Name Reactions pp 480-481

Rupe rearrangement

Chapter

Acid-catalyzed rearrangement of tertiary α-acetylenic (terminal) alcohols, leading to the formation of α,β-unsaturated ketones rather than the corresponding α,βunsaturated aldehydes. Cf.Meyer–Schuster rearrangement.

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Copyright information

© Springer-Verlag Berlin Heidelberg 2009

Authors and Affiliations

  1. 1.Dept. Discovery ChemistryBristol-Myers Squibb CompanyWallingfordUSA

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