Spectra of Conjugated Polymer Aggregates

Conference paper
Part of the Astrophysics and Space Science Proceedings book series (ASSSP)

Summary

We consider an interchain interaction model to understand the spectral properties of aggregates of conjugated polymers which belong to the family of polycyclic aromatic hydrocarbons, abundant in interstellar medium. As a typical model of aggregation, we have calculated the dressed eigenstates for the equivalent and inequivalent chain-dimers with classified symmetry. The various disorder-induced effects on the spectra can be explained by the dimeric chains which are generally inequivalent.

Keywords

Polycyclic Aromatic Hydrocarbon Interstellar Medium Excitonic State Dipole Orientation Interchain Interaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Allamandola, L. J., Top. Curr. Chem., 153, 1 (1990).Google Scholar
  2. Bittner, E. R., Karabunarliev, S., Herz, L. M., J. Chem. Phys., 126, 191102.Google Scholar
  3. Brown, P. J., Thomas, D. S., Köhler, A., Wilson, J. S., Kim, J. S., Ramsdale, C. M., Sirringhaus, H., Friend, R. H., Phys. Rev. B, 67, 064203 (2003).CrossRefADSGoogle Scholar
  4. Cornil, J., Beljonne, D., Heller, C. M., Campbell, I. H., Laurich, B. K., Smith, D. L., Bradley, D. D. C., Müllen, K., Brédas, J. L., Chem. Phys. Lett., 278, 139 (1997).CrossRefADSGoogle Scholar
  5. Cornil, J., dos Santos, D. A., Crispin, X., Silbey, R., Brédas, J. L., J. Am. Chem. Soc., 120, 1289 (1998).CrossRefGoogle Scholar
  6. Harrison, N. T., Hayes, G. R., Phillips, R. T., Friend, R. H., Phys. Rev. Lett., 77, 1881 (1996).CrossRefADSGoogle Scholar
  7. Ho, P. K. H., Kim, J. S., Tessler, N., Friend, R. H., J. Chem. Phys., 115, 2709 (2001).CrossRefADSGoogle Scholar
  8. Kasha, M., Radiat.Res., 20, 55 (1963).CrossRefGoogle Scholar
  9. Klemperer, W., Vaida, V., Proc. Natl. Acad. Sci. U.S.A., 103, 10584 (2006).CrossRefADSGoogle Scholar
  10. Kwok, S., Astrophys. and Space Sci., 319, 5 (2009).CrossRefADSGoogle Scholar
  11. Pascoli, G., Polleux, A., Astron. Astrophys., 359, 799 (2000).ADSGoogle Scholar
  12. Salama, F., Bakes, E. L. O., Allamandola, L. J., Tielens, A. G. G. M., Astrophys. J., 458, 621 (1996).CrossRefADSGoogle Scholar
  13. Spano, F. C., J. Chem. Phys., 122, 234701 (2005).CrossRefADSGoogle Scholar
  14. Yan, M., Rothberg, L. J., Papadimitrakopoulos, F., Galvin, M. E., Miller, T. M., Phys. Rev. Lett., 72, 1104 (1994).CrossRefADSGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2010

Authors and Affiliations

  1. 1.S.N. Bose National Centre for Basic SciencesKolkataIndia

Personalised recommendations