. 165Google Scholar
  15. Karlov N.V., N. Kirichenko, B. Luk’yanchuk: Laser Thermochemistry (Nauka, Moscow 1992) (in Russian)Google Scholar
  16. Liberts G., M. Eyett, D. Bäuerle: Direct laser writing of superconducting patterns into semiconducting ceramic Y-Ba-Cu-O, Appl. Phys. A 46, 331 (1988a)ADSGoogle Scholar
  17. Liberts G., M. Eyett, D. Bäuerle: Laser-induced surface reduction of the high T\(_{\mathrm{c}}\) superconductor YBa2Cu\(_{3}<Emphasis Type="Italic">O</Emphasis>_{7-\mathrm{x}}\), Appl. Phys. A 45, 313 (1988b)ADSCrossRefGoogle Scholar
  18. Lu Z., M.T. Schmidt, D.V. Podlesnik, C.F. Yu, R.M. Osgood: Ultraviolet-light-induced oxide formation on GaAs surfaces, J. Chem. Phys. 93, 7951 (1990)ADSCrossRefGoogle Scholar
  19. Marks R.F., R.A. Pollak, P. Avouris, C.T. Lin, Y.J. Théfaine: Laser-Pulsed Plasma Chemistry: Laser-Initiated Plasma Oxidation of Niobium, J. Chem. Phys. 78, 4270 (1983)ADSCrossRefGoogle Scholar
  20. Massoud H.Z., J.D. Plummer: Analytical relationship for the oxidation of Silicon in Dry Oxygen in the Thin-Filme Regime, J. Appl. Phys. 62, 3416 (1987)ADSCrossRefGoogle Scholar
  21. Migoni R., H. Bilz, D. Bäuerle: Origin of Raman Scattering and Ferroelectricity in Oxidic Perovskites, Phys. Rev. Lett. 37, 1155 (1976)ADSCrossRefGoogle Scholar
  22. Nanai L., R. Vajtai, I. Hevesi, D.A. Jelski, T.F. George: Metal Oxide layer growth under laser irradiation, Thin. Sol. Film. 227, 13 (1993)ADSCrossRefGoogle Scholar
  23. Orlowski T.E., D.A. Mantell: Ultraviolet laser-induced oxidation of Silicon: The effect of Oxygen photodissociation upon Oxide growth kinetics, J. Appl. Phys. 64, 4410 (1988)ADSCrossRefGoogle Scholar
  24. Pedarnig J.D., H. Göttlich, R. Rössler, W.M. Heckl, D. Bäuerle: Patterning of YBa2Cu\(_{3}<Emphasis Type="Italic">O</Emphasis>_{7-\updelta}\) films using a near-field optical configuration, Appl. Phys. A 67, 403 (1998)ADSCrossRefGoogle Scholar
  25. Pereira A., A. Cros, P. Delaporte, S. Georgiou, A. Manousaki, W. Marine, M. Sentis: Surface nanostructuring of metals by laser irradiation: effects of pulse duration, wavelength and gas atmosphere, Appl. Phys. A 79, 1433 (2004)ADSCrossRefGoogle Scholar
  26. Roberts M.W., C.S. McKee: Chemistry of the Metal-Gas Interface (Clarendon Press, Oxford 1978)Google Scholar
  27. Samsonov G.V. ed.: The Oxide Handbook (Plenum, New York 1973)Google Scholar
  28. Schwartz B.: GaAs Surface Chemistry – a Review, CRC critical review in solid state sciences, 5 (CRC Press, Boca Raton 1975) p. 609Google Scholar
  29. Seo J.M., Y.Z. Li, S.G. Anderson, D.J.W. Aastuen, U.S. Ayyala, G.H. Kroll, J.H. Weaver: X-Ray-Induced Low-Temperature Oxidation: N2O/GaAs(110), Phys. Rev. B 42, 9080 (1990)ADSCrossRefGoogle Scholar
  30. Shen Y.Q., T. Freltoft, P. Vase: Laser writing and rewriting on YBa2Cu\(_{3}<Emphasis Type="Italic">O</Emphasis>_{7}\) Films, Appl. Phys. Lett. 59, 1365 (1991)ADSCrossRefGoogle Scholar
  31. Sobolewski R., W. Xiong, W. Kula, J.R. Gavaler: Laser Patterning of Y-Ba-Cu-O Thin-Film Devices and Circuits, Appl. Phys. Lett. 64, 643 (1994)ADSCrossRefGoogle Scholar
  32. Sugii T., T. Ito, H. Ishikawa: Low-temperature fabrication of Silicon Nitride films by ArF excimer laser irradiation, Appl. Phys. A 46, 249 (1988)ADSGoogle Scholar
  33. Takada N., H. Ushida, K. Sasaki: Nitridation of titanium surface by the irradiation of YAG laser pulses in N2/O2 gas mixture and liquid nitrogen, J. Phys. Conf. Ser. 59, 40 (2007)ADSCrossRefGoogle Scholar
  34. Wagner D., D. Bäuerle, F. Schwabl, B. Dorner, H. Kraxenberger: Soft Modes in Semiconducting SrTiO3: I. Zone Boundary Mode, Z. Phys. B 37, 317 (1980)ADSCrossRefGoogle Scholar
  35. Wautelet M.: Laser-Assisted Reaction of Metals with Oxygen, Appl. Phys. A 50, 131 (1990)ADSCrossRefGoogle Scholar
  36. Young E.M.: Electron-Active Silicon Oxidation, Appl. Phys. A 47, 259 (1988)ADSCrossRefGoogle Scholar
  37. Otto J., R. Stumpe, D. Bäuerle: Laser induced reduction and etching of Oxidic perovskites, in Laser Processing and Diagnostics, ed. D. Bäuerle, Springer Ser. Chem. Phys., 39 (Springer, Berlin, Heidelberg 1984) p. 320Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2011

Authors and Affiliations

  1. 1.Johannes-Kepler-Universität Linz, Inst. Angewandte PhysikLinzAustria

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