NLO Molecules and Materials Based on Organometallics: Cubic NLO Properties

  • Mark G. Humphrey
  • Marie P. Cifuentes
  • Marek Samoc
Chapter
Part of the Topics in Organometallic Chemistry book series (TOPORGAN, volume 28)

Abstract

Relevant background theory, experimental procedures, and significant recent advances in the third-order NLO properties of organometallic complexes are reviewed, with particular emphasis on spectral dependence studies and switching of nonlinearity.

Keywords

Cubic nonlinearity Molecular switches Nonlinear absorption Nonlinear refraction 

References

  1. 1.
    Marder SR, Sohn JE, Stucky GD (1991) Materials for nonlinear optics, chemical perspectives. ACS, Washington DCCrossRefGoogle Scholar
  2. 2.
    Marder SR (1992) In: Bruce DW, O'Hare D (eds) Inorganic materials. Wiley, Chichester, UKGoogle Scholar
  3. 3.
    Long NJ (1995) Angew Chem Int Ed Engl 34:21–38CrossRefGoogle Scholar
  4. 4.
    Whittall IR, McDonagh AM, Humphrey MG, Samoc M (1999) Adv Organomet Chem 43: 349–405CrossRefGoogle Scholar
  5. 5.
    Gray GM, Lawson CM (1999) In: Roundhill DM, Fackler JP Jr (eds) Optoelectronic properties of inorganic compounds. Plenum, New York, NYGoogle Scholar
  6. 6.
    Kershaw SV (1999) In: Roundhill DM, Fackler JP Jr (eds) Optoelectronic properties of inorganic compounds. Plenum, New York, NYGoogle Scholar
  7. 7.
    Long NJ (1999) In: Roundhill DM, Fackler JP Jr (eds) Optoelectronic properties of inorganic compounds. Plenum, New York, NYGoogle Scholar
  8. 8.
    Morrall JP, Dalton GT, Humphrey MG, Samoc M (2008) Adv Organomet Chem 55:61–136CrossRefGoogle Scholar
  9. 9.
    Roy S, Kulshrestha K (2005) Opt Commun 252:275–285CrossRefGoogle Scholar
  10. 10.
    Liu Y-C, Kan Y-H, Wu S-X, Yang G-C, Zhao L, Zhang M, Guan W, Su Z-M (2008) J Phys Chem A 112:8086–8092CrossRefGoogle Scholar
  11. 11.
    Shi RF, Garito AF (1998) In: Kuzyk MG, Dirk AF (eds) Characterization techniques and tabulations for organic nonlinear optical materials. CRC, Boca Raton, USAGoogle Scholar
  12. 12.
    Buckingham AD, Pople JA (1955) Proc Phys Soc A 68:905–909CrossRefGoogle Scholar
  13. 13.
    Sutherland RL (2003) Handbook of nonlinear optics, 2nd edn. Marcel Dekker, New YorkGoogle Scholar
  14. 14.
    Sheikh-bahae M, Said AA, Wei T, Hagan DJ, Van Stryland EW (1990) IEEE J Quantum Electron 26:760–769CrossRefGoogle Scholar
  15. 15.
    Li G, Song Y, Hou H, Li L, Fan Y, Zhu Y, Meng X, Mi L (2003) Inorg Chem 42:913–920CrossRefGoogle Scholar
  16. 16.
    Luc J, Migalska-Zalas A, Tkaczyk S, Andriès J, Fillaut J-L, Meghea A, Sahraoui B (2008) J Optoelectron Adv Mater 10:29–43Google Scholar
  17. 17.
    Lang J-P, Sun Z-R, Xu Q-F, Yu H, Tatsumi K (2003) Mater Chem Phys 82:493–498CrossRefGoogle Scholar
  18. 18.
    Lang J-P, Yu H, Ji S-J, Sun Z-R (2003) Phys Chem Chem Phys 5:5127–5132CrossRefGoogle Scholar
  19. 19.
    De Boni L, Andrade AA, Misoguti L, Mendonça CR, Zilio SC (2004) Opt Express 12: 3921–3927CrossRefGoogle Scholar
  20. 20.
    Schafer KJ, Hales JM, Balu M, Belfield KD, Van Stryland EW, Hagan DJ (2004) J Photochem Photobiol A Chem 162:497–502CrossRefGoogle Scholar
  21. 21.
    Collini E, Ferrante C, Bozio R (2005) J Phys Chem B 109:2–5CrossRefGoogle Scholar
  22. 22.
    Lepkowicz RS, Cirloganu CM, Fu J, Przhonska OV, Hagan DJ, Van Stryland EW, Bondar MV, Slominsky YL, Kachkovski AD (2005) J Opt Soc Am B 22:2664–2685CrossRefGoogle Scholar
  23. 23.
    Zheng S, Leclercq A, Fu J, Beverina L, Padilha LA, Zojer E, Schmidt K, Barlow S, Luo J, Jiang S-H, Jen AK-Y, Yi Y, Shuai Z, Van Stryland EW, Hagan DJ, Brédas J-L, Marder SR (2007) Chem Mater 19:432–442CrossRefGoogle Scholar
  24. 24.
    Signorini R, Ferrante C, Pedron D, Zerbetto M, Cecchetto E, Slaviero M, Fortunati I, Collini E, Bozio R, Abbotto A, Beverina L, Pagani GA (2008) J Phys Chem A 112:4224–4234CrossRefGoogle Scholar
  25. 25.
    De Boni L, Gaffo L, Misoguti L, Mendonça CR (2006) Chem Phys Lett 419:417–420CrossRefGoogle Scholar
  26. 26.
    De Boni L, Correa DS, Pavinatto FJ, dos Santos DS Jr, Mendonça CR (2007) J Chem Phys 126:165102-1–165102-4CrossRefGoogle Scholar
  27. 27.
    De Boni L, Piovesan E, Gaffo L, Mendonça CR (2008) J Phys Chem A 112:6803–6807CrossRefGoogle Scholar
  28. 28.
    Balu M, Hales J, Hagan DJ, Van Stryland EW (2004) Opt Express 12:3820–3826CrossRefGoogle Scholar
  29. 29.
    Balu M, Hales J, Hagan DJ, Van Stryland EW (2005) Opt Express 13:3594–3599CrossRefGoogle Scholar
  30. 30.
    Oliveira SL, Corrêa DS, De Boni L, Misoguti L, Zilio SC, Mendonça CR (2006) Appl Phys Lett 88:021911-1–021911-3CrossRefGoogle Scholar
  31. 31.
    Corrêa DS, De Boni L, Gonçalves VC, Balogh DT, Mendonça CR (2007) Polymer 48:5303–5307CrossRefGoogle Scholar
  32. 32.
    Samoc M, Dalton GT, Gladysz JA, Zheng Q, Velkov Y, Ågren H, Norman P, Humphrey MG (2008) Inorg Chem 47:9946–9957CrossRefGoogle Scholar
  33. 33.
    Powell CE, Morrall JP, Ward SA, Cifuentes MP, Notaras EGA, Samoc M, Humphrey MG (2004) J Am Chem Soc 126:12234–12235CrossRefGoogle Scholar
  34. 34.
    Samoc M, Morrall JP, Dalton GT, Cifuentes MP, Humphrey MG (2007) Angew Chem Int Ed 46:731–733CrossRefGoogle Scholar
  35. 35.
    Coe BJ (1999) Chem Eur J 5:2464–2471CrossRefGoogle Scholar
  36. 36.
    Cifuentes MP, Powell CE, Humphrey MG, Heath GA, Samoc M, Luther-Davies B (2001) J Phys Chem A 105:9625–9627CrossRefGoogle Scholar
  37. 37.
    Powell CE, Cifuentes MP, Morrall JPL, Stranger R, Humphrey MG, Samoc M, Luther-Davies B, Heath GA (2003) J Am Chem Soc 125:602–610CrossRefGoogle Scholar
  38. 38.
    Powell CE, Humphrey MG, Cifuentes MP, Morrall JP, Samoc M, Luther-Davies B (2003) J Phys Chem A 107:11264–11266CrossRefGoogle Scholar
  39. 39.
    Cifuentes MP, Powell CE, Morrall JP, McDonagh AM, Lucas NT, Humphrey MG, Samoc M, Houbrechts S, Asselberghs I, Clays K, Persoons A, Isoshima I (2006) J Am Chem Soc 128:10819–10832CrossRefGoogle Scholar
  40. 40.
    Samoc M, Gauthier N, Cifuentes MP, Paul F, Lapinte C, Humphrey MG (2006) Angew Chem Int Ed 45:7376–7379CrossRefGoogle Scholar
  41. 41.
    Hurst SK, Cifuentes MP, Morrall JPL, Lucas NT, Whittall IR, Humphrey MG, Asselberghs I, Persoons A, Samoc M, Luther-Davies B, Willis AC (2001) Organometallics 20:4664–4675CrossRefGoogle Scholar
  42. 42.
    Dalton GT, Cifuentes MP, Petrie S, Stranger R, Humphrey MG, Samoc M (2007) J Am Chem Soc 129:11882–11883CrossRefGoogle Scholar
  43. 43.
    Klapshina LG, Grigoryev IS, Lopatina TI, Semenov VV, Domrachev GA, Douglas WE, Bushuk BA, Bushuk SB, Lukianov AYu, Afanas'ev AV, Benfield RE, Korytin AI (2006) New J Chem 30:615–628CrossRefGoogle Scholar
  44. 44.
    Luc J, Niziol J, Niechowski M, Sahraoui B, Fillaut J-L, Krupka O (2008) Mol Cryst Liq Cryst 485:990–1001CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2010

Authors and Affiliations

  • Mark G. Humphrey
    • 1
  • Marie P. Cifuentes
    • 1
  • Marek Samoc
    • 2
  1. 1.Research School of ChemistryAustralian National UniversityCanberraAustralia
  2. 2.Institute of Physical and Theoretical ChemistryWroclaw University of TechnologyWroclawPoland

Personalised recommendations