Mine Wastes pp 43-117

Sulfidic Mine Wastes

Chapter

Abstract

Sulfide minerals are common minor constituents of the Earth’s crust. In some geological environments, sulfides constitute a major proportion of rocks. In particular, metallic ore deposits (Cu, Pb, Zn, Au, Ni, U, Fe), phosphate ores, coal seams, oil shales, and mineral sands may contain abundant sulfides. Mining of these resources can expose the sulfides to an oxygenated environment. In fact, large volumes of sulfide minerals can be exposed in: tailings dams; waste rock dumps; coal spoil heaps; heap leach piles; run-of-mine and low-grade ore stockpiles; waste repository embankments; open pit floors and faces; underground workings; haul roads; road cuts; quarries; and other rock excavations. When the sulfides are exposed to the atmosphere or oxygenated ground water, the sulfides will oxidize to produce an acid water laden with sulfate, heavy metals and metalloids. The mineral pyrite (FeS2) tends to be the most common sulfide mineral present. The weathering of this mineral at mine sites causes the largest, and most testing, environmental problem facing the industry today – acid mine drainage (AMD) (Scientific Issue 2.1).

References

  1. Aachid M, Mbonimpa M, Aubertin M (2004) Measurement and prediction of the oxygen diffusion coefficient in unsaturated media, with applications to soil covers. Water Air Soil Poll 156:163–193Google Scholar
  2. Abraitis PK, Pattrick RAD, Kelsall GH, Vaughan DJ (2004) Acid leaching and dissolution of major sulphide ore minerals: processes and galvanic effects in complex systems. Min Mag 68:343–351Google Scholar
  3. Abreu MM, Matias MJ, Magalhães MCF, Basto MJ (2008a) Impacts on water, soil and plants from the abandoned Miguel Vacas copper mine, Portugual. J Geochem Explor 96:161–170Google Scholar
  4. Abreu MM, Tavares MT, Batista MJ (2008b) Potential use of Erica andevalensis and Erica australis in phytoremediation of sulphide mine environments: São Domingos, Portugual. J Geochem Explor 96:210–222Google Scholar
  5. Acero P, Cama J, Ayora C (2007a) Rate law for galena dissolution in acidic environment. Chem Geol 245:219–229Google Scholar
  6. Acero P, Ayora C, Carrera J (2007c) Coupled thermal, hydraulic and geochemical evolution of pyritic tailings in unsaturated column experiments. Geochim Cosmochim Acta 71:5325–5338Google Scholar
  7. Ackman TE (2003) An introduction to the use of airborne technologies for watershed characterization in mined areas. Mine Water Environ 22:62–68Google Scholar
  8. Agricola G (1546) De natura fossilium (trans: Bandy MC, Bandy JA (2004)). Dover Publications, New YorkGoogle Scholar
  9. Agricola G (1556) De re metallica (trans: Hoover HC, Hoover LH (1950)). Dover Publications, New YorkGoogle Scholar
  10. Al TA, Martin CJ, Blowes DW (2000) Carbonate-mineral/water interactions in sulfide-rich mine tailings. Geochim Cosmochim Acta 64:3933–3948Google Scholar
  11. Alakangas L, Öhlander B (2006a) Formation and composition of cemented layers in low-sulphide mine tailings, Laver, northern Sweden. Environ Geol 50:809–819Google Scholar
  12. Alakangas L, Öhlander B (2006b) Pilot-scale studies of different covers on unoxidised sulphide-rich tailings in northern Sweden: the geochemistry of leachate waters. Mine Water Environ 25:171–183Google Scholar
  13. Alpers CN, Blowes DW, Nordstrom DK, Jambor JL (1994) Secondary minerals and acid mine-water chemistry. In: Jambor JL, Blowes DW (eds) Environmental geochemistry of sulfide mine-wastes, vol 22. Mineralogical Association of Canada, Nepean, pp 247–270 (Short course handbook)Google Scholar
  14. Anawar HM, Garcia-Sanchez A, Murciego A, Buyolo T (2006) Exposure and bioavailability of arsenic in contaminated soils from the La Parrilla mine, Spain. Environ Geol 50:170–179Google Scholar
  15. Anderson CWN, Brooks RR, Chiarucci A, LaCoste CJ, Leblanc M, Robinson BH, Simcock R, Stewart RB (1999) Phytomining for nickel, thallium and gold. J Geochem Explor 67:407–415Google Scholar
  16. Ardau C, Blowes DW, Ptacek CJ (2009) Comparison of laboratory testing protocols to field observations of the weathering of sulfide-bearing mine tailings. J Geochem Explor 100:182–191Google Scholar
  17. Ashley PM, Lottermoser BG (1999a) Geochemical, mineralogical and biogeochemical characterisation of abandoned metalliferous mine sites, southern New England Orogen. In: Proceedings of the NEO’99 Conference. Armidale, Division of Earth Sciences, University of New England, pp 409–418Google Scholar
  18. Ashley PM, Lottermoser BG (1999b) Arsenic contamination at the Mole River mine, northeastern New South Wales, Australia. Austral J Earth Sci 46:861–874Google Scholar
  19. Ashley PM, Lottermoser BG, Chubb AJ (2003a) Environmental geochemistry of the Mt Perry copper mines area, southeast Queensland, Australia. Geochem Explor Environ Anal 3:345–357Google Scholar
  20. Ashley PM, Lottermoser BG, Collins A, Grant CD (2004) Environmental geochemistry of the derelict Webbs Consols mine, New South Wales, Australia. Environ Geol 46:596–609Google Scholar
  21. Avery ER, Benning LG (2008) Anaerobic pyrite oxidation rates determined via direct volume-loss measurements: a Vertical Scanning Interferometric approach. Mineral Mag 72:15–18Google Scholar
  22. Baker AJM (1981) Accumulators and excluders – strategies in the response of plants to heavy metals. J Plant Nutr 3:643–654Google Scholar
  23. Baker AJM, Brooks RR (1989) Terrestrial higher plants which hyperaccumulate chemical elements – a review of their distribution, ecology and phytochemistry. Biorecovery 1:81–126Google Scholar
  24. Banks D, Younger PL, Arnesen R-T, Iversen ER, Banks SB (1997) Mine-water chemistry; the good, the bad and the ugly. Environ Geol 32:157–174Google Scholar
  25. Basta NT, McGowen SL (2004) Evaluation of chemical immobilization treatments for reducing heavy metal transport in a smelter-contaminated soil. Environ Poll 127, 73–82Google Scholar
  26. Batista MJ, Abreu MM, Serrano Pinto M (2007) Biogeochemistry in Neves Corvo mining region, Iberian Pyrite Belt, Portugual. J Geochem Explor 92:159–176Google Scholar
  27. Belzile N, Chen YW, Cai MF, Li Y (2004) A review on pyrrhotite oxidation. J Geochem Explor 84:65–76Google Scholar
  28. Bennett JW, Gibson DK, Ritchie AIM, Tan Y, Broman PG, Jönsson H (1994) Oxidation rates and pollution loads in drainage; correlation of measurements in a pyritic waste rock dump. In: Proceedings of the international land reclamation and mine drainage conference and 3rd international conference on the abatement of acidic drainage, vol 1. United States Department of the Interior, Bureau of Mines Special Publication SP06A-94, pp 401–409Google Scholar
  29. Bennett JW, Timms GP, Ritchie AIM (1999) The effectiveness of the covers on waste rock dumps at Rum Jungle and the impact in the long term. In: Proceedings of the 24th annual Minerals Council of Australia environmental workshop. Minerals Council of Australia, Dickson, pp 379–388Google Scholar
  30. Bennett MW, Kempton JH, Maley PJ (1997) Applications of geological block models to environmental management. In: Proceedings from the 4th international conference on acid rock drainage, vol 1. Vancouver, pp 293–303Google Scholar
  31. Benzaazoua M, Bussiere B, Dagenais AM, Archambault M (2004) Kinetic test comparison and interpretation for prediction of the Joutel tailings acid generation potential. Environ Geol 46:1086–1101Google Scholar
  32. Berger AC, Bethke CM, Krumhansl JL (2000) A process model of natural attentuation in drainage from a historic mining district. Appl Geochem 15:655–666Google Scholar
  33. Bernier L, Warren LA (2007) Geochemical diversity in S processes mediated by culture-adapted and environmental-enrichments of Acidithiobacillus spp. Geochim Cosmochim Acta 71:5684–5697Google Scholar
  34. Bethune KJ, Lockington DA, Williams DJ (1997) Acid mine drainage: comparison of laboratory testing to mine site conditions. In: Proceedings from the 4th international conference on acid rock drainage, vol 1. Vancouver, pp 306–318Google Scholar
  35. Bigham JM, Nordstrom DK (2000) Iron and aluminium hydroxysulfates from acid sulfate waters. In: Alpers CN, Jambor JL, Nordstrom DK (eds) Sulfate minerals: crystallography, geochemistry and environmental significance, vol 40. Mineralogical Society of America, Washington, DC, pp 351–403 (Reviews in mineralogy and geochemistry)Google Scholar
  36. Blowes DW, Ptacek CJ (1994) Acid-neutralization mechanisms in inactive mine tailings. In: Jambor JL, Blowes DW (eds) Environmental geochemistry of sulfide mine-wastes, vol 22. Mineralogical Association of Canada, Nepean, pp 271–292 (Short course handbook)Google Scholar
  37. Blowes DW, Reardon EJ, Jambor JL, Cherry JA (1991) The formation and potential importance of cemented layers in inactive sulfide mine tailings. Geochim Cosmochim Acta 55:965–978Google Scholar
  38. Blowes DW, Ptacek CJ, Jambor JL (1994) Remediation and prevention of low-quality drainage from tailings impoundments. In: Jambor JL, Blowes DW (eds) Environmental geochemistry of sulfide mine-wastes, vol 22. Mineralogical Association of Canada, Nepean, pp 365–380 (Short course handbook)Google Scholar
  39. Blowes DW, Jambor JL, Hanton-Fong CJ, Lortie L, Gould WD (1998) Geochemical, mineralogical and microbiological characterization of a sulphide-bearing carbonate-rich gold-mine tailings impoundment, Joutel, Québec. Appl Geochem 13:687–705Google Scholar
  40. Bond PL, Druschel GK, Banfield JE (2000) Comparison of acid mine drainage microbial communities in physically and geochemically distinct ecosystems. Appl Environ Microbiol 66:4962–4971Google Scholar
  41. Boon M, Snijder M, Hansfrod GS, Heijnen JJ (1998) The oxidation kinetics of zinc sulphide with Thiobacillus ferrooxidans. Hydrometallurgy 48:171–186Google Scholar
  42. Boorman RS, Watson DM (1976) Chemical processes in abandoned sulphide tailings dumps and environmental implication for northeastern New Brunswick. CIM Bulletin 69:86–96Google Scholar
  43. Borden R (2001) Geochemical evolution of sulphide-bearing waste rock soils at the Bingham Canyon mine, Utah. Geochem Explor Environ Anal 1:15–22Google Scholar
  44. Bordon RK, Black R (2005) Volunteer revegetation of waste rock surfaces at the Bingham Canyon mine, Utah. J Environ Qual 34:2234–2242Google Scholar
  45. Bosso ST, Enzweiler J, Angelica RS (2008) Lead bioaccessibility in soil and mine wastes after immobilization with phosphate. Water Air Soil Poll 195:257–273Google Scholar
  46. Briggs TJ, Kelso IJ (2003) Ammonium nitrate-sulfide reactivity at the Century Zn-Pb-Ag mine, northwest Queensland, Australia. Expl Min Geol 10:177–190Google Scholar
  47. Bril H, Zainoun K, Puziewicz J, Courtin-Nomade A, Vanaecker M, Bollinger JC (2008) Secondary phases from the alteration of a pile of zinc-smelting slag as indicators of environmental conditions: an example from Swietochlowice, Upper Silesia, Poland. Can Mineral 46:1235–1248Google Scholar
  48. Brown M, Barley B, Wood H (2002) Minewater treatment: technology, application and policy. International Water Association PublishingGoogle Scholar
  49. Bruce S, Noller B, Matanitobua V, Ng J (2007) In vitro physiologically based extraction test (PBET) and bioaccessibility of arsenic and lead from various mine waste materials. J Toxicol Environ Health 70:1700–1711Google Scholar
  50. Bryan CG, Hallberg KB, Johnson DB (2006) Mobilisation of metals in mineral tailings at the abandoned São Domingos copper mine (Portugual) by indigenous acidophilic bacteria. Hydrometallurgy 83:184–194Google Scholar
  51. Bullock SET, Bell FG (1997) Some problems associated with past mining at a mine in the Witbank coalfield, South Africa. Environ Geol 33:61–71Google Scholar
  52. Bussière B, Benzaazoua M, Aubertin M, Mbonimpa M (2004) A laboratory study of covers made of low-sulphide tailings to prevent acid mine drainage. Environ Geol 45:609–622Google Scholar
  53. Cabral A, Lefebvre G, Proulx ME, Audet C, Labbé M, Michaud C (1997) Use of deinking residues as cover material in the prevention of AMD generation at an abandoned mine site. In: Tailings and mine waste ’97. Balkema, Rotterdam, pp 257–266Google Scholar
  54. Campbell AR, Lueth VW (2008) Isotopic and textural discrimination between hypogene, ancient supergene, and modern sulfates at the Questa mine, New Mexico. Appl Geochem 23:308–319Google Scholar
  55. Cappuyns V, Swennen R, Niclaes M (2007) Application of the BCR sequential extraction scheme to dredged pond sediments contaminated by Pb-Zn mining: a combined geochemical and mineralogical approach. J Geochem Explor 93:78–90Google Scholar
  56. Casagrande DJ, Finkelman RB, Caruccio FT (1989) The nonparticipation of organic sulfur in acid mine drainage. Environ Geochem Health 11:187–192Google Scholar
  57. Cathles LM (1994) Attempts to model the industrial-scale leaching of copper-bearing mine waste. In: Alpers CN, Blowes DW (eds) Environmental geochemistry of sulfide oxidation. American Chemical Society Symposium Series 550, Washington, DC, pp 123–131Google Scholar
  58. Chermak JA, Runnells DD (1996) Self-sealing hardpan barriers to minimize infiltration of water into sulfide-bearing overburden, ore, and tailings piles. In: Tailings and mine waste ’96. Balkema, Rotterdam, pp 265–273Google Scholar
  59. Chopin EIB, Alloway BJ (2007) Distribution and mobility of trace elements in soils and vegetation around the mining and smelting areas of Tharsis, Ríotinto and Huelva, Iberian Pyrite Belt, SW Spain. Water Air Soil Poll 182:245–261Google Scholar
  60. Chrysochoou M, Dermatas D, Grubb DG (2007) Phosphate application to firing range soils for Pb immobilization: the unclear role of phosphate. J Haz Mat 144:1–14Google Scholar
  61. Cidu R, Fanfani L (2002) Overview of the environmental geochemistry of mining districts in southwestern Sardinia, Italy. Geochem Explor Environ Anal 2:243–251Google Scholar
  62. Conesa HM, Schulin R, Nowack B (2007) A laboratory study on revegetation and metal uptake in native plant species from neutral mine tailings. Water Air Soil Pollut 183:201–212Google Scholar
  63. Conesa HM, Robinson BH, Schulin R, Nowack B (2008) Metal extractability in acidic and neutral mine tailings from the Cartagena-La Unión Mining District (SE Spain). Appl Geochem23:1232–1240Google Scholar
  64. Cook T, Skousen J, Hilton T (2008) Covering pre-existing, acid-producing fills with alkaline sandstone to control acid mine drainage. Mine Water Environ 27:259–264Google Scholar
  65. Corkhill CL, Vaughan DJ (2009) Arsenopyrite oxidation. Appl Geochem 24:2342–2361Google Scholar
  66. Corkhill CL, Wincott PL, Lloyd JR, Vaughan DJ (2008) The oxidative dissolution of arsenopyrite (FeAsS) and enargite (Cu3AsS4) by Leptospirillum ferrooxidans. Geochim Cosmochim Acta 72:5616–5633Google Scholar
  67. Cornejo-Garrido H, Fernández-Lomelín P, Guzmán J, Cervini-Silva J (2008) Dissolution of arsenopyrite (FeAsS) and galena (PbS) in the presence of desferrioxamine-B at pH 5. Geochim Cosmochim Acta 72:2754–2766Google Scholar
  68. Courtin-Nomade A, Grosbois C, Marcus MA, Fakra SC, Beny JM, Foster AL (2009) The weathering of a sulfide orebody: speciation and fate of some potential contaminants. Can Mineral 47:493–508Google Scholar
  69. Cousins C, Penner GH, Liu B, Beckett P, Spiers G (2009) Organic matter degradation in paper sludge amendments over gold mine tailings. Appl Geochem 24:2293–2300Google Scholar
  70. Craw D, Chappell D, Nelson M, Walrond M (1999) Consolidation and incipient oxidation of alkaline arsenopyrite-bearing mine tailings, Macreas Mine, New Zealand. Appl Geochem 14:485–498Google Scholar
  71. Craw D, Rufaut CG, Hammit S, Clearwater SG, Smith CM (2007a) Geological controls on natural ecosystem recovery on mine waste in southern New Zealand. Environ Geol 51:1389–1400Google Scholar
  72. Craw D, Rufaut C, Haffert L, Paterson L (2007b) Plant colonization and arsenic uptake on high arsenic mine wastes, New Zealand. Water Air Soil Poll 179:351–364Google Scholar
  73. Crock JG, Arbogast BF, Lamothe PJ (1999) Laboratory methods for the analysis of environmental samples. In: Plumlee GS, Logsdon MS (eds) The environmental geochemistry of mineral deposits. Part A: processes, techniques and health issues, vol 6A. Society of Economic Geologists, Littleton, pp 265–287 (Reviews in economic geology)Google Scholar
  74. Cruz R, Bertrand V, Monroy M, Ganzalez I (2001a) Effect of sulfide impurities on the reactivity of pyrite and pyritic concentrates; a multi-tool approach. Appl Geochem 16:803–819Google Scholar
  75. Cruz R, Mendez BA, Monroy M, Gonzalez I (2001b) Cyclic voltammetry applied to evaluate reactivity in sulfide mining residues. Appl Geochem 16:1631–1640Google Scholar
  76. Currey NA, Ritchie PJ, Durham AJP, Wilson GW (1999) Field performance and optimisation of two low flux soil cover systems for the prevention of acid mine drainage in a semi arid environment. In: Proceedings of the 24th annual Minerals Council of Australia environmental workshop. Minerals Council of Australia, Dickson, pp 458–465Google Scholar
  77. Dalton JB, King TVV, Bove DJ, Kokaly RF, Clark RN, Vance JS, Swayze GA (2000) Distribution of acid-generating and acid-buffering minerals in the Animas River watershed as determined by AVIRIS spectroscopy. In: Proceedings from the 5th international conference on acid rock drainage, vol 2. Society for Mining, Metallurgy, and Exploration, Littleton, pp 1541–1550Google Scholar
  78. Dermatas D, Chrysochoou M, Grubb DG, Xu X (2008) Phosphate treatment of firing range soils: lead fixation or phosphorus release? J Environ Qual 37:47–56Google Scholar
  79. Deutsch WJ (1997) Groundwater geochemistry; fundamentals and applications to contamination. Lewis Publishers, Boca RatonGoogle Scholar
  80. Díez M, Simón M, García I, Martín F (2009) Assessment of the critical load of trace elements in soils polluted by pyrite tailings. A laboratory experiment. Water Air Soil Poll 199:381–387Google Scholar
  81. Dinelli E, Tateo F (2001) Sheet silicates as effective carriers of heavy metals in the ophiolitic mine area of Vigonzano (northern Italy). Mineral Mag 65:121–132Google Scholar
  82. Dobos SK (2000) Potential problems with geologically uncontrolled sampling and the interpretation of chemical tests for waste characterisation and AMD prediction. 4th Australian workshop on acid mine drainage. Australian Centre for Mining Environmental Research, BrisbaneGoogle Scholar
  83. Dokoupilová P, Sracek O, Losos Z (2007) Geochemical behavior and mineralogical transformations during spontaneous combustion of a coal waste pile in Oslavany, Czech Republic. Mineral Mag 71:443–460Google Scholar
  84. Dold B (2003) Speciation of the most soluble phases in a sequential extraction procedure adapted for geochemical studies of copper sulfide mine waste. J Geochem Explor 80:55–68Google Scholar
  85. Domvile SJ, Li MG, Sollner DD, Nesbitt W (1994) Weathering behaviour of mine tailings and waste rock: a surface investigation. In: Proceedings of the international land reclamation and mine drainage conference and 3rd international conference on the abatement of acidic drainage, vol 1. United States Department of the Interior, Bureau of Mines Special Publication SP06A-94, pp 167–176Google Scholar
  86. Druschel GK, Emerson D, Sutka R, Suchecki P, Luther GW III (2008) Low-oxygen and chemical kinetic constraints on the geochemical niche of neutrophilic iron (II) oxidizing microorganisms. Geochim Cosmochim Acta 72:3358–3370Google Scholar
  87. Durães N, Bobos I, Ferreira da Silva E (2008) Chemistry and FT-IR spectroscopic studies of plants from contaminated mining sites in the Iberian Pyrite Belt, Portugual. Mineral Mag 72:405–409Google Scholar
  88. Ebenå G, Hagberg J, Carlsson E (2007) Origin and distribution of low molecular weight organic acids and bacteria in a depth profile of a soil covered tailings impoundment in northern Sweden. J Geochem Explor 92:186–195Google Scholar
  89. Elberling B, Schippers A, Sand W (2000) Bacterial and chemical oxidation of pyritic mine tailings at low temperatures. J Contam Hydrol 41:225–238Google Scholar
  90. Elberling BO, Søndergaard J, Jensen LA, Schmidt LB, Hansen BU, Asmund G, Balić-Zunić T, Hollesen J, Hanson S, Jansson PE, Friborg T (2007) Arctic vegetation damage by winter-generated coal mining pollution released upon thawing. Environ Sci Technol 41:2407–2413Google Scholar
  91. Elliott LCM, Liu L, Stogran SW (1997) Evaluation of single layer organic and inorganic cover materials for oxidized tailings. In: Tailings and mine waste ’97. Balkema, Rotterdam, pp 247–256Google Scholar
  92. Ettler V, Legendre O, Bodénan F, Touray JC (2001) Primary phases and natural weathering of old lead-zinc pyrometallurgical slag from Pribram, Czech Republic. Can Mineral 39:873–888Google Scholar
  93. Ettler V, Piantone P, Touray JC (2003) Mineralogical control on inorganic contaminant mobility in leachate from lead-zinc metallurgical slag: experimental approach and long-term assessment. Mineral Mag 67:1269–1283Google Scholar
  94. Ettler V, Johan Z, Kříbek B, Šebek O, Mihaljevič (2009) Mineralogy and environmental stability of slags from the Tsumeb smelter, Namibia. Appl Geochem 24:1–15Google Scholar
  95. Ettner DC, Braastad G (1999) Induced hardpan formation in a historic tailings impoundment, Røros, Norway. In: Tailings and mine waste ’99. Balkema, Rotterdam, pp 457–464Google Scholar
  96. Eusden JD, Gallagher L, Eighmy TT, Crannell BS, Krzanowski JE, Butler LG, Cartledge FK, Emery EF, Shaw EL, Francis CA (2002) Petrographic and spectroscopic characterization of phosphate-stabilized mine tailings from Leadville, Colorado. Waste Manag 22:117–135Google Scholar
  97. Evangelou VP (1995) Pyrite oxidation and its control. CRC Press, Boca RatonGoogle Scholar
  98. Evangelou VP (1996) Pyrite oxidation inhibition in coal waste by PO4 and H2O2 pH buffered pre-treatment. Int J Surf Min Reclam Environ 10:135–142Google Scholar
  99. Evangelou VP (1998) Pyrite chemistry: the key for abatement of acid mine drainage. In: Geller W, Klapper H, Salomons W (eds) Acidic mining lakes: acid mine drainage, limnology and reclamation. Springer, Heidelberg, pp 197–222Google Scholar
  100. Evangelou VP (2001) Pyrite microencapsulation technologies: principles and potential field applications. Ecol Eng 17:165–178Google Scholar
  101. Evangelou VP, Zhang YL (1995) A review: pyrite oxidation mechanisms and acid mine drainage prevention. Crit Rev Environ Sci Technol 25:141–199Google Scholar
  102. Falk H, Lavergren U, Bergbäck B (2006) Metal mobility in alum shale from Öland, Sweden. J Geochem Explor 90:157–165Google Scholar
  103. Farkas IM, Weiszburg TG, Pekker P, Kuzmann E (2009) A half-century of environmental mineral formation on a pyrite-bearing waste dump in the Mátra Mountains, Hungary. Can Mineral 47:509–524Google Scholar
  104. Fernández-Caliani JC, Barba-Brioso C, González I, Galán E (2009) Heavy metal pollution in soils around the abandoned mine sites of the Iberian Pyrite Belt (Southwest Spain). Water Air Soil Poll 200:211–226Google Scholar
  105. Ferrier G, Hudson-Edwards KA, Pope RJ (2009) Characterisation of the environmental impact of the Rodalquilar mine, Spain by ground-based reflectance spectroscopy. J Geochem Explor 100:11–19Google Scholar
  106. Ficklin WH, Mosier EL (1999) Field methods for sampling and analysis of environmental samples for unstable and selected stable constituents. In: Plumlee GS, Logsdon MS (eds) The environmental geochemistry of mineral deposits. Part A: processes, techniques and health issues, vol 6A. Society of Economic Geologists, Littleton , pp 249–264 (Reviews in economic geology)Google Scholar
  107. Forsberg LS, Ledin S (2003) Effects of iron precipitation and organic amendments on porosity and penetrability in sulphide mine tailings. Water Air Soil Poll 142:395–408Google Scholar
  108. Forsberg LS, Gustafsson JP, Kleja DB, Ledin S (2008) Leaching of metals from oxidising sulphide mine tailings with and without sewage sludge application. Water Air Soil Pollut 194:331–341Google Scholar
  109. Fowler TA, Holmes PR, Crundwell FK (1999) Mechanism of pyrite dissolution in the presence of Thiobacillus ferrooxidans. Appl Environ Microbiol 65:2987–2993Google Scholar
  110. Frau F (2000) The formation-dissolution-precipitation cycle of melanterite at the abandoned pyrite mine of Genna Luas in Sardinia, Italy; environmental implications. Mineral Mag 64:995–1006Google Scholar
  111. Frostad S, Klein B, Lawrence RW (2002) Evaluation of laboratory kinetic test methods for measuring rates of weathering. Mine Water Environ 21:183–192Google Scholar
  112. Furman O, Strawn DG, Heinz GH, Williams B (2006) Risk assessment test for lead bioaccessibility to waterfowl in mine-impacted soils. J Environ Qual 35:450–458Google Scholar
  113. Ganne P, Cappuyns V, Vervoort A, Buvé, Swennen R (2006) Leachability of heavy metals and arsenic from slags of metal extraction industry at Angleur (eastern Belgium). Sci Total Environ 356:69–85Google Scholar
  114. Georgopoulou ZJ, Fytas K, Soto H, Evangelou B (1996) Feasibility and cost of creating an iron-phosphate coating on pyrrhotite to prevent oxidation. Environ Geol 28:61–69Google Scholar
  115. Gibson DK, Ritchie AIM (1991) Options to control acid generation in existing pyritic mine waste dumps. In: Randol Gold Forum Cairns ’91, pp 109–111Google Scholar
  116. Gleisner M, Herbert RB Jr, Frogner Kockum PC (2006) Pyrite oxidation by Acidithiobacillus ferrooxidans at various concentrations of dissolved oxygen. Chem Geol 225:16–29Google Scholar
  117. Goh SW, Buckley AN, Lamb RN, Rosenberg RA, Moran D (2006) The oxidation states of copper and iron in mineral sulfides, and the oxides formed on initial exposure of chalcopyrite and bornite to air. Geochim Cosmochim Acta 70:2210–2228Google Scholar
  118. Gomes MEP, Favas PJC (2006) Mineralogical controls on mine drainage of the abandoned Ervedosa tin mine in north-eastern Portugal. Appl Geochem 21:1322–1334Google Scholar
  119. Gould WD, Bechard G, Lortie L (1994) The nature and role of microorganisms in the tailings environment. In: Jambor JL, Blowes DW (eds) Environmental geochemistry of sulfide mine-wastes, vol 22. Mineralogical Association of Canada, Nepean, pp 185–199 (Short course handbook)Google Scholar
  120. Gould WD, Kapoor A (2003) The microbiology of acid mine drainage. In: Jambor JL, Blowes DW, Ritchie AIM (eds) Environmental aspects of mine wastes, vol 31. Mineralogical Association of Canada, Nepean, pp 203–226 (Short course handbook)Google Scholar
  121. Graupner T, Kassahun A, Rammlmair D, Meima JA, Kock D, Furche M, Fiege A, Schippers A, Melcher F (2007) Formation of sequences of cemented layers and hardpans within sulfide-bearing mine tailings (mine district Freiberg, Germany). Appl Geochem 22:2486–2508Google Scholar
  122. Hakkou R, Benzaazoua M, Bussière B (2008a) Acid mine drainage at the abandoned Kettara mine (Morocco): 1. Environmental characterization. Mine Water Environ 27:145–159Google Scholar
  123. Hakkou R, Benzaazoua M, Bussière B (2008b) Acid mine drainage at the abandoned Kettara mine (Morocco): 2. Mine waste geochemical behavior. Mine Water Environ 27:160–170Google Scholar
  124. Hallberg KB, Johnson DB (2005) Mine water microbiology. Mine Water Environ 24:28–37Google Scholar
  125. Harmer SL, Thomas JE, Fornasiero D, Gerson AR (2006) The evolution of surface layers formed during chalcopyrite leaching. Geochim Cosmochim Acta 70:4392–4402Google Scholar
  126. Harries JR, Ritchie AIM (1987) The effect of rehabilitation on the rate of oxidation of pyrite in a mine waste rock dump. Environ Geochem Health 9:27–36Google Scholar
  127. Harris DL, Lottermoser BG (2006a) Phosphate stabilization of polyminerallic mine wastes. Mineral Mag 70:1–13Google Scholar
  128. Heikkinen PM, Räisänen ML (2008) Mineralogical and geochemical alteration of Hitura sulphide mine tailings with emphasis on nickel mobility and retention. J Geochem Explor 97:1–20Google Scholar
  129. Heikkinen PM, Räisänen ML (2009) Trace metal and As solid-phase speciation in sulphide mine tailings – indicators of spatial distribution of sulphide oxidation in active tailings impoundments. Appl Geochem 24:1224–1237Google Scholar
  130. Hita R, Torrent J, Bigham JM (2006) Experimental oxidative dissolution of sphalerite in the Aznalcóllar sludge and other pyrite matrices. J Environ Qual 35:1032–1039Google Scholar
  131. Hodson ME (2006) Does reactive surface area depend on grain size? Results from pH 3, 25˚C far-from-equilibrium flow-through dissolution experiments on anorthite and biotite. Geochim Cosmochim Acta 70:1655–1667Google Scholar
  132. Hojdová M, Navrátil T, Rohovec J, Penížek V, Grygar T (2009) Mercury distribution and speciation in soils affected by historic mercury mining. Water Air Soil Pollut 200:89–99Google Scholar
  133. Hollings P, Hendry MJ, Nicholson RV, Kirkland RA (2001) Quantification of oxygen consumption and sulphate release rates for waste rock piles using kinetic cells; Cluff lake uranium mine, northern Saskatchewan, Canada. Appl Geochem 16:1215–1230Google Scholar
  134. Holmström H, Ljungberg J, Ekström M, Öhlander B (1999) Secondary copper enrichment in tailings at the Laver mine, northern Sweden. Environ Geol 38:327–342Google Scholar
  135. Huang X, Evangelou VP (1994) Suppression of pyrite oxidation rate by phosphate addition: In: Alpers CN, Blowes DW (eds) Environmental geochemistry of sulfide oxidation. American Chemical Society Symposium Series 550, Washington, DC, pp 562–573Google Scholar
  136. Hudson-Edwards KA, Schell C, Macklin MG (1999) Mineralogy and geochemistry of alluvium contaminated by metal mining in the Rio Tinto area, southwest Spain. Appl Geochem 14:1015–1030Google Scholar
  137. Hudson-Edwards KA, Edwards SJ (2005) Mineralogical controls on storage of As, Cu, Pb and Zn at the abandoned Mathiatis massive sulphide mine, Cyprus. Mineral Mag 69:695–706Google Scholar
  138. Hughes J, Craw D, Peake B, Lindsay P, Weber P (2007) Environmental characterization of coal mine waste rock in the field: an example from New Zealand. Environ Geol 52:1501–1509Google Scholar
  139. Hulshof AHM, Blowes DW, Gould WD (2006) Evaluation of in situ layers for treatment of acid mine drainage: a field comparison. Water Res 40:1816–1826Google Scholar
  140. Hutchison I, Ellison R (1992) Mine waste management. Lewis Publishers, Boca RatonGoogle Scholar
  141. Ibrahim KM, Jaber JO (2007) Geochemistry and environmental impacts of retorted oil shale from Jordan. Environ Geol 52:979–984Google Scholar
  142. Jambor JL (1994) Mineralogy of sulfide-rich tailings and their oxidation products. In: Jambor JL, Blowes DW (eds) Environmental geochemistry of sulfide mine-wastes, vol 22. Mineralogical Association of Canada, Nepean, pp 59–102 (Short course handbook)Google Scholar
  143. Jambor JL (2000) The relationship of mineralogy to acid- and neutralization-potential values in ARD. In: Cotter-Howells JD, Campbell LS, Valsami-Jones E, Batchelder M (eds) Environmental mineralogy; microbial interactions, anthropogenic influences, contaminated land and waste management. Mineralogical Society Series no 9. Mineralogical Society, London, pp 141–159Google Scholar
  144. Jambor JL (2003) Mine-waste mineralogy and mineralogical perspectives of acid-base accounting. In: Jambor JL, Blowes DW, Ritchie AIM (eds) Environmental aspects of mine wastes, vol 31. Mineralogical Association of Canada, Nepean, pp 117–145 (Short course handbook)Google Scholar
  145. Jambor JL, Nordstrom DK, Alpers CN (2000a) Metal sulfate salts from sulfide mineral oxidation. In: Alpers CN, Jambor JL, Nordstrom (eds) Sulfate minerals; crystallography, geochemistry and environmental significance, vol 40. Mineralogical Society of America, Washington, DC, pp 303–350 (Reviews in mineralogy and geochemistry)Google Scholar
  146. Jambor JL, Dutrizac JE, Chen TT (2000c) Contribution of specific minerals to the neutralization potential in static tests. In: Proceedings from the 5th international conference on acid rock drainage, vol 1. Society for Mining, Metallurgy, and Exploration, Littleton, pp 551–565Google Scholar
  147. Jambor JL, Dutrizac JE, Raudsepp M, Groat LA (2003) Effect of peroxide on neutralization-potential values of siderite and other carbonate minerals. J Environ Qual 32:2373–2378Google Scholar
  148. Jambor JL, Dutrizac JE, Raudsepp M (2007) Measured and computed neutralization potentials from static tests of diverse rock types. Environ Geol 52:1019–1031Google Scholar
  149. Janzen MP, Nicholson RV, Scharper JM (2000) Pyrrhotite reaction kinetics; reaction rates for oxidation by oxygen, ferric iron, and for nonoxidative dissolution. Geochim Cosmochim Acta 64:1511–1522Google Scholar
  150. Jennings SR, Dollhopf DJ, Inskeep WP (2000) Acid production from sulfide minerals using hydrogen peroxide weathering. Appl Geochem 15:235–243Google Scholar
  151. Jerz JK, Rimstidt JD (2003) Efflorescent iron sulfate minerals: paragenesis, relative stability, and environmental impact. Am Mineral 88:1919–1932Google Scholar
  152. Jiménez-Cárceles FJ, Álvarez-Rogel J, Alcaraz HM (2008) Trace element concentrations in saltmarsh soils strongly affected by wastes from metal sulphide mining areas. Water Air Soil Poll 188:283–295Google Scholar
  153. Jin S, Fallgren PH, Morris JM, Gossard RB (2008a) Biological source treatment of acid mine drainage using microbial and substrate amendments: microcosm studies. Mine Water Environ 27:20–30Google Scholar
  154. Jones RA, Koval SF, Nesbitt HW (2003) Surface alteration of arsenopyrite (FeAsS) by Thiobacillus ferrooxidans. Geochim Cosmochim Acta 67:955–965Google Scholar
  155. Johnson DB (1998a) Biological abatement of acid mine drainage: the role of acidophilic protozoa and other indigenous microflora. In: Geller W, Klapper H, Salomons W (eds) Acidic mining lakes. Springer, Heidelberg, pp 285–301Google Scholar
  156. Kalin M, Harris B (2005) Chemical precipitates within pyritic waste rock. Hydrometallurgy 78:209–225Google Scholar
  157. Kargbo DM, He J (2004) A simple accelerated rock weathering method to predict acid generation kinetics. Environ Geol 46:775–783Google Scholar
  158. Karpenko V, Norris JA (2002) Vitriol in the history of chemistry. Chem Listy 96:997–1005Google Scholar
  159. Keith CN, Vaughan DJ (2000) Mechanisms and rates of sulphide oxidation in relation to the problems of acid rock (mine) drainage. In: Cotter-Howells JD, Campbell LS, Valsami-Jones E, Batchelder M (eds) Environmental mineralogy; microbial interactions, anthropogenic influences, contaminated land and waste management. Mineralogical Society Series no 9. Mineralogical Society, London, pp 117–139Google Scholar
  160. Kelepertsis A, Argyraki A, Alexakis D (2006) Multivariate statistics and spatial interpretation of geochemical data for assessing soil contamination by potentially toxic elements in the mining area of Stratoni, north Greece. Geochem Explor Environ Anal 6:349–355Google Scholar
  161. Kelly DP, Wood AP (2000) Reclassification of some species of Thiobacillus to the newly designated genera Acidithiobacillus gen. nov., Halothiobacillus gen. nov. and Thermithiobacillus gen. nov. Int J Syst Evol Microbiol 50:511–516Google Scholar
  162. Kierczak J, Néel C, Puziewicz J, Bril H (2009) The mineralogy and weathering of slag produced by the smelting of lateritic Ni ores, Szklary, southwestern Poland. Can Mineral 47:557–572Google Scholar
  163. Kilgour DW, Moseley RB, Barnett MO, Savage KS, Jardine PM (2008) Potential negative consequences of adding phosphorus-based fertilizers to immobilize lead in soil. J Environ Qual 35:1733–1740Google Scholar
  164. Kim H, Benson CH (2004) Contributions of advective and diffusive oxygen transport through multilayer composite caps over mine waste. J Contam Hydrol 71:193–218Google Scholar
  165. Kleinmann RLP (1997) Mine drainage systems. In: Marcus JJ (ed) Mining environmental handbook: effects of mining on the environment and American environmental controls on mining. Imperial College Press, London, pp 237–244Google Scholar
  166. Kleinmann RLP (1998) Bactericidal control of acidic drainage. In: Coal mine drainage prediction and pollution prevention in Pennsylvania. The Pennsylvania Department of Environmental Protection, Chapter 15, pp 15–1 to 15–6Google Scholar
  167. Kock D, Schippers A (2006) Geomicrobiological investigation of two different mine waste tailings generating acid mine drainage. Hydrometallurgy 83:167–175Google Scholar
  168. Kolker A, Huggins FE (2007) Progressive oxidation of pyrite in five bituminous coal samples: an As XANES and Fe Mössbauer spectroscopic study. Appl Geochem 22:778–787Google Scholar
  169. Koski RA, Munk L, Foster AL, Shanks WC III, Stillings LL (2008) Sulfide oxidation and distribution of metals near abandoned copper mines in coastal environments, Prince William Sound, Alaska, USA. Appl Geochem 23:227–254Google Scholar
  170. Kucha H , Martens A, Ottenburgs R, De Vos W, Viaene W (1996) Primary minerals of Zn-Pb mining and metallurgical dumps and their environmental behavior at Plombieres, Belgium. Environ Geol 27:1–15Google Scholar
  171. Kuechler R, Noack K (2007) Comparison of the solution behavior of a pyrite-calcite mixture in batch and unsaturated sand column. J Contam Hydrol 90:203–220Google Scholar
  172. Kwong YTJ (1993) Mine site acid rock drainage assessment and prevention; a new challenge for a mining geologist. In: Proceedings of the international mining geology conference, Kalgoorlie, pp 213–217Google Scholar
  173. Kwong YTJ, Swerhone GW, Lawrence JR (2003) Galvanic sulphide oxidation as a metal-leaching mechanism and its environmental implications. Geochem Explor Environ Anal 3:337–343Google Scholar
  174. Langmuir D (1997) Aqueous environmental geochemistry. Prentice Hall, Upper Saddle RiverGoogle Scholar
  175. Lasaga AC, Berner RA (1998) Fundamental aspects of quantitative models for geochemical cycles. Chem Geol 145:161–175Google Scholar
  176. Lavergren U, Åström ME, Bergbäck B, Holmström H (2009) Mobility of trace elements in black shale assessed by leaching tests and sequential chemical extraction. Geochem Explor Environ Anal 9:71–79Google Scholar
  177. Lawrence RW, Scheske M (1997) A method to calculate the neutralization potential of mining wastes. Environ Geol 32:100–106Google Scholar
  178. Ledin M, Pedersen K (1996) The environmental impact of mine wastes; roles of microorganisms and their significance in treatment of mine wastes. Earth-Sci Rev 41:67–108Google Scholar
  179. Lee CSL, Qi SH, Zhang G, Luo CL, Zhao LYL, Li XD (2008) Seven thousand years of records on the mining and utilization of metals from lake sediments in central China. Environ Sci Technol 42:4732–4738Google Scholar
  180. Lehner S, Savage K (2008) The effect of As, Co, and Ni impurities on pyrite oxidation kinetics: batch and flow-through reactor experiments with synthetic pyrite. Geochim Cosmochim Acta 72:1788–1800Google Scholar
  181. Lehner S, Savage K, Ciobanu M, Cliffel DE (2007) The effect of As, Co, and Ni impurities on pyrite oxidation kinetics: an electrochemical study of synthetic pyrite. Geochim Cosmochim Acta 71:2491–2509Google Scholar
  182. Lengke MF, Tempel RN (2003) Natural realgar and amorphous AsS oxidation kinetics. Geochim Cosmochim Acta 67:859–871Google Scholar
  183. Lengke MF, Sanpawanitchakit C, Tempel RN (2009) The oxidation and dissolution of arsenic-bearing sulfides. Can Mineral 47:593–613Google Scholar
  184. Li J, Xie ZM, Xu JM, Sun YF (2006) Risk assessment for safety of soils and vegetables around a lead/zinc mine. Environ Geochem Health 28:37–44Google Scholar
  185. Li J, Smart RSC, Schumann RC, Gerson AR, Levay G (2007a) A simplified method for estimation of jarosite and acid-forming sulfates in acid mine wastes. Sci Total Environ 373:391–403Google Scholar
  186. Li MG, St-Arnoud L (1997) Hydrogeochemistry of secondary mineral dissolution: column leaching experiment using oxidized waste rock. In: Proceedings of the 4th international conference on acid rock drainage, vol 1. Vancouver, pp 465–477Google Scholar
  187. Liao B, Huang LN, Ye ZH, Lan CY, Shu WS (2007) Cut-off net acid generation pH in predicting acid-forming potential in mine spoils. J Environ Qual 36:887–891Google Scholar
  188. Lim HS, Lee JS, Chon HT, Sager M (2008) Heavy metal contamination and health risk assessment in the vicinity of the abandoned Songcheon Au-Ag mine in Korea. J Geochem Explor 96:223–230Google Scholar
  189. Lin Z (1997) Mineralogical and chemical characterization of wastes from the sulfuric acid industry in Falun, Sweden. Environ Geol 30:152–162Google Scholar
  190. Lin Z, Herbert RB Jr (1997) Heavy metal retention in secondary precipitates from a mine rock dump and underlying soil, Dalarna, Sweden. Environ Geol 33:1–12Google Scholar
  191. Linklater CM, Sinclair DJ, Brown PL (2005) Coupled chemistry and transport modeling of sulphidic waste rock dumps at the Aitik mine site, Sweden. Appl Geochem 20:275–293Google Scholar
  192. Liu J, Aruguete DM, Jinschek JR, Rimstidt JD, Hochella MF Jr (2008a) The non-oxidative dissolution of galena nanocrystals: insights into mineral dissolution rates as a function of grain size, shape, and aggregation state. Geochim Cosmochim Acta 72:5984–5996Google Scholar
  193. Liu Q, Li H, Zhou L (2008b) Galvanic interactions between metal sulfide minerals in a flowing system: implications for mines environmental restoration. Appl Geochem 23:2316–2323Google Scholar
  194. Liu R, Wolfe AL, Dzombak DA, Horwitz CP, Stewart BW, Capo RC (2008c) Electrochemical study of hydrothermal and sedimentary pyrite dissolution. Appl Geochem 23:2724–2734Google Scholar
  195. Liu R, Wolfe AL, Dzombak DA, Stewart BW, Capo RC (2008d) Comparison of dissolution under oxic acid drainage conditions for eight sedimentary and hydrothermal pyrite samples. Environ Geol 56:171–182Google Scholar
  196. Loredo J, Ordonez A, Gallego JR, Baldo C, Garcia-Iglesias J (1999) Geochemical characterisation of mercury mining spoil heaps in the area of Mieres (Asturias, northern Spain). J Geochem Explor 67:377–390Google Scholar
  197. Loredo J, Álvarez R, Ordóñez A, Bros T (2008) Mineralogy and geochemistry of the Texeo Cu-CO mine site (NW Spain): screening tools for environmental assessment. Environ Geol 55:1299–1310Google Scholar
  198. Lottermoser BG (2002) Mobilization of heavy metals from historical smelting slag dumps, north Queensland, Australia. Mineral Mag 66:475–490Google Scholar
  199. Lottermoser BG (2005) Evaporative mineral precipitates from a historical smelting slag dump, Río Tinto, Spain. Neues Jb Miner Abh 181:183–190Google Scholar
  200. Lottermoser BG, Ashley PM (2006a) Mobility and retention of trace elements in hardpan-cemented cassiterite tailings, north Queensland, Australia. Environ Geol 50:835–846Google Scholar
  201. Lottermoser BG, Ashley PM, Lawie DC (1999) Environmental geochemistry of the Gulf Creek copper mine area, northeastern New South Wales, Australia. Environ Geol 39:61–74Google Scholar
  202. Lottermoser BG, Ashley PM, Munksgaard NC (2008) Biogeochemistry of Pb-Zn gossans, northwest Queensland, Australia: implications for mineral exploration and mine site rehabilitation. Appl Geochem 23:723–742Google Scholar
  203. Lu L, Wang R, Chen F, Xue J, Zhang P, Lu J (2005) Element mobility during pyrite weathering; implications for acid and heavy metal pollution at mining-impacted sites. Environ Geol 49:82–89Google Scholar
  204. Lundgren T (2001) The dynamics of oxygen transport into soil covered mining waste deposits in Sweden. J Geochem Explor 74:163–173Google Scholar
  205. Luther GW (1987) Pyrite oxidation and reduction; molecular orbital theory considerations. Geochim Cosmochim Acta 51:3193–3199Google Scholar
  206. Malmström ME, Gleisner M, Herbert RB (2006) Element discharge from pyritic mine tailings at limited oxygen availability in column experiments. Appl Geochem 21:184–202Google Scholar
  207. Marescotti P, Carbone C, De Capitani L, Grieco G, Lucchetti G, Servida D (2008) Mineralogical and geochemical characterization of open-air tailing and waste-rock dumps from the Libiola Fe-Cu sulphide mine (Eastern Liguria, Italy). Environ Geol 53:1613–1626Google Scholar
  208. Martínez-Ruiz C, Fernández-Santos B, Putwain PD, Fernández-Gómez MJ (2007) Natural and man-induced revegetation on mining wastes: changes in the floristic composition during early succession. Ecol Eng 30:286–294Google Scholar
  209. Martínez López J, Llamas Borrajo J, de Miguel García E, Rey Arrans J, Hidalgo Estévez MC, Sáez Castillo AJ (2008) Multivariate analysis of contamination in the mining district of Linares (Jaén, Spain). Appl Geochem 23:2324–2336Google Scholar
  210. Masalehdani MNN, Mees F, Dubois M, Coquinot Y, Potdevin JL, Fialin M, Blanc-Valleron MM (2009) Condensate minerals from a burning coal-waste heap in Avion, Northern France. Can Mineral 47:573–591Google Scholar
  211. Mathews WH, Bustin RM (1984) Why do the Smoking Hills smoke? Can J Earth Sci 21:737–742Google Scholar
  212. Matlock MM, Howerton BS, Atwood DA (2003) Covalent coating of coal refuse to inhibit leaching. Adv Environ Res 7:495–501Google Scholar
  213. McKibben MA, Tallant BA, del Angel JK (2008) Kinetics of inorganic arsenopyrite oxidation in acidic aqueous solutions. Appl Geochem 23:121–135Google Scholar
  214. McSweeney K, Madison FW (1988) Formation of a cemented subsurface horizon in sulfidic minewaste. J Environ Qual 17:256–262Google Scholar
  215. Miller JR, Lechler PJ, Mackin G, Germanoski D, Villarroel LF (2007) Evaluation of particle dispersal from mining and milling operations using lead isotopic fingerprinting techniques, Rio Pilcomayo Basin, Bolivia. Sci Total Environ 384:355–373Google Scholar
  216. Miller SD (1995) Geochemical indicators of sulfide oxidation and acid generation in the field. In: Grundon NJ, Bell LC (eds) Proceedings of the 2nd Australian acid mine drainage workshop. Australian Centre for Minesite Rehabilitation Research, Brisbane, pp 117–120Google Scholar
  217. Miller SD (1996) Advances in acid drainage: prediction and implications for risk management. In: Proceedings of 3rd international and 21st annual Minerals Council of Australia environmental workshop, vol 1. Minerals Council of Australia, Dickson, pp 149–157Google Scholar
  218. Miller SD (1998b) Theory, design and operation of covers for controlling sulfide oxidation in waste rock dumps. In: McLean RW, Bell LC (eds) Proceedings of the 3rd Australian acid mine drainage workshop. Australian Centre for Minesite Rehabilitation Research, Brisbane, pp 115–126Google Scholar
  219. Mitchell P (2000) Prediction, prevention, control and treatment of acid rock drainage. In: Warhurst A, Noronha L (eds) Environmental policy in mining; corporate strategy and planning for closure. Lewis Publishers, Boca Raton, pp 117–143Google Scholar
  220. Mlayah A, Ferreira da Silva E, Rocha F, Ben Hamza C, Charef A, Noronha F (2009) The Oued Mellègue: mining activity, stream sediments and dispersion of base metals in natural environments, North-western Tunisia. J Geochem Explor 102:27–36Google Scholar
  221. Modis K, Komnitsas K (2007) Optimum sampling density for the prediction of acid mine drainage in an underground sulphide mine. Mine Water Environ 26:237–242Google Scholar
  222. Molina JA, Oyarzun R, Esbrí JM, Higueras P (2006) Mercury accumulation in soils and plants in the Almadén mining district, Spain: one of the most contaminated sites on Earth. Environ Geochem Health 28:487–498Google Scholar
  223. Moncur MC, Ptacek CJ, Blowes DW, Jambor JL (2005) Release, transport and attenuation of metals from an old tailings impoundment. Appl Geochem 20:639–659Google Scholar
  224. Moncur MC, Jambor JL, Ptacek CJ, Blowes DW (2009) Mine drainage from the weathering of sulfide minerals and magnetite. Appl Geochem 24:2362–2373Google Scholar
  225. Morin KA, Hutt NM (1997) Environmental geochemistry of minesite drainage. MDAG Publication, VancouverGoogle Scholar
  226. Morrison AL, Gulson BL (2007) Preliminary findings of chemistry and bioaccessibility in base metal smelter slags. Sci Total Environ 382:30–42Google Scholar
  227. Müller N, Franke K, Schreck P, Hirsch D (2008) Georadiochemical evidence to weathering of mining residues of the Mansfeld mining district, Germany. Environ Geol 54:869–877Google Scholar
  228. Munk LA, Faure G, Koski R (2006) Geochemical evolution of solutions derived from experimental weathering of sulfide-bearing rocks. Appl Geochem 21:1123–1134Google Scholar
  229. Munroe EA, McLemore VT, Kyle P (1999) Waste rock pile characterization, heterogeneity, and geochemical anomalies in the Hillsboro Mining District, Sierra County, New Mexico. J Geochem Explor 67:391–405Google Scholar
  230. Murad E, Schwertmann U, Bigham JM, Carlson L (1994) Mineralogical characteristics of poorly crystallized precipitates formed by oxidation of Fe2+ in acid sulfate waters. In: Alpers CN, Blowes DW (eds) Environmental geochemistry of sulfide oxidation. American Chemical Society Symposium Series 550, Washington, DC, pp 190–200Google Scholar
  231. Natarajan KA, Subramanian S, Braun JJ (2006) Environmental impact of metal mining – biotechnological aspects of water pollution and remediation – an Indian experience. J Geochem Explor 88:45–48Google Scholar
  232. Navarro A, Cardellach E, Mendoza JL, Corbella M, Domènech LM (2008a) Metal mobilization from base-metal smelting slag dumps in Sierra Almagrera (Almería, Spain). Appl Geochem 23:895–913Google Scholar
  233. Navarro MC, Pérez-Sirvent C, Martínez-Sánchez MJ, Vidal J, Tovar PJ, Bech J (2008b) Abandoned mine sites as a source of contamination by heavy metals: a case study in a semi-arid zone. J Geochem Explor 96:183–193Google Scholar
  234. Ngoc KC, Nguyen NV, Dinh BN, Thanh SL, Tanaka S, Kang Y, Sakurai K, Iwasaki K (2009) Arsenic and heavy metal concentrations in agricultural soils around tin and tungsten mines in the Dai Tu district, N Vietnam. Water Air Soil Poll 197:75–89Google Scholar
  235. Nicholson RV, Scharer JM (1994) Laboratory studies of pyrrhotite oxidation kinetics. In: Alpers CN, Blowes DW (eds) Environmental geochemistry of sulfide oxidation. American Chemical Society Symposium Series 550, Washington, DC, pp 14–30Google Scholar
  236. Nicholson RV, Gillham RW, Reardon EJ (1990) Pyrite oxidation in carbonate-buffered solution; 2. Rate control by oxide coatings. Geochim Cosmochim Acta 54:395–402Google Scholar
  237. Nordstrom DK, Alpers CN (1999a) Geochemistry of acid mine waters. In: Plumlee GS, Logsdon MS (eds) The environmental geochemistry of mineral deposits. Part A: processes, techniques and health issues, vol 6A. Society of Economic Geologists, Littleton, pp 133–160 (Reviews in economic geology)Google Scholar
  238. Nugraha C, Shimada H, Sasaoka T, Ichinose M, Matsui K, Manege I (2009) Geochemistry of waste rock at dumping area. Int J Min Reclam Environ 23:132–143Google Scholar
  239. Oerter EJ, Brimhall GH Jr, Redmond J, Walker B (2007) A method for quantitative pyrite abundance in mine rock piles by powder X-ray diffraction and Rietveld refinement. Appl Geochem 22:2907–2925Google Scholar
  240. Ollier CD, Pain CF (1997) Regolith, soils and landforms. Wiley, New YorkGoogle Scholar
  241. Ostergren JD, Brown GE, Parks GA, Tingle TN (1999) Quantitative speciation of lead in selected mine tailings from Leadville, CO. Environ Sci Technol 33:1627–1636Google Scholar
  242. Oyarzun R, Cubas P, Higueras P, Lillo J, Llanos W (2009) Environmental assessment of the arsenic-rich, Rodalquilar gold–(copper-lead-zinc) mining district, SE Spain: data from soils and vegetation. Environ Geol 58:761–777Google Scholar
  243. Pagnanelli F, Luigi M, Mainelli S, Toro L (2007) Use of natural materials for the inhibition of iron oxidizing bacteria involved in the generation of acid mine drainage. Hydrometallurgy 87:27–35Google Scholar
  244. Paktunc AD (1999) Mineralogical constraints on the determination of neutralization potential and prediction of acid mine drainage. Environ Geol 39:103–112Google Scholar
  245. Parker G (1999) A critical review of acid generation resulting from sulfide oxidation: processes, treatment and control. In: Acid Drainage. Australian Minerals & Energy Environment Foundation, Melbourne, occasional paper no 11, pp 1–182Google Scholar
  246. Parsons MB, Bird DK, Einaudi MT, Alpers CN (2001) Geochemical and mineralogical controls on trace element release from the Penn Mine base-metal slag dump, California. Appl Geochem 16:1567–1593Google Scholar
  247. Pedersen TF, McNee JJ, Flather DH, Mueller B, Pelletier CA (1998) Geochemical behaviour of submerged pyrite-rich tailings in Canadian lakes. In: Geller W, Klapper H, Salomons W (eds) Acidic mining lakes. Springer, Heidelberg, pp 87–125Google Scholar
  248. Peng B, Piestrzynski A, Pieczonka J, Xiao M, Wang Y, Xie S, Tang X, Yu C, Song Z (2007) Mineralogical and geochemical constraints on environmental impacts from waste rock at Taojiang Mn-ore deposit, central Hunan, China. Environ Geol 52:1277–1296Google Scholar
  249. Pérez-López R, Nieto JM, Álvarez-Valero AM, Ruiz de Almodóvar G (2007a) Mineralogy of the hardpan formation processes in the interface between sulfide-rich sludge and fly ash: applications for acid mine drainage mitigation. Amer Mineral 92:1966–1977Google Scholar
  250. Pérez-López R, Álvarez-Valero AM, Nieto JM, Sáez R, Matos JX (2008) Use of sequential extraction procedure for assessing the environmental impact at regional scale of the Sao Domingos Mine (Iberian Pyrite Belt). Appl Geochem 23:3452–3463Google Scholar
  251. Petrunic BM, Al TA, Weaver L, Hall D (2009) Identification and characterization of secondary minerals formed in tungsten mine tailings using transmission electron microscopy. Appl Geochem 24:2222–2233Google Scholar
  252. Piatak NM, Seal RR, Hammarstrom JM (2004) Mineralogical and geochemical controls on the release of trace elements from slag produced by base- and precious-metal smelting at abandoned mine sites. Appl Geochem 19:1039–1064Google Scholar
  253. Pirrie D, Camm GS, Sear LG, Hughes SH (1997) Mineralogical and geochemical signature of mine waste contamination, Tresillian River, Fal Estuary, Cornwall, UK. Environ Geol 29:58–65Google Scholar
  254. Plumlee GS (1999) The environmental geology of mineral deposits. In: Plumlee GS, Logsdon MS (eds) The environmental geochemistry of mineral deposits. Part A: processes, techniques and health issues, vol 6A. Society of Economic Geologists, Littleton, pp 71–116 (Reviews in economic geology)Google Scholar
  255. Pond AP, White SA, Milczarek M, Thompson TL (2005) Accelerated weathering of biosolid-amended copper mine tailings. J Environ Qual 34:1293–1301Google Scholar
  256. Price WA, Morin K, Hutt N (1997) Guidelines for the prediction of acid rock drainage Part II. Recommended procedures for static and kinetic testing. In: Proceedings from the 4th international conference on acid rock drainage, vol 1. Vancouver, pp 15–30Google Scholar
  257. Ptacek CJ, Blowes DW (1994) Influence of siderite on the pore-water chemistry of inactive mine-tailings impoundments. In: Alpers CN, Blowes DW (eds) Environmental geochemistry of sulfide oxidation. American Chemical Society Symposium Series 550, Washington, DC, pp 172–189Google Scholar
  258. Puura E, Neretnieks I (2000) Atmospheric oxidation of the pyritic waste rock in Maardu, Estonia. 2. An assessment of aluminosilicate buffering potential. Environ Geol 39:560–566Google Scholar
  259. Puura E, Neretnieks I, Kirsimäe K (1999) Atmospheric oxidation of the pyritic waste rock in Maardu, Estonia. 1. Field study and modelling. Environ Geol 39:1–19Google Scholar
  260. Puziewicz J, Zainoun K, Bril H (2007) Primary phases in pyrometallurgical slags from a zinc-smelting waste dump, Swiętochłowice, Upper Silesia, Poland. Can Mineral 45:1189–1200Google Scholar
  261. Qi C, Liu G, Chou CL, Zheng L (2008) Environmental geochemistry of antimony in Chinese coals. Sci Total Environ 389:225–234Google Scholar
  262. Rapant S, Dietzová Z, Cicmanová S (2006) Environmental and health risk assessment in abandoned mining area, Zlata Idka, Slovakia. Environ Geol 51:387–397Google Scholar
  263. Reglero MM, Monsalve-González L, Taggart MA, Mateo R (2008) Transfer of metals to plants and red deer in an old lead mining area in Spain. Sci Total Environ 406:287–297Google Scholar
  264. Rimstidt JD, Vaughan DJ (2003) Pyrite oxidation: a state-of-the-art assessment of the reaction mechanism. Geochim Cosmochim Acta 67:873–880Google Scholar
  265. Rimstidt JD, Chermak JA, Gagen PM (1994) Rates of reaction of galena, sphalerite, chalcopyrite and arsenopyrite with Fe(III) in acidic solutions. In: Alpers CN, Blowes DW (eds) Environmental geochemistry of sulfide oxidation. American Chemical Society Symposium Series 550, Washington, DC, pp 2–13Google Scholar
  266. Ritchie AIM (1994a) The waste-rock environment. In: Jambor JL, Blowes DW (eds) Environmental geochemistry of sulfide mine-wastes, vol 22. Mineralogical Association of Canada, Nepean, pp 133–161 (Short course handbook)Google Scholar
  267. Ritchie AIM (1994b) Sulfide oxidation mechanisms; controls and rates of oxygen transport. In: Jambor JL, Blowes DW (eds) Environmental geochemistry of sulfide mine-wastes, vol 22. Mineralogical Association of Canada, Nepean, pp 201–245 (Short course handbook)Google Scholar
  268. Ritchie AIM (1995) Application of oxidation rates in rehabilitation design. In: Grundon NJ, Bell LC (eds) Proceedings of the 2nd Australian acid mine drainage workshop. Australian Centre for Minesite Rehabilitation Research, Brisbane, pp 101–116Google Scholar
  269. Romano P, Blazquez ML, Alguacil FJ, Munoz JA, Ballester A, Gonzalez F (2001) Comparitive study on the selective chalcopyrite bioleaching of a molybdenite concentrate with mesophilic and thermophilic bacteria. FEMS Microbiol Lett 196:71–75Google Scholar
  270. Rosado, L, Morais C, Candeias AE, Pinto AP, Guimarães F, Mirão J (2008) Weathering of S. Domingos (Iberian Pyritic Belt) abandoned mine slags. Mineral Mag 72:489–494Google Scholar
  271. Rozalén ML, Huertas FJ, Brady PV, Cama J, García-Palma S, Linares J (2008) Experimental study of the effect of pH on the kinetics of montmorillonite dissolution at 25˚C. Geochim Cosmochim Acta 72:4224–4253Google Scholar
  272. Ruby MV, Davis A, Nicholson A (1994) In situ formation of lead phosphates in soils as a method to immobilize lead. Environ Sci Technol 28:646–654Google Scholar
  273. Rufo L, Rodríguez N, Amils R, de la Fuente V, Jiménez-Ballesta R (2007) Surface geochemistry of soils associated to the Tinto River (Huelva, Spain). Sci Total Environ 378:223–227Google Scholar
  274. Salkield LU (1987) A technical history of the Rio Tinto mines: some notes on exploitation from pre-Phoenician times to the 1950 s. The Institution of Mining and Metallurgy, LondonGoogle Scholar
  275. Salmon SU, Malmström ME (2006) Quantification of mineral dissolution rates and applicability of rate laws: laboratory studies of mill tailings. Appl Geochem 21:269–288Google Scholar
  276. Salomons W (1995) Environmental impact of metals derived from mining activities; processes, predictions, prevention. J Geochem Explor 52:5–23Google Scholar
  277. Sams JI, Veloski GA (2003) Evaluation of airborne thermal infrared imagery for locating mine drainage sites in the Lower Kettle Creek and Cook Run Basins, Pennsylvania, USA. Mine Water Environ 22:85–93Google Scholar
  278. Sams JI, Veloski GA, Ackman TE (2003) Evaluation of airborne thermal infrared imagery for locating mine drainage sites in the lower Youghiogheny River Basin, Pennsylvania, USA. Mine Water Environ 22:94–103Google Scholar
  279. Sánchez España JS, Pamo EL, Pastor ES (2007) The oxidation of ferrous iron in acidic mine effluents from the Iberian Pyrite Belt (Odiel Basin, Huelva, Spain): field and laboratory rates. J Geochem Explor 92:120–132Google Scholar
  280. Sánchez España JS, Toril EG, López Pamo E, Amils R, Ercilla MD, Pastor ES, Martin-Úriz PS (2008a) Biogeochemistry of a hyperacidic and ultraconcentrated pyrite leachate in San Telmo mine (Iberian Pyrite Belt, Spain). Water Air Soil Poll 194:243–257Google Scholar
  281. Sand W, Jozsa PG, Kovacs ZM, Săsăran N, Schippers A (2007) Long-term evaluation of acid rock drainage mitigation measures in large lysimeters. J Geochem Explor 92:2005–211Google Scholar
  282. Sato M (1992) Persistency-field Eh-pH diagrams for sulfides and their application to supergene oxidation and enrichment of sulfide ore bodies. Geochim Cosmochim Acta 56:3133–3156Google Scholar
  283. Schaaf W, Hüttl RF (2006) Direct and indirect effects of soil pollution by lignite mining. Water Air Soil Poll: Foc 6:353–364Google Scholar
  284. Schaider LA, Senn DB, Brabander DJ, McCarthy KD, Shine JP (2007) Characterization of zinc, lead, and cadmium in mine waste: implications for transport, exposure, and bioavailability. Environ Sci Technol 41:4164–4171Google Scholar
  285. Schippers A, Sand W (1999) Bacterial leaching of metal sulfides proceeds by two indirect mechanisms via thiosulfate or via polysulfides and sulfur. Appl Environ Microbiol 65:319–321Google Scholar
  286. Schippers A, Kock D, Schwartz M, Bottcher ME, Vogel H, Hagger M (2007) Geomicrobiological and geochemical investigation of a pyrrhotite-containing mine waste tailings dam near Selebi-Phikwe in Botswana. J Geochem Explor 92:151–158Google Scholar
  287. Schrenk MO, Edwards KJ, Goodman RM, Hamers RJ, Banfield JF (1998) Distribution of Thiobacillus ferrooxidans and Leptospirillum ferrooxidans: implications for generation of acid mine drainage. Science 279:1519–1522Google Scholar
  288. Schubert M, Osenbrück K, Knöller K (2008) Using stable and radioactive isotopes for the investigation of contaminant metal mobilization in a metal mining district. Appl Geochem 23:2945–2954Google Scholar
  289. Schuwirth N, Voegelin A, Kretzschmar R, Hofmann T (2007) Vertical distribution and speciation of trace metals in weathering flotation residues of a zinc/lead sulfide mine. J Environ Qual 36:61–99Google Scholar
  290. Seignez N, Gauthier A, Bulteel D, Damidot D, Potdevin JL (2008) Leaching of lead metallurgical slags and pollutant mobility far from equilibrium conditions. Appl Geochem 23:3699–3711Google Scholar
  291. Shaw SA, Hendry MJ (2009) Geochemical and mineralogical impacts of H2SO4 on clays between pH 5.0 and -3.0. Appl Geochem 24:333–345Google Scholar
  292. Shay DA, Cellan RR (2000) Use of a chemical cap to remediate acid rock conditions at Homestake’s Santa Fe mine. In: Tailings and mine waste ’00. Balkema, Rotterdam, pp 203–210Google Scholar
  293. Sherlock EJ, Lawrence RW, Poulin R (1995) On the neutralization of acid rock drainage by carbonate and silicate minerals. Environ Geol 25:43–54Google Scholar
  294. Shevade AV, Erickson L, Pierzynski G, Jiang S (2001) Formation and stability of substituted pyromorphite: a molecular modeling study. J Hazard Subst Res 3:2–1 to 2–12Google Scholar
  295. Shipitalo MJ, Bonta JV (2008) Impact of using paper mill sludge for surface-mine reclamation on runoff water quality and plant growth. J Environ Qual 37:2351–2359Google Scholar
  296. Sidenko NV, Gieré R, Bortnikova SB, Cottard F, Pal’chik NA (2001) Mobility of heavy metals in self-burning waste heaps of the zinc smelting plant in Belovo (Kemerovo Region, Russia). J Geochem Explor 74:109–125Google Scholar
  297. Sidenko NV, Khozhina EI, Sherriff BL (2007) The cycling of Ni, Zn, Cu in the system “mine tailings – ground water – plants”: a case study. Appl Geochem 22:30–52Google Scholar
  298. Singer PC, Stumm W (1970) Acid mine drainage: rate-determining step. Science 167:1121–1123Google Scholar
  299. Skousen J, Renton J, Brown H, Evans P, Leavitt B, Brady K, Cohen L, Ziemkiewicz P (1997) Neutralization potential of overburden samples containing siderite. J Environ Qual 26:673–681Google Scholar
  300. Skousen J, Simmons J, McDonald LM, Ziemkiewicz P (2002) Acid-base accounting to predict post-mining drainage quality on surface mines. J Environ Qual 31:2034–2044Google Scholar
  301. Slowey AJ, Johnson SB, Newville M, Brown GE Jr (2007) Speciation and colloid transport of arsenic from mine tailings. Appl Geochem 22:1884–1898Google Scholar
  302. Smart R, Skinner B, Levay G, Gerson A, Thomas J, Sobieraj H, Schumann R, Weisener C, Weber P, Miller S, Stewart W (2002) ARD testbook. Project P387A prediction and kinetic control of acid mine drainage. AMIRA International, MelbourneGoogle Scholar
  303. Smith A, Robertson A, Barton-Bridges J, Hutchison IPG (1992) Prediction of acid generation potential. In: Hutchison IPG, Ellison RD (eds) Mine waste management. Lewis Publishers, Boca Raton, pp 123–199Google Scholar
  304. Smith AML, Hudson-Edwards KA, Dubbin WE, Wright K (2006) Dissolution of jarosite [KFe3(SO4)2(OH)2] at pH 2 and 8; insights from batch experiments and computational modelling. Geochim Cosmochim Acta 70:608–621Google Scholar
  305. Smith KS, Ramsey CA, Hageman PL (2000) Sampling strategy for the rapid screening of mine-waste dumps on abandoned mine lands. In: Proceedings from the 5th international conference on acid rock drainage, vol 2. Society for Mining, Metallurgy, and Exploration, Littleton, pp 1453–1461Google Scholar
  306. Smith MW, Brady KBC (1998) Alkaline addition. In: Coal mine drainage prediction and pollution prevention in Pennsylvania. The Pennsylvania Department of Environmental Protection, Chapter 13, 13–1 to 13–13Google Scholar
  307. Smuda J, Dold B, Friese K, Morgenstern P, Glaesser W (2007) Mineralogical and geochemical study of element mobility at the sulphide-rich Excelsior waste rock dump from the polymetallic Zn-Pb-(Ag-Bi-Cu) deposit, Cerro de Pasco, Peru. J Geochem Explor 92:97–110Google Scholar
  308. Sneddon IR, Orueetxebarria M, Hodson ME, Schofield PF, Valsami-Jones E (2008) Field trial using bone meal amendments to remediate mine waste derived soil contaminated with zinc, lead and cadmium. Appl Geochem 23:2414–2424Google Scholar
  309. Sobek AA, Schuller WA, Freeman JR, Smith RM (1978) Field and laboratory methods applicable to overburdens and minesoils. US EPA 600/2-78-054, Washington, DCGoogle Scholar
  310. Spuller C, Weigand H, Marb C (2007) Trace metal stabilisation in a shooting range soil: mobility and phytotoxicity. J Hazard Mat 141:378–387Google Scholar
  311. Sracek O, Gélinas P, Lefebvre R, Nicholson RV (2006) Comparison of methods for the estimation of pyrite oxidation rate in a waste rock pile at Mine Doyon site, Quebec, Canada. J Geochem Explor 91:99–109Google Scholar
  312. Stanton MR, Gemery-Hill PA, Shanks WC III, Taylor CD (2008) Rates of zinc and trace metal release from dissolving sphalerite at pH 2.0-4.0. Appl Geochem 23:136–147Google Scholar
  313. Strömberg B, Banwart SA (1999) Experimental study of acidity-consuming processes in mine waste rock; some influences of mineralogy and particle size. Appl Geochem 14:1–16Google Scholar
  314. Stumm W, Morgan JJ (1995) Aquatic chemistry, 3rd edn. Wiley, New YorkGoogle Scholar
  315. Svendson A, Henry C, Brown S (2007) Revegetation of high zinc and lead tailings with municipal biosolids and lime: greenhouse study. J Environ Qual 36:1609–1617Google Scholar
  316. Sverdrup HU (1990) The kinetics of base cation release due to chemical weathering. Lund University Press, LundGoogle Scholar
  317. Swayze GA, Smith KS, Clark RN, Sutley SJ, Pearson RM, Vance JS, Hageman PL, Briggs PH, Meier AL, Singleton MJ, Roth S (2000) Using imaging spectroscopy to map acidic mine waste. Environ Sci Technol 34:47–54Google Scholar
  318. Taylor JR, Waring CL, Murphy NC, Leake MJ (1998) An overview of acid mine drainage control and treatment options, including recent advances. In: McLean RW, Bell LC (eds) Proceedings of the 3rd Australian acid mine drainage workshop. Australian Centre for Minesite Rehabilitation Research, Brisbane, pp 147–159Google Scholar
  319. Teršič T, Gosar M, šajn R (2009) Impact of mining activities on soils and sediments at the historical mining area in Podljubelj, NW Slovenia. J Geochem Explor 100:1–10Google Scholar
  320. Trois C, Marcello A, Pretti S, Trois P, Rossi G (2007) The environment risk posed by small dumps of complex arsenic, antimony, nickel and cobalt sulphides. J Geochem Explor 92:83–95Google Scholar
  321. Vaughan DJ, Craig JR (1978) Mineral chemistry of metal sulfides. Cambridge Earth Science Series, Cambridge University Press, CambridgeGoogle Scholar
  322. Velasco F, Alvaro A, Suarez S, Herrero JM, Yusta I (2005) Mapping Fe-bearing hydrated sulphate minerals with short wave infrared (SWIR) spectral analysis at San Miguel mine environment, Iberian Pyrite Belt (SW Spain). J Geochem Explor 87:45–72Google Scholar
  323. Velleux ML, Julien PY, Rojas-Sanchez R, Clements WH, England JF Jr (2006) Simulation of metals transport and toxicity at a mine-impacted watershed: California Gulch, Colorado. Environ Sci Technol 40:6996–7004Google Scholar
  324. Walker FP, Schreiber ME, Rimstidt JD (2006) Kinetics of arsenopyrite oxidative dissolution by oxygen. Geochim Cosmochim Acta 70:1668–1676Google Scholar
  325. Weber PA, Stewart WA, Skinner WM, Weisener CG, Thomas JE, Smart RSC (2004) Geochemical effects of oxidation products and framboidal pyrite oxidation in acid mine drainage prediction techniques. Appl Geochem 19:1953–1974Google Scholar
  326. White WW, Lapakko KA, Cox RL (1999) Static-test methods most commonly used to predict acid-mine drainage: practical guidelines and interpretation. In: Plumlee GS, Logsdon MS (eds) The environmental geochemistry of mineral deposits. Part A: processes, techniques and health issues, vol 6A. Society of Economic Geologists, Littleton, pp 325–338 (Reviews in economic geology)Google Scholar
  327. Williams DJ (1997) Effectiveness of co-disposing coal washery wastes. In: Tailings and mine waste ’97. Balkema, Rotterdam, pp 335–341Google Scholar
  328. Williams DJ, Wilson GW, Currey NA (1997) A cover system for a potentially acid forming waste rock dump in a dry climate. In: Tailings and mine waste ’97. Balkema, Rotterdam, pp 231–236Google Scholar
  329. Williams DJ, Bigham JM, Cravotta CA, Traina SJ, Anderson JE, Lyon JG (2002) Assessing mine drainage pH from the colour and spectral reflectance of chemical precipitates. Appl Geochem 17:1273–1286Google Scholar
  330. Williams PA (1990) Oxide zone geochemistry. Ellis Horwood, New YorkGoogle Scholar
  331. Wilson GW, Newman LL, Ferguson KD (2000) The co-disposal of waste rock and tailings. In: Proceedings from the 5th international conference on acid rock drainage, vol 2. Society for Mining, Metallurgy, and Exploration, Littleton, pp 789–796Google Scholar
  332. Xenidis A, Mylona E, Paspaliaris I (2002) Potential use of lignite fly ash for the control of acid generation from sulphidic wastes. Waste Manage 22:631–641Google Scholar
  333. Xu Y, Schwartz FW (1994) Lead immobilization by hydroxyapatite in aqueous solutions. J Contam Hydrol 15:187–206Google Scholar
  334. Yang J (2006) Concentrations and modes of occurrence of trace elements in the Late Permian coals from the Puan Coalfield, southwestern Guizhou, China. Environ Geochem Health 28:567–576Google Scholar
  335. Yang JE, Skousen JG, Ok YS, Yoo KY, Kim HJ (2006) Reclamation of abandoned coal mine waste in Korea using lime cake by-products. Mine Water Environ 25:227–232Google Scholar
  336. Yin G, Catalan LJJ (2003) Use of alkaline extraction to quantify sulfate concentration in oxidized mine tailings. J Environ Qual 32:2410–2413Google Scholar
  337. You LQ, Heping L, Li Z (2007) Study of galvanic interactions between pyrite and chalcopyrite in a flowing system: implications for the environment. Environ Geol 52:11–18Google Scholar
  338. Younger PL (2004) Environmental impacts of coal mining and associated wastes: a geochemical perspective. In: Gieré R, Stille P (eds) Energy, waste, and the environment: a geochemical perspective, vol 236. Geological Society, London, Special Publications, pp 169–209Google Scholar
  339. Younger PL, Banwart SA, Hedin RS (2002) Mine water; hydrology, pollution, remediation. Kluwer Academic Publishers, DordrechtGoogle Scholar
  340. Yunmei Y, Yongxuan Z, Williams-Jones AE, Zhenmin G, Dexian L (2004) A kinetic study of the oxidation of arsenopyrite in acidic solutions: implications for the environment. Appl Geochem 19:435–444Google Scholar
  341. Zheng G, Kuno A, Mahdi TA, Evans DJ, Miyahara M, Takahashi Y, Matsuo M, Shimizu H (2007) Iron speciation and mineral characterization of contaminated sediments by coal mine drainage in Neath Canal, South Wales, United Kingdom. Geochem J 41:463–474Google Scholar
  342. Zielinski RA, Otton JK, Johnson CA (2001) Sources of salinity near a coal mine spoil pile, north-central Colorado. J Environ Qual 30:1237–1248Google Scholar

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© Springer-Verlag Berlin Heidelberg 2010

Authors and Affiliations

  1. 1.School of Earth & Environmental SciencesJames Cook UniversityTownsvilleAustralia

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