Dynamics of Internal Variables from the Mesoscopic Background for the Example of Liquid Crystals and Ferrofluids

Chapter

Abstract

Liquid crystals are an interesting example of complex materials, showing fluid-like flow behavior on one hand and anisotropic solid-like behavior on the other hand. Macroscopically such complex behavior is taken into account by internal variables, and the question of the equations of motion for the internal variables arises. One way to derive such equations of motion is the so-called mesoscopic theory. The general concept of the mesoscopic theory is presented, and it is applied to the examples of liquid crystals and ferrofluids. The internal variables, here the alignment tensor in the case of liquid crystals, and the polarization in case of ferrofluids, are defined from the mesoscopic background. Equations of motion are derived in both cases. The well-known Landau-type equation for the alignment tensor in liquid crystals is recovered.

Keywords

Liquid Crystal Internal Variable Nematic Liquid Crystal Orientation Distribution Function Isotropic Phase 
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References

  1. 1.
    Blenk, S., Ehrentraut, H., Muschik, W.: Orientation balances for liquid crystals and their representation by alignment tensors. Mol. Cryst. Liqu. Cryst. 204, 133–141 (1991) CrossRefGoogle Scholar
  2. 2.
    Blenk, S., Ehrentraut, H., Muschik, W.: Statistical foundation of macroscopic balances for liquid crystals in alignment tensor formulation. Physica A 174, 119–138 (1991) CrossRefMathSciNetGoogle Scholar
  3. 3.
    Blenk, S., Ehrentraut, H., Muschik, W.: Macroscopic constitutive equations for liquid crystals induced by their mesoscopic orientation distribution. Int. J. Eng. Sci. 30(9), 1127–1143 (1992) MATHCrossRefMathSciNetGoogle Scholar
  4. 4.
    Blenk, S., Ehrentraut, H., Muschik, W.: A continuum theory for liquid crystals describing different degrees of orientational order. Liquid Crystals 14(4), 1221–1226 (1993) CrossRefGoogle Scholar
  5. 5.
    Blenk, S., Ehrentraut, H., Muschik, W., Papenfuss, C.: Mesoscopic orientation balances and macroscopic constitutive equations of liquid crystals. In: Proc. 7th Intl.Symp. on Continuum Models of Discrete Systems, Materials Science Forum, vol. 123–125, pp. 59–68. Trans Tech, Paderborn (1992) Google Scholar
  6. 6.
    Blenk, S., Muschik, W.: Orientational balances for nematic liquid crystals. J. Non-Equilib. Thermodyn. 16, 67–87 (1991) MATHCrossRefGoogle Scholar
  7. 7.
    Blenk, S., Muschik, W.: Orientational balances for nematic liquid crystals describing different degrees of orientational order. ZAMM 72(5), T400–T403 (1992) Google Scholar
  8. 8.
    Blenk, S., Muschik, W.: Mesoscopic concepts for constitutive equations of nematic liquid crystals in alignment tensor formulation. ZAMM 73(4-5), T331–T333 (1993) MATHGoogle Scholar
  9. 9.
    Bogolyubov, N.N.: Kinetic equations. Acad. Sci. USSR J. Phys. 10, 265–274 (1946) MathSciNetGoogle Scholar
  10. 10.
    Born, M., Green, H.S.: A general kinetic theory of liquids I: the molecular distribution functions. Proc. Roy. Soc. Lond. A 188, 10–18 (1946) MATHCrossRefMathSciNetGoogle Scholar
  11. 11.
    Born, M., Green, H.S.: A general kinetic theory of liquids III: dynamical properties. Proc. Roy. Soc. Lond. A 190, 455–474 (1947) MATHCrossRefMathSciNetGoogle Scholar
  12. 12.
    Brand, H., Pleiner, H.: Hydrodynamics of biaxial discotics. Phys. Rev. A 24(5), 2777–2779 (1981) CrossRefGoogle Scholar
  13. 13.
    Carlsson, T., Leslie, F.M.: Behaviour of biaxial nematics in the presence of electric and magnetic fields. Liq. Cryst. 10(3), 325–340 (1991) CrossRefGoogle Scholar
  14. 14.
    Chapman, S., Cowling, T.G.: The mathematical theory of nonuniform gases. Cambridge University Press (1970) Google Scholar
  15. 15.
    Ciancio, V.: On the generalized Debye equation of media with dielectric relaxation phenomena described by vectorial internal thermodynamic variables. J. Non-Equilib. Thermodyn. 14, 239–250 (1989) MATHCrossRefGoogle Scholar
  16. 16.
    Ciancio, V., Dolfin, M., Ván, P.: Thermodynamic theory of dia- and paramagnetic materials. Int. J. of Applied Electromagnetics and Mechanics 7, 237–247 (1996) Google Scholar
  17. 17.
    Coleman, B.D., Gurtin, M.E.: Thermodynamics with internal state variables. J. Chem. Phys. 47(2), 597–613 (1967) CrossRefGoogle Scholar
  18. 18.
    Coleman, B.D., Mizel, V.J.: Thermodynamics and departures from Fouriers law of heat conduction. Arch. Rational Mech. Anal. 13, 245–261 (1963) MATHCrossRefMathSciNetGoogle Scholar
  19. 19.
    Coleman, B.D., Noll, W.: The thermodynamics of elastic materials with heat conduction and viscosity. Arch. Rat. Mech. Anal. 13, 167–168 (1963) MATHCrossRefMathSciNetGoogle Scholar
  20. 20.
    Cosserat, E., Cosserat, F.: Sur la méchanique générale. Acad. Sci. Paris 145, 1139–1142 (1907) Google Scholar
  21. 21.
    De Gennes, P.G.: The Physics of Liquid Crystals. Clarendon Press, Oxford (1974) Google Scholar
  22. 22.
    De Gennes, P.G.: Simple Views on Condensed Matter, Series in Modern Condensed Matter Physics, vol. 4. World Scientific, Singapore (1992) Google Scholar
  23. 23.
    De Gennes, P.G., Prost, J.: The Physics of Liquid Crystals, 2nd ed. Monographs on Physics. Clarendon Press, Oxford (1995) Google Scholar
  24. 24.
    De Groot, S.R.: Thermodynamics of Irreversible Processes. North-Holland, Amsterdam (1951) MATHGoogle Scholar
  25. 25.
    De Groot, S.R., Mazur, P.: Non-equilibrium Thermodynamics. North-Holland, Amsterdam (1962) Google Scholar
  26. 26.
    Debye, P.: Polar Molecules. Dover, New York (1945) Google Scholar
  27. 27.
    Doi, M.: Molecular dynamics and rheological properties of concentrated solutions of rodlike polymers in isotropic and liquid crystalline phases. J. Polym. Sci. Polym. Phys. 19(2), 229–243 (1981) MathSciNetGoogle Scholar
  28. 28.
    Doi, M., Edwards, S.F.: The Theory of Polymer Dynamics. Clarendon, Oxford (1986) Google Scholar
  29. 29.
    Dreyer, W.: Molekulare Erweiterte Thermodynamik Realer Gase. Habilitationsschrift, Technische Universität Berlin (1990) Google Scholar
  30. 30.
    Ehrentraut, H.: A Unified Mesoscopic Continuum Theory of Uniaxial and Biaxial Liquid Crystals. Wissenschaft und Technik, Berlin (1996) Google Scholar
  31. 31.
    Ehrentraut, H., Muschik, W., Papenfuss, C.: Mesoscopically derived orientation dynamics of liquid crystals. J. Non-Equilib. Thermodyn. 22, 285–298 (1997) MATHCrossRefGoogle Scholar
  32. 32.
    Eringen, A.C.: Simple microfluids. Int. J. Eng. Sci. 2, 205–217 (1964) MATHCrossRefMathSciNetGoogle Scholar
  33. 33.
    Eringen, A.C.: Theory of micropolar fluids. J. Math. Mech. 16, 1–18 (1966) MathSciNetGoogle Scholar
  34. 34.
    Eringen, A.C.: Micropolar theory of liquid crystals. In: J.F. Johnson, R.S. Porter (eds.) Liquid Crystals and Ordered Fluids, Vol. 3, pp. 443–474. Plenum Press, New York (1978) Google Scholar
  35. 35.
    Eringen, A.C., Lee, J.D.: Relations of two continuum theories of liquid crystals. In: Johnson, J.F., Porter, R.S. (eds.) Liquid Crystals and Ordered Fluids, Vol. 2, pp. 315–330. Plenum Press, New York (1974) Google Scholar
  36. 36.
    Friedrichs, K.O., Lax, P.D.: Systems of conservation equations with a convex extension. Proc. Nat. Acad. Sci USA 68, 1686–1688 (1971) MATHCrossRefMathSciNetGoogle Scholar
  37. 37.
    Grad, H.: Principles of the kinetic theory of gases. In: Flügge, S. (ed.) Handbuch der Physik XII. Springer, Berlin (1958) Google Scholar
  38. 38.
    Grebel, H., Hornreich, R.M., Shtrikman, S.: Landau theory of cholesteric blue phases. Phys. Rev. A 28, 1114–1138 (1983) CrossRefGoogle Scholar
  39. 39.
    Grebel, H., Hornreich, R.M., Shtrikman, S.: Landau theory of cholesteric blue phases: The role of higher harmonics. Phys. Rev. A 30, 3264–3278 (1984) CrossRefGoogle Scholar
  40. 40.
    Hess, S.: Irreversible thermodynamics of nonequilibrium alignment phenomena in molecular liquids and in liquid crystals. Z. Naturforsch. 30a, 728–733 (1975) Google Scholar
  41. 41.
    Hess, S.: Irreversible thermodynamics of nonequilibrium alignment phenomena in molecular liquids and in liquid crystals ii. Z. Naturforsch. 30a, 1224–1232 (1975) Google Scholar
  42. 42.
    Kirkwood, J.G.: The statistical mechanical theory of transport processes I: general theory. J. Chem. Phys. 14, 180–201 (1946) CrossRefGoogle Scholar
  43. 43.
    Kluitenberg, G.A.: On dielectric and magnetic relaxation phenomena and non-equilibrium thermodynamics. Physica 68, 75–92 (1973) CrossRefGoogle Scholar
  44. 44.
    Kluitenberg, G.A.: On dielectric and magnetic relaxation phenomena and vectorial internal degrees of freedom in thermodynamics. Physica 87A, 302–330 (1977) Google Scholar
  45. 45.
    Kluitenberg, G.A.: On vectorial internal variables and dielectric and magnetic relaxation phenomena. Physica 109A, 91–122 (1981) MathSciNetGoogle Scholar
  46. 46.
    Kröger, M.: Rheologie und Struktur von Polymerschmelzen. W&T Verlag, Berlin (1995). PhD Thesis, Technische Universität Berlin Google Scholar
  47. 47.
    Landau, L.D., Ginzburg, V.L.: K theorii sverkhrovodimosti. Zh. Eksp. Teor. Fiz. 20, 1064–1082 (1950). English translation: On the theory of superconductivity. In: ter Haar, D. (ed.) Collected Papers of L.D. Landau, pp. 626–633. Pergamon, Oxford (1965) Google Scholar
  48. 48.
    Lax, P.D.: Hyperbolic Systems of Conservation Laws and the Mathematical Theory of Shock Waves. Society for Industrial and Applied Mathematics, Philadelphia (1973) MATHGoogle Scholar
  49. 49.
    Reichl, L.E.: A Modern Course in Statistical Physics. Edward Arnold, London (1980) Google Scholar
  50. 50.
    Leslie, F.M.: Some constitutive equations for liquid crystals. Arch. Rat. Mech. Anal. 28, 265–283 (1968) MATHCrossRefMathSciNetGoogle Scholar
  51. 51.
    Liu, I.S.: Method of Lagrange multipliers for exploitation of the entropy principle. Arch. Rat. Mech. Anal. 46, 131–148 (1972) MATHGoogle Scholar
  52. 52.
    Liu, I.S.: Continuum Mechanics. Springer, New York (2002) MATHGoogle Scholar
  53. 53.
    Longa, L., Monselesan, D., Trebin, H.R.: An extension of the Landau-Ginzburg-de Gennes theory for liquid crystals. Liquid Crystals 2(6), 769–796 (1987) CrossRefGoogle Scholar
  54. 54.
    Maier, W., Saupe, A.: Eine einfache molekular-statistische Theorie der nematischen kristallinflüssigen Phase. Teil 1. Z. Naturforsch. 14a, 882–889 (1959) Google Scholar
  55. 55.
    Maier, W., Saupe, A.: Eine einfache molekular-statistische Theorie der nematischen kristallinflüssigen Phase. Teil 2. Z. Naturforsch. 15a, 287–292 (1960) Google Scholar
  56. 56.
    Miesowicz, M.: The three coefficients of viscosity of anisotropic liquids. Nature 158(4001), 27–27 (1946) CrossRefGoogle Scholar
  57. 57.
    Muschik, W., Ehrentraut, H., Papenfuss, C., Blenk, S.: Mesoscopic theory of liquid crystals. In: Brey, J.J., Marro, J., Rubi, J.M., San Miguel, M. (eds.) 25 Years of Non-Equilibrium Statistical Mechanics, Proceedings of the XIII Sitges Conference 1994, Lecture Notes in Physics, vol. 445, pp. 303–311. Springer, New York (1995) CrossRefGoogle Scholar
  58. 58.
    Muschik, W., Papenfuss, C., Ehrentraut, H.: Alignment tensor dynamics induced by the mesoscopic balance of the orientation distribution function. Proc. Estonian Acad. Sci. Phys. Math. 46, 94–101 (1997) MATHMathSciNetGoogle Scholar
  59. 59.
    Muschik, W., Papenfuss, C., Ehrentraut, H.: Sketch of the mesoscopic description of nematic liquid crystals. J. Non-Newton. Fluid Mech. 119(1-3), 91–104 (2004) MATHCrossRefGoogle Scholar
  60. 60.
    Müller, I.: Thermodynamics. Pitman, Boston (1985) MATHGoogle Scholar
  61. 61.
    Müller, I.: Grundzüge der Thermodynamik. Springer, Berlin (1994) Google Scholar
  62. 62.
    Papenfuss, C.: Nonlinear dynamics of the alignment tensor in the presence of electric fields. Arch. Mech. 50(3), 529–536 (1998) Google Scholar
  63. 63.
    Papenfuss, C., Muschik, W.: Constitutive theory for two dimensional liquid crystals. Mol. Cryst. Liq. Cryst. 262, 473–484 (1995) CrossRefGoogle Scholar
  64. 64.
    Papenfuss, C., Muschik, W.: Orientational order in free standing liquid crystalline films and derivation of a closure relation for higher order alignment tensors. Mol. Cryst. Liq. Cryst. 330, 541–548 (1999) CrossRefGoogle Scholar
  65. 65.
    Papenfuss, C., Ván, P., Muschik, W.: Mesoscopic theory of microcracks. Archive of Mechanics 55, 481–499 (2003) MATHGoogle Scholar
  66. 66.
    Stegemeyer, H., Kelker, H.: 100-jähriges Jubiläum: Flüssigkristalle-Blaue Phasen. Nachr. Chem. Tech. Lab. 36(4), 360–364 (1988) CrossRefGoogle Scholar
  67. 67.
    Ván, P.: Weakly nonlocal irreversible thermodynamics. Annalen der Physik (Leipzig) 12, 142–169 (2003) Google Scholar
  68. 68.
    Ván, P.: Exploiting the second law in weakly non-local continuum physics. Periodica Polytechnica Ser. Mech. Eng. 49(1), 79–94 (2005) Google Scholar
  69. 69.
    Ván, P.: The Ginzburg-Landau equation as a consequence of the second law. Continuum Mech. Thermodyn. 17, 165–169 (2005) MATHCrossRefGoogle Scholar
  70. 70.
    Ván, P., Papenfuss, C., Muschik, W.: Mesoscopic dynamics of microcracks. Phys. Rev. E 62(5), 6206–6215 (2000) CrossRefGoogle Scholar
  71. 71.
    Ván, P., Papenfuss, C., Muschik, W.: Griffith cracks in the mesoscopic microcrack theory. J. Phys. A 37(20), 5315–5328 (2004). Published online: Condensed Matter, abstract, cond-mat/0211207; 2002. MATHCrossRefMathSciNetGoogle Scholar
  72. 72.
    Verhás, J.: Irreversible thermodynamics of nematic liquid crystals. Acta Phys. Hung. 55, 275–291 (1984) Google Scholar
  73. 73.
    Vertogen, G., Jeu, de W.: Thermotropic Liquid Crystals: Fundamentals. Series in Chemical Physics Vol. 45. Springer, Berlin (1988) Google Scholar
  74. 74.
    Virga, E.G.: Variational Theories for Liquid Crystals. Chapman and Hall, London (1994) MATHGoogle Scholar

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Authors and Affiliations

  1. 1.Institute of Cybernetics at Tallinn University of TechnologyTallinnEstonia

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