Applied Wave Mathematics pp 89-125 | Cite as
Dynamics of Internal Variables from the Mesoscopic Background for the Example of Liquid Crystals and Ferrofluids
Abstract
Liquid crystals are an interesting example of complex materials, showing fluid-like flow behavior on one hand and anisotropic solid-like behavior on the other hand. Macroscopically such complex behavior is taken into account by internal variables, and the question of the equations of motion for the internal variables arises. One way to derive such equations of motion is the so-called mesoscopic theory. The general concept of the mesoscopic theory is presented, and it is applied to the examples of liquid crystals and ferrofluids. The internal variables, here the alignment tensor in the case of liquid crystals, and the polarization in case of ferrofluids, are defined from the mesoscopic background. Equations of motion are derived in both cases. The well-known Landau-type equation for the alignment tensor in liquid crystals is recovered.
Keywords
Liquid Crystal Internal Variable Nematic Liquid Crystal Orientation Distribution Function Isotropic PhasePreview
Unable to display preview. Download preview PDF.
References
- 1.Blenk, S., Ehrentraut, H., Muschik, W.: Orientation balances for liquid crystals and their representation by alignment tensors. Mol. Cryst. Liqu. Cryst. 204, 133–141 (1991) CrossRefGoogle Scholar
- 2.Blenk, S., Ehrentraut, H., Muschik, W.: Statistical foundation of macroscopic balances for liquid crystals in alignment tensor formulation. Physica A 174, 119–138 (1991) CrossRefMathSciNetGoogle Scholar
- 3.Blenk, S., Ehrentraut, H., Muschik, W.: Macroscopic constitutive equations for liquid crystals induced by their mesoscopic orientation distribution. Int. J. Eng. Sci. 30(9), 1127–1143 (1992) MATHCrossRefMathSciNetGoogle Scholar
- 4.Blenk, S., Ehrentraut, H., Muschik, W.: A continuum theory for liquid crystals describing different degrees of orientational order. Liquid Crystals 14(4), 1221–1226 (1993) CrossRefGoogle Scholar
- 5.Blenk, S., Ehrentraut, H., Muschik, W., Papenfuss, C.: Mesoscopic orientation balances and macroscopic constitutive equations of liquid crystals. In: Proc. 7th Intl.Symp. on Continuum Models of Discrete Systems, Materials Science Forum, vol. 123–125, pp. 59–68. Trans Tech, Paderborn (1992) Google Scholar
- 6.Blenk, S., Muschik, W.: Orientational balances for nematic liquid crystals. J. Non-Equilib. Thermodyn. 16, 67–87 (1991) MATHCrossRefGoogle Scholar
- 7.Blenk, S., Muschik, W.: Orientational balances for nematic liquid crystals describing different degrees of orientational order. ZAMM 72(5), T400–T403 (1992) Google Scholar
- 8.Blenk, S., Muschik, W.: Mesoscopic concepts for constitutive equations of nematic liquid crystals in alignment tensor formulation. ZAMM 73(4-5), T331–T333 (1993) MATHGoogle Scholar
- 9.Bogolyubov, N.N.: Kinetic equations. Acad. Sci. USSR J. Phys. 10, 265–274 (1946) MathSciNetGoogle Scholar
- 10.Born, M., Green, H.S.: A general kinetic theory of liquids I: the molecular distribution functions. Proc. Roy. Soc. Lond. A 188, 10–18 (1946) MATHCrossRefMathSciNetGoogle Scholar
- 11.Born, M., Green, H.S.: A general kinetic theory of liquids III: dynamical properties. Proc. Roy. Soc. Lond. A 190, 455–474 (1947) MATHCrossRefMathSciNetGoogle Scholar
- 12.Brand, H., Pleiner, H.: Hydrodynamics of biaxial discotics. Phys. Rev. A 24(5), 2777–2779 (1981) CrossRefGoogle Scholar
- 13.Carlsson, T., Leslie, F.M.: Behaviour of biaxial nematics in the presence of electric and magnetic fields. Liq. Cryst. 10(3), 325–340 (1991) CrossRefGoogle Scholar
- 14.Chapman, S., Cowling, T.G.: The mathematical theory of nonuniform gases. Cambridge University Press (1970) Google Scholar
- 15.Ciancio, V.: On the generalized Debye equation of media with dielectric relaxation phenomena described by vectorial internal thermodynamic variables. J. Non-Equilib. Thermodyn. 14, 239–250 (1989) MATHCrossRefGoogle Scholar
- 16.Ciancio, V., Dolfin, M., Ván, P.: Thermodynamic theory of dia- and paramagnetic materials. Int. J. of Applied Electromagnetics and Mechanics 7, 237–247 (1996) Google Scholar
- 17.Coleman, B.D., Gurtin, M.E.: Thermodynamics with internal state variables. J. Chem. Phys. 47(2), 597–613 (1967) CrossRefGoogle Scholar
- 18.Coleman, B.D., Mizel, V.J.: Thermodynamics and departures from Fouriers law of heat conduction. Arch. Rational Mech. Anal. 13, 245–261 (1963) MATHCrossRefMathSciNetGoogle Scholar
- 19.Coleman, B.D., Noll, W.: The thermodynamics of elastic materials with heat conduction and viscosity. Arch. Rat. Mech. Anal. 13, 167–168 (1963) MATHCrossRefMathSciNetGoogle Scholar
- 20.Cosserat, E., Cosserat, F.: Sur la méchanique générale. Acad. Sci. Paris 145, 1139–1142 (1907) Google Scholar
- 21.De Gennes, P.G.: The Physics of Liquid Crystals. Clarendon Press, Oxford (1974) Google Scholar
- 22.De Gennes, P.G.: Simple Views on Condensed Matter, Series in Modern Condensed Matter Physics, vol. 4. World Scientific, Singapore (1992) Google Scholar
- 23.De Gennes, P.G., Prost, J.: The Physics of Liquid Crystals, 2nd ed. Monographs on Physics. Clarendon Press, Oxford (1995) Google Scholar
- 24.De Groot, S.R.: Thermodynamics of Irreversible Processes. North-Holland, Amsterdam (1951) MATHGoogle Scholar
- 25.De Groot, S.R., Mazur, P.: Non-equilibrium Thermodynamics. North-Holland, Amsterdam (1962) Google Scholar
- 26.Debye, P.: Polar Molecules. Dover, New York (1945) Google Scholar
- 27.Doi, M.: Molecular dynamics and rheological properties of concentrated solutions of rodlike polymers in isotropic and liquid crystalline phases. J. Polym. Sci. Polym. Phys. 19(2), 229–243 (1981) MathSciNetGoogle Scholar
- 28.Doi, M., Edwards, S.F.: The Theory of Polymer Dynamics. Clarendon, Oxford (1986) Google Scholar
- 29.Dreyer, W.: Molekulare Erweiterte Thermodynamik Realer Gase. Habilitationsschrift, Technische Universität Berlin (1990) Google Scholar
- 30.Ehrentraut, H.: A Unified Mesoscopic Continuum Theory of Uniaxial and Biaxial Liquid Crystals. Wissenschaft und Technik, Berlin (1996) Google Scholar
- 31.Ehrentraut, H., Muschik, W., Papenfuss, C.: Mesoscopically derived orientation dynamics of liquid crystals. J. Non-Equilib. Thermodyn. 22, 285–298 (1997) MATHCrossRefGoogle Scholar
- 32.Eringen, A.C.: Simple microfluids. Int. J. Eng. Sci. 2, 205–217 (1964) MATHCrossRefMathSciNetGoogle Scholar
- 33.Eringen, A.C.: Theory of micropolar fluids. J. Math. Mech. 16, 1–18 (1966) MathSciNetGoogle Scholar
- 34.Eringen, A.C.: Micropolar theory of liquid crystals. In: J.F. Johnson, R.S. Porter (eds.) Liquid Crystals and Ordered Fluids, Vol. 3, pp. 443–474. Plenum Press, New York (1978) Google Scholar
- 35.Eringen, A.C., Lee, J.D.: Relations of two continuum theories of liquid crystals. In: Johnson, J.F., Porter, R.S. (eds.) Liquid Crystals and Ordered Fluids, Vol. 2, pp. 315–330. Plenum Press, New York (1974) Google Scholar
- 36.Friedrichs, K.O., Lax, P.D.: Systems of conservation equations with a convex extension. Proc. Nat. Acad. Sci USA 68, 1686–1688 (1971) MATHCrossRefMathSciNetGoogle Scholar
- 37.Grad, H.: Principles of the kinetic theory of gases. In: Flügge, S. (ed.) Handbuch der Physik XII. Springer, Berlin (1958) Google Scholar
- 38.Grebel, H., Hornreich, R.M., Shtrikman, S.: Landau theory of cholesteric blue phases. Phys. Rev. A 28, 1114–1138 (1983) CrossRefGoogle Scholar
- 39.Grebel, H., Hornreich, R.M., Shtrikman, S.: Landau theory of cholesteric blue phases: The role of higher harmonics. Phys. Rev. A 30, 3264–3278 (1984) CrossRefGoogle Scholar
- 40.Hess, S.: Irreversible thermodynamics of nonequilibrium alignment phenomena in molecular liquids and in liquid crystals. Z. Naturforsch. 30a, 728–733 (1975) Google Scholar
- 41.Hess, S.: Irreversible thermodynamics of nonequilibrium alignment phenomena in molecular liquids and in liquid crystals ii. Z. Naturforsch. 30a, 1224–1232 (1975) Google Scholar
- 42.Kirkwood, J.G.: The statistical mechanical theory of transport processes I: general theory. J. Chem. Phys. 14, 180–201 (1946) CrossRefGoogle Scholar
- 43.Kluitenberg, G.A.: On dielectric and magnetic relaxation phenomena and non-equilibrium thermodynamics. Physica 68, 75–92 (1973) CrossRefGoogle Scholar
- 44.Kluitenberg, G.A.: On dielectric and magnetic relaxation phenomena and vectorial internal degrees of freedom in thermodynamics. Physica 87A, 302–330 (1977) Google Scholar
- 45.Kluitenberg, G.A.: On vectorial internal variables and dielectric and magnetic relaxation phenomena. Physica 109A, 91–122 (1981) MathSciNetGoogle Scholar
- 46.Kröger, M.: Rheologie und Struktur von Polymerschmelzen. W&T Verlag, Berlin (1995). PhD Thesis, Technische Universität Berlin Google Scholar
- 47.Landau, L.D., Ginzburg, V.L.: K theorii sverkhrovodimosti. Zh. Eksp. Teor. Fiz. 20, 1064–1082 (1950). English translation: On the theory of superconductivity. In: ter Haar, D. (ed.) Collected Papers of L.D. Landau, pp. 626–633. Pergamon, Oxford (1965) Google Scholar
- 48.Lax, P.D.: Hyperbolic Systems of Conservation Laws and the Mathematical Theory of Shock Waves. Society for Industrial and Applied Mathematics, Philadelphia (1973) MATHGoogle Scholar
- 49.Reichl, L.E.: A Modern Course in Statistical Physics. Edward Arnold, London (1980) Google Scholar
- 50.Leslie, F.M.: Some constitutive equations for liquid crystals. Arch. Rat. Mech. Anal. 28, 265–283 (1968) MATHCrossRefMathSciNetGoogle Scholar
- 51.Liu, I.S.: Method of Lagrange multipliers for exploitation of the entropy principle. Arch. Rat. Mech. Anal. 46, 131–148 (1972) MATHGoogle Scholar
- 52.Liu, I.S.: Continuum Mechanics. Springer, New York (2002) MATHGoogle Scholar
- 53.Longa, L., Monselesan, D., Trebin, H.R.: An extension of the Landau-Ginzburg-de Gennes theory for liquid crystals. Liquid Crystals 2(6), 769–796 (1987) CrossRefGoogle Scholar
- 54.Maier, W., Saupe, A.: Eine einfache molekular-statistische Theorie der nematischen kristallinflüssigen Phase. Teil 1. Z. Naturforsch. 14a, 882–889 (1959) Google Scholar
- 55.Maier, W., Saupe, A.: Eine einfache molekular-statistische Theorie der nematischen kristallinflüssigen Phase. Teil 2. Z. Naturforsch. 15a, 287–292 (1960) Google Scholar
- 56.Miesowicz, M.: The three coefficients of viscosity of anisotropic liquids. Nature 158(4001), 27–27 (1946) CrossRefGoogle Scholar
- 57.Muschik, W., Ehrentraut, H., Papenfuss, C., Blenk, S.: Mesoscopic theory of liquid crystals. In: Brey, J.J., Marro, J., Rubi, J.M., San Miguel, M. (eds.) 25 Years of Non-Equilibrium Statistical Mechanics, Proceedings of the XIII Sitges Conference 1994, Lecture Notes in Physics, vol. 445, pp. 303–311. Springer, New York (1995) CrossRefGoogle Scholar
- 58.Muschik, W., Papenfuss, C., Ehrentraut, H.: Alignment tensor dynamics induced by the mesoscopic balance of the orientation distribution function. Proc. Estonian Acad. Sci. Phys. Math. 46, 94–101 (1997) MATHMathSciNetGoogle Scholar
- 59.Muschik, W., Papenfuss, C., Ehrentraut, H.: Sketch of the mesoscopic description of nematic liquid crystals. J. Non-Newton. Fluid Mech. 119(1-3), 91–104 (2004) MATHCrossRefGoogle Scholar
- 60.Müller, I.: Thermodynamics. Pitman, Boston (1985) MATHGoogle Scholar
- 61.Müller, I.: Grundzüge der Thermodynamik. Springer, Berlin (1994) Google Scholar
- 62.Papenfuss, C.: Nonlinear dynamics of the alignment tensor in the presence of electric fields. Arch. Mech. 50(3), 529–536 (1998) Google Scholar
- 63.Papenfuss, C., Muschik, W.: Constitutive theory for two dimensional liquid crystals. Mol. Cryst. Liq. Cryst. 262, 473–484 (1995) CrossRefGoogle Scholar
- 64.Papenfuss, C., Muschik, W.: Orientational order in free standing liquid crystalline films and derivation of a closure relation for higher order alignment tensors. Mol. Cryst. Liq. Cryst. 330, 541–548 (1999) CrossRefGoogle Scholar
- 65.Papenfuss, C., Ván, P., Muschik, W.: Mesoscopic theory of microcracks. Archive of Mechanics 55, 481–499 (2003) MATHGoogle Scholar
- 66.Stegemeyer, H., Kelker, H.: 100-jähriges Jubiläum: Flüssigkristalle-Blaue Phasen. Nachr. Chem. Tech. Lab. 36(4), 360–364 (1988) CrossRefGoogle Scholar
- 67.Ván, P.: Weakly nonlocal irreversible thermodynamics. Annalen der Physik (Leipzig) 12, 142–169 (2003) Google Scholar
- 68.Ván, P.: Exploiting the second law in weakly non-local continuum physics. Periodica Polytechnica Ser. Mech. Eng. 49(1), 79–94 (2005) Google Scholar
- 69.Ván, P.: The Ginzburg-Landau equation as a consequence of the second law. Continuum Mech. Thermodyn. 17, 165–169 (2005) MATHCrossRefGoogle Scholar
- 70.Ván, P., Papenfuss, C., Muschik, W.: Mesoscopic dynamics of microcracks. Phys. Rev. E 62(5), 6206–6215 (2000) CrossRefGoogle Scholar
- 71.Ván, P., Papenfuss, C., Muschik, W.: Griffith cracks in the mesoscopic microcrack theory. J. Phys. A 37(20), 5315–5328 (2004). Published online: Condensed Matter, abstract, cond-mat/0211207; 2002. MATHCrossRefMathSciNetGoogle Scholar
- 72.Verhás, J.: Irreversible thermodynamics of nematic liquid crystals. Acta Phys. Hung. 55, 275–291 (1984) Google Scholar
- 73.Vertogen, G., Jeu, de W.: Thermotropic Liquid Crystals: Fundamentals. Series in Chemical Physics Vol. 45. Springer, Berlin (1988) Google Scholar
- 74.Virga, E.G.: Variational Theories for Liquid Crystals. Chapman and Hall, London (1994) MATHGoogle Scholar